Poly(arylene ether) compositions, methods, and articles
View Patent ↗A thermoplastic composition includes particular amounts of a poly(arylene ether), a polystyrene, and glass fibers. The composition exhibits a highly desirable balance of stiffness, strength, and melt flow properties. Methods of preparing the composition are also described, as are articles prepared from the composition.
1. A composition, consisting of:
about 30 to about 35 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether) having a post-compounding weight average molecular weight of about 50,000 to about 60,000 atomic mass units;
about 20 to about 25 weight percent of an atactic homopolystyrene having a number average molecular weight of about 30,000 to about 100,000 atomic mass units;
about 0.2 to about 2 weight percent of a mold release agent; and
about 35 to about 45 weight percent glass fibers having a diameter of about 10 to about 20 micrometers; and
optionally, up to 5 weight percent of an additive selected from the group consisting of stabilizers, processing aids, drip retardants, nucleating agents, dyes, pigments, antioxidants, anti-static agents, blowing agents, metal deactivators, antiblocking agents, fragrances, and combinations thereof;
wherein all weight percents are based on the total weight of the composition; and
wherein the composition is free of any polymer other than the poly(2,6-dimethyl-1,4-phenylene ether), the atactic homopolystyrene, and the mold release agent; and
wherein the composition exhibits
a tensile strength of at least 145 megapascals measured at 23° C. according to ISO 527,
a tensile knitline strength of at least 55 megapascals measured on a double-gated tensile bar according to ISO 527,
a flexural strength of at least 180 megapascals measured at 23° C. according to ISO 178, and
a melt volume-flow rate of at least 15 milliliters per 10 minutes measured at 300° C. and 10 kilogram load according to ISO 1133.
2. The composition of claim 1 , wherein the poly(arylene ether) has a pre-compounding weight average molecular weight of about 40,000 to about 50,000 atomic mass units.
3. The composition of claim 1 , wherein the poly(arylene ether) has a pre-compounding molecular weight distribution comprising about 15 to about 20 weight percent of molecules having a molecular weight less than or equal to 12,000 atomic mass units.
4. The composition of claim 1 , wherein the poly(arylene ether) has a pre-compounding molecular weight distribution comprising about 6 to about 15 weight percent of molecules having a molecular weight greater than or equal to 100,000 atomic mass units.
5. The composition of claim 1 , wherein the composition exhibits
a tensile strength of 145 to about 160 megapascals,
a tensile knitline strength of 55 to about 70 megapascals,
a flexural strength of 180 to about 230 megapascals, and
a melt volume-flow rate of 15 to about 25 milliliters per 10 minutes.
6. An article consisting of a composition consisting of:
about 30 to about 35 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether) having a post-compounding weight average molecular weight of about 50,000 to about 60,000 atomic mass units;
about 20 to about 25 weight percent of an atactic homopolystyrene having a number average molecular weight of about 30,000 to about 100,000 atomic mass units;
about 0.2 to about 2 weight percent of a mold release agent; and
about 35 to about 45 weight percent glass fibers having a diameter of about 10 to about 20 micrometers; and
optionally, up to 5 weight percent of an additive selected from the group consisting of stabilizers, processing aids, drip retardants, nucleating agents, dyes, pigments, antioxidants, anti-static agents, blowing agents, metal deactivators, antiblocking agents, fragrances, and combinations thereof;
wherein all weight percents are based on the total weight of the composition; and
wherein the composition is free of any polymer other than the poly(2,6-dimethyl-1,4-phenylene ether), the atactic homopolystyrene, and the mold release agent; and
wherein the composition exhibits
a tensile strength of at least 145 megapascals measured at 23° C. according to ISO 527,
a tensile knitline strength of at least 55 megapascals measured on a double-gated tensile bar according to ISO 527,
a flexural strength of at least 180 megapascals measured at 23° C. according to ISO 178, and
a melt volume-flow rate of at least 15 milliliters per 10 minutes measured at 300° C. and 10 kilogram load according to ISO 1133.
7. The article of claim 6 , wherein the article is a water meter pressure plate.
8. The article of claim 6 , wherein the article is fabricated by a method comprising injection molding, compression molding, or a combination thereof.
9. A method of preparing a composition, comprising:
melt kneading components consisting of
about 30 to about 35 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether) having a post-compounding weight average molecular weight of
about 50,000 to about 60,000 atomic mass units, about 20 to about 25 weight percent of an atactic homopolystyrene having a number average molecular weight of about 30,000 to about 100,000 atomic mass units,
about 0.2 to about 2 weight percent of a mold release agent, about 35 to about 45 weight percent glass fibers having a diameter of about 10 to about 20 micrometers, and
optionally, up to 5 weight percent of an additive selected from the group consisting of stabilizers, processing aids, drip retardants, nucleating agents, dyes, pigments, antioxidants, anti-static agents, blowing agents, metal deactivators, antiblocking agents, fragrances, and combinations thereof
to form a composition;
wherein all weight percents are based on the total weight of the composition;
wherein the composition is free of any polymer other than the poly(2,6-dimethyl-1,4-phenylene ether), the atactic homopolystyrene, and the mold release agent; and
wherein the composition exhibits
a tensile strength of at least 145 megapascals measured at 23° C. according to ISO 527,
a tensile knitline strength of at least 55 megapascals measured on a double-gated tensile bar according to ISO 527,
a flexural strength of at least 180 megapascals measured at 23° C. according to ISO 178, and
a melt volume-flow rate of at least 15 milliliters per 10 minutes measured at 300° C. and 10 kilogram load according to ISO 1133.
10. The method of claim 9 , wherein the melt kneading comprises extruding the composition at a temperature of about 350 to about 360° C.
11. The method of claim 9 , wherein the melt kneading comprises melt kneading with an extruder having a die temperature of about 290 to about 320° C.