Alkali metal titanates and methods for their synthesis
View Patent ↗Disclosed is a doped lithium titanate and its use as an electrode in a battery. Further disclosed is a method for making an alkali metal titanate, which method includes mixing an alkali metal compound and a titanium compound, impact milling the mixture, and heating the milled mixture for a time, and at a temperature, sufficient to convert the mixture to the alkali metal titanate. The alkali metal compound can be in the form of Li 2 CO 3 and the titanium compound can be in the form of TiO 2 . A dopant may be included in the mixture.
1. A method of making a zirconium doped, alkali metal titanate, said method comprising the steps of:
providing an alkali metal compound which comprises lithium carbonate;
providing a first preselected amount of a titanium compound;
providing a second preselected amount of a zirconium compound wherein the atomic percent of zirconium in said second preselected amount is in the range of 0.1-5% of the combined atomic percent of titanium in said first preselected amount and zirconium in said second preselected amount;
preparing a mixture of said alkali metal compound, said first preselected amount of said titanium and said second preselected amount of said zirconium compound by impact milling said alkali metal compound, said titanium compound and said zirconium compound; and
heating said mixture for a time, and at a temperature, sufficient to convert said mixture to said zirconium doped alkali metal titanate.
2. The method of claim 1 , wherein said titanium compound comprises an oxide of titanium, and said alkali metal titanate comprises lithium titanate which is doped with 0.1-5 atomic percent of zirconium.
3. The method of claim 1 wherein said step of preparing a mixture comprises mixing approximately 2 moles of Li 2 CO 3 and approximately 5 moles of TiO 2 .
4. The method of claim 1 , wherein said impact milling process comprises ball milling or attritor milling.
5. The method of claim 1 , wherein said step of heating said mixture comprises heating said mixture to a temperature of no more than 1000° C.
6. The method of claim 5 , wherein said step of heating said mixture comprises maintaining said mixture at a temperature of 800° C.
7. The method of claim 1 , wherein said reaction mixture is maintained at said temperature for at least one minute.
8. The method of claim 1 , wherein said reaction mixture is maintained at said temperature for at least two hours.
9. The method of claim 1 , wherein said step of heating is carried out under an atmosphere which is an inert atmosphere or an oxidizing atmosphere.
10. The method of claim 1 , wherein the atomic percentage of zirconium in said second predetermined amount is 1% of the combined atomic percent of titanium in said first preselected amount and zirconium in said second preselected amount.