Bimodal acrylate PSA for bonding low-energy and rough surfaces
View Patent ↗A Polyacrylate having an at least bimodal molecular weight distribution is disclosed. The polyacrylate is characterized by at least two maxima in the molar mass distribution curve, at points M 1 and M 2 , with M 1 >M 2 , in which, viewed formally, there are at least two polymers