Roll to roll manufacturing of organic solar modules
View Patent ↗The invention discloses for the first time how an organic component can be produced in a process designed entirely as a roll-to-roll process. The advantage of the continuous production method described here is, further, that the active regions of the active semiconductor layer are not exposed to unprotected solvents and/or solvent vapors at any time during the production process. This makes it possible to produce a high-quality organic component.
1. A method, comprising:
forming a first electrode supported by a substrate,
forming a first sacrificial layer supported by the first electrode;
forming an organic semiconductor material supported by the first sacrificial layer, the organic semiconductor material including first and second portions,
removing the first sacrificial layer, thereby removing the first portion of the organic semiconductor material, and
after removing the first sacrificial layer, forming a second electrode supported by the second portion of the organic semiconductor material, thereby providing an organic electronic component that comprises the substrate, the first electrode, the second portion of the organic semiconductor material and the second electrode,
wherein:
the second electrode does not contact the substrate, and
the first electrode, the first sacrificial layer, the organic semiconductor material and the second electrode are formed via a roll-to-roll process.
2. The method as recited in claim 1 , further comprising forming a second sacrificial layer supported by the substrate.
3. The method as recited in claim 2 , wherein the second sacrificial layer is formed via the roll-to-roll process.
4. The method as recited in claim 2 , further comprising a sealing step.
5. A method, comprising:
forming a photovoltaic cell using a roll-to-roll process, the photovoltaic cell comprising an organic active layer,
wherein the roll-to-roll process comprises:
forming a first electrode supported by a substrate;
forming first and second sacrificial layers, each of which being supported by at least one element selected from the group consisting of the first electrode and the substrate;
forming an organic active material that is supported by the first and second sacrificial layers;
after forming the organic active material, removing the first and second sacrificial layers, thereby removing portions of the organic active material to provide the organic active layer; and
after removing at least one of the first and second sacrificial layers, forming a second electrode supported by the organic active layer, thereby providing a photovoltaic cell that comprises the substrate, the first electrode, the organic active layer, and the second electrode,
wherein the second electrode does not contact the substrate.
6. The method of claim 5 , wherein the organic active layer comprises a polymer.
7. The method of claim 6 , wherein the polymer comprises polythiophene.
8. The method of claim 7 , wherein the organic active layer comprises a fullerene.
9. The method of claim 6 , wherein the organic active layer comprises a fullerene.
10. The method of claim 5 , wherein the organic active layer comprises a fullerene.
11. A method, comprising:
providing a first electrode supported by a substrate;
forming a sacrificial layer supported by at least one element selected from the group consisting of the first electrode and the substrate;
forming an organic semiconductor material supported by the sacrificial layer, the organic semiconductor material including first and second portions;
removing the sacrificial layer, thereby removing the first portion of the organic semiconductor material;
after removing the sacrificial layer, forming a second electrode supported by the second portion of the organic semiconductor material, thereby forming a photovoltaic cell that comprises the substrate, the first electrode, the second portion of the organic semiconductor material and the second electrode,
wherein the method is a roll-to-roll process, and the second electrode does not contact the substrate.
12. The method of claim 11 , wherein the sacrificial layer comprises one or more oils.
13. The method of claim 11 , wherein the sacrificial layer comprises a wax.
14. The method of claim 11 , wherein the sacrificial layer comprises a photoresist.
15. The method of claim 11 , wherein the sacrificial layer comprises a polymer film.
16. The method of claim 11 , wherein the method comprises forming at least two sacrificial layers during formation of the photovoltaic cell.
17. The method of claim 11 , wherein the sacrificial layer is disposed on the substrate.
18. The method of claim 11 , wherein the sacrificial layer is disposed on the first electrode.
19. The method of claim 11 , wherein the method comprises disposing a first sacrificial layer on the substrate, and disposing a second sacrificial layer on the first electrode.
