IP Library Granted Patent US 8,431,284
Granted Patent B2
US 8,431,284 · App. 11/768,471 · Granted Apr 30, 2013

Low electrical resistance bipolar plate-diffusion media assembly

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Quick Facts
Patent No.
US 8,431,284
App. No.
11/768,471
Granted
Apr 30, 2013
Kind
B2
Abstract

A fuel cell assembly and method of forming the same is disclosed, the fuel cell assembly including a membrane electrode assembly, a plurality of diffusion media, and a plurality of bipolar plates, wherein the diffusion media are adhered to the bipolar plates with an adhesive layer adapted to minimize an electrical resistance within the fuel cell assembly.

Claims (38)

1. A fuel cell assembly comprising:

a membrane electrode assembly including a membrane disposed between a plurality of catalyst layers;

a plurality of diffusion media, each having a microporous layer disposed on a side thereof, wherein the side of said diffusion media having the microporous layer is adhered to the catalyst layers of said membrane electrode assembly;

a first bipolar plate including a first working face and a second working face;

a second bipolar plate including a first working face and a second working face; and

an electrically conductive adhesive layer disposed on at least a portion of at least one of the first working face and the second working face of said first bipolar plate and said second bipolar plate, wherein said adhesive layer adheres said first bipolar plate to one of said diffusion media and said second bipolar plate to another of said diffusion media to minimize an electrical contact resistance between said diffusion media and said first and second bipolar plates.

2. The fuel assembly of claim 1 , wherein said first bipolar plate and said second bipolar plate include a plurality of flow channels and a plurality of lands formed along the first working face and the second working face.

3. The fuel assembly of claim 2 , wherein said adhesive layer adheres said diffusion media to the lands of the at least one of the first working face and the second working face of said first bipolar plate and said second bipolar plate.

4. The fuel cell assembly of claim 1 , wherein said adhesive layer is a b-stage adhesive.

5. The fuel assembly of claim 1 , wherein said first bipolar plate and said second bipolar plate each include a first unipolar plate having an inner surface and a second unipolar plate having an inner surface, wherein the inner surface of the first unipolar plate is coupled to the inner surface of the second unipolar plate.

6. The fuel cell assembly of claim 5 , wherein the inner surface of the first unipolar plates and the inner surface of the second unipolar plates are coupled by one of a b-stage adhesive, soldering, and weld-adhering.

7. The fuel cell assembly of claim 1 , further including a primer layer disposed intermediate said first bipolar plate and said adhesive layer and intermediate said second bipolar plate and said adhesive layer.

8. The fuel cell assembly of claim 1 , wherein said first bipolar plate and said second bipolar plate each include a perimeter portion adapted to receive a sealant therein.

9. The fuel cell assembly of claim 8 , wherein the sealant is adapted to adhere said first bipolar plate, said second bipolar plate, and said membrane electrode assembly and provide and a substantially fluid-tight seal.

10. A fuel cell stack comprising:

a plurality of membrane electrode assemblies, each including a membrane disposed between a plurality of catalyst layers;

a plurality of diffusion media, wherein one of said plurality of diffusion media is adjacent each side of said membrane electrode assemblies;

a plurality of bipolar plates, each of said bipolar plates including a first working face and a second working face and having a perimeter portion, wherein each of said bipolar plates is disposed between two of said membrane electrode assemblies;

a sealant disposed in a void formed by the perimeter portions of said bipolar plates, wherein said sealant forms a seal between said bipolar plates and said membrane electrode assembly; and

an electrically conductive adhesive layer disposed on at least a portion of at least one of the first working face and the second working face of said bipolar plates, wherein said adhesive layer adheres one of said bipolar plates to one of said diffusion media and another of said bipolar plates to another of said diffusion media to minimize an electrical contact resistance between said diffusion media and said bipolar plates.

11. The fuel cell stack of claim 10 , wherein said plurality of bipolar plates include a plurality of flow channels and a plurality of lands formed along the first working face and the second working face.

