ADDITIVES FOR IMPROVED WELDABLE COMPOSITES
The present invention is directed to additives for improved weldable composites. A metal composite structure ( 10 ) features two metal members ( 12 )( 14 ) sandwiching a viscoelastic layer ( 26 ) where the viscoelastic layer entrains carbide-forming, carbon trapping particles ( 28 ) configured and sized to provide an effective inhibitor to carbon migration from the viscoelastic layer during welding.
1 . A weldable metal composite, comprising:
a first metal member and a second metal member;
a viscoelastic layer disposed between said first and second metal members, said viscoelastic layer including carbon trapping particles sized and configured to inhibit carbon pick up and migration of carbon containing moieties from the viscoelastic layer to the metal members during welding of the composite.
2 . The weldable composite of claim 1 , wherein said carbon trapping particles have a rod-shaped configuration.
3 . The weldable composite of claim 1 , wherein said carbon trapping particles are in the form of flakes.
4 . The metal composite according to claim 1 where during welding said carbon trapping particles establish at least one carbide-forming boundary between said viscoelastic layer and at least one of said metal members.
5 . The metal composite according to claim 1 where said viscoelastic layer is a pressure sensitive adhesive further comprising electrically conductive particles dispersed therethrough and where the composite exhibits sound damping properties.
6 . The metal composite according to claim S where said pressure sensitive adhesive is selected from the group consisting of poly(isoprene:styrene} and poly (alkyl acrylate).
7 . The metal composite according to claim 6 wherein said electrically conductive particles are selected from the group consisting of iron, nickel, copper, aluminum, and electrically conductive alloys and compounds thereof.
8 . The metal composite according to claim 1 , wherein said first metal member and said second metal member are composed of a material selected from the group consisting of steel and steel alloys.
9 . The metal composite of claim 1 , wherein first and second metal members possess a substantially sheet-like form and comprise steel selected from the group consisting of low carbon, interstitial free, bake hardenable, high strength low alloy, transformation induced plasticity, martensitic, dual phase, and stainless steel.
10 . The metal composite of claim 4 , wherein said carbon trapping particles defines a discontinuous boundary layer.
11 . The metal composite of claim 4 , wherein said carbon trapping particles define a continuous boundary layer.
12 . A method of making a sound damping metal composite for welding, comprising the steps of:
selecting a first metal member formed of a metal selected from the group consisting of low carbon steel, interstitial free steel, bake hardenable steel, high-strength low-alloy steel, transformation induced plasticity, martensitic, dual-phase steel, stainless steel and alloys thereof susceptible to carbide formation;
selecting a second metal member formed of a metal selected from the group consisting of low carbon steel, interstitial free steel, bake hardenable steel, high-strength low-alloy steel, transformation induced plasticity, martensitic, dual-phase steel, stainless steel, and alloys thereof susceptible to carbide formation; and
applying a viscoelastic layer between said first metal member and said second metal member, said layer including carbon trapping particles sized and configured to inhibit migration of carbon containing moieties from the viscoelastic layer to the metal members during welding of the composite.
13 . The method of claim 12 , further comprising the step of:
dispersing conductive particles within the viscoelastic layer.
14 . The method of claim 13 further comprising the step of:
resistance spot welding the composite whereby said carbon trapping particles melt and react with carbon to form carbides and to thereby inhibit carbon diffusion from the viscoelastic into the metal members.