20. The method of claim 11 , wherein the organic semiconductor material comprises a polymer.
21. The method of claim 20 , wherein the polymer comprises polythiophene.
22. The method of claim 21 , wherein the organic semiconductor material comprises a fullerene.
23. The method of claim 20 , wherein the organic semiconductor material comprises a fullerene.
24. The method of claim 11 , wherein the organic semiconductor material comprises a fullerene.
25. The method of claim 2 , wherein a third portion of the organic semiconductor material is supported by the second sacrificial layer.
26. The method of claim 25 , further comprising removing the second sacrificial layer, thereby removing the third portion of the organic semiconductor material.
27. The method of claim 26 , wherein the second sacrificial layer is removed before the first sacrificial layer is removed.
28. The method of claim 27 , wherein the first sacrificial layer is formed before the second sacrificial layer is formed.
29. The method of claim 28 , wherein the first electrode comprises a plurality of discrete electrodes.
30. The method of claim 1 , wherein the first electrode comprises a plurality of discrete electrodes.
31. The method of claim 2 , wherein the first electrode comprises a plurality of discrete electrodes.
32. The method of claim 1 , wherein the organic electronic component comprises a device selected from the group consisting of a photodetector, a solar cell, an electrochromic component, an OLED display, a sensor, and an electronic circuit.
33. The method of claim 1 , wherein the organic electronic component comprises a solar cell.
34. The method of claim 2 , wherein the organic electronic component comprises a device selected from the group consisting of a photodetector, a solar cell, an electrochromic component, an OLED display, a sensor, and an electronic circuit.
35. The method of claim 2 , wherein the organic electronic component comprises a solar cell.
36. The method of claim 27 , wherein the organic electronic component comprises a device selected from the group consisting of a photodetector, a solar cell, an electrochromic component, an OLED display, a sensor, and an electronic circuit.
37. The method of claim 27 , wherein the organic electronic component comprises a solar cell.
38. A method, comprising:
providing a first electrode supported by a substrate,
forming a first sacrificial layer supported by the first electrode;
forming a second sacrificial layer supported by the substrate;
forming an organic semiconductor material supported by the first sacrificial layer, the organic semiconductor material including first, second and third portions,
removing the second sacrificial layer, thereby removing the third portion of the organic semiconductor material;
removing the first sacrificial layer, thereby removing the first portion of the organic semiconductor material, and
after removing at least one of the first and second sacrificial layers, forming a second electrode supported by the second portion of the organic semiconductor material, thereby providing an organic electronic component that comprises the substrate, the first electrode, the second portion of the organic semiconductor material and the second electrode,
wherein the method comprises a roll-to-roll process, and the second electrode does not contact the substrate.
39. The method of claim 38 , wherein the organic electronic component is selected from the group consisting of a photodetector, a solar cell, an electrochromic component, an OLED display, a sensor, and an electronic circuit.
40. The method of claim 38 , wherein the organic electronic component is a solar cell.
41. The method of claim 38 , wherein the organic semiconductor material comprises a polymer.
42. The method of claim 41 , wherein the polymer comprises polythiophene.
43. The method of claim 42 , wherein the organic semiconductor material comprises a fullerene.
44. The method of claim 40 , wherein the organic semiconductor material comprises a fullerene.
45. The method of claim 38 , wherein the organic semiconductor material comprises a fullerene.
46. The method of claim 30 , wherein the second electrode comprises a plurality of discrete electrodes.
47. The method of claim 46 , wherein the organic electronic component comprises a plurality of photovoltaic cells, each photovoltaic cell comprising a discrete electrode in the first electrode, the organic semiconductor material, and a discrete electrode in the second electrode, and the discrete electrode in the first electrode of a photovoltaic cell being electrically connected to the discrete electrode in the second electrode of a neighboring photovoltaic cell.
48. The method of claim 38 , wherein the first electrode comprises a plurality of discrete electrodes and the second electrode comprises a plurality of discrete electrodes.
49. The method of claim 38 , wherein the organic electronic component comprises a plurality of photovoltaic cells, each photovoltaic cell comprising a discrete electrode in the first electrode, the organic semiconductor material, and a discrete electrode in the second electrode, and the discrete electrode in the first electrode of a photovoltaic cell being electrically connected to the discrete electrode in the second electrode of a neighboring photovoltaic cell.