12. The fuel cell stack of claim 11 , wherein said adhesive layer adheres said diffusion media to the lands of the at least one of the first working face and the second working face of said plurality of bipolar plates.

13. The fuel cell stack of claim 10 , wherein said adhesive layer is a b-stage adhesive.

14. The fuel cell stack of claim 10 , wherein said bipolar plates each include a first unipolar plate having an inner surface and a second unipolar plate having an inner surface, wherein the inner surface of the first unipolar plate is coupled to the inner surface of the second unipolar plate by one of a b-stage adhesive, soldering, and weld-adhering.

15. The fuel cell stack of claim 10 , wherein the seal between said bipolar plates and said membrane electrode assembly is a fluid-tight seal.

16. A method for making a fuel cell assembly for use in a PEM fuel cell, comprising the steps of:

providing a plurality of bipolar plates, each plate having a first working face and a second working face;

providing an electrically conductive adhesive layer on the first working face and the second working face of the bipolar plates;

providing a membrane electrode assembly having a membrane disposed between catalyst layers;

coating a diffusion media with a paste to form a microporous layer thereon;

sintering the diffusion media and microporous layers together;

adhering the microporous layers of the diffusion media to the catalyst layers of the membrane electrode assembly;

adhering the catalyst layers and the proton exchange membrane;

adhering the diffusion media to the first working face of one of the bipolar plates with the adhesive layer and adhering another diffusion media to the first working face of another bipolar plate with the adhesive layer.

17. The method of claim 16 , wherein the adhesive layers is a b-stage adhesive.

18. The method of claim 16 , further including the step of forming the plurality of bipolar plates from a material coil coated with the adhesive layer.

19. The method of claim 16 , wherein each of the plurality of bipolar plates include a perimeter portion.

20. The method of claim 19 , further including the step of providing a sealant disposed on the perimeter portion of said bipolar plates adapted to seal a first bipolar plate, a second bipolar plate, and the membrane electrode assembly together.

Assignments (12)
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2014
From: WILMINGTON TRUST COMPANY
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 034185/0587 →
CHANGE OF NAME Recorded Feb 10, 2011
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 025781/0035 →
SECURITY AGREEMENT Recorded Nov 8, 2010
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: WILMINGTON TRUST COMPANY
Reel/Frame 025324/0057 →
RELEASE OF SECURITY INTEREST Recorded Nov 5, 2010
From: UAW RETIREE MEDICAL BENEFITS TRUST
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 025314/0946 →
RELEASE OF SECURITY INTEREST Recorded Nov 4, 2010
From: UNITED STATES DEPARTMENT OF THE TREASURY
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 025245/0656 →
SECURITY AGREEMENT Recorded Aug 28, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UAW RETIREE MEDICAL BENEFITS TRUST
Reel/Frame 023162/0140 →
SECURITY AGREEMENT Recorded Aug 27, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UNITED STATES DEPARTMENT OF THE TREASURY
Reel/Frame 023156/0264 →
RELEASE OF SECURITY INTEREST Recorded Aug 21, 2009
From: CITICORP USA, INC. AS AGENT FOR BANK PRIORITY SECURED PARTIES; CITICORP USA, INC. AS AGENT FOR HEDGE PRIORITY SECURED PARTIES
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 023155/0663 →
RELEASE OF SECURITY INTEREST Recorded Aug 20, 2009
From: UNITED STATES DEPARTMENT OF THE TREASURY
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 023124/0563 →
SECURITY AGREEMENT Recorded Apr 16, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: CITICORP USA, INC. AS AGENT FOR BANK PRIORITY SECURED PARTIES; CITICORP USA, INC. AS AGENT FOR HEDGE PRIORITY SECURED PARTIES
Reel/Frame 022553/0540 →
SECURITY AGREEMENT Recorded Feb 3, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UNITED STATES DEPARTMENT OF THE TREASURY
Reel/Frame 022195/0334 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 6, 2007
From: BUDINSKI, MICHAEL K.
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 019653/0638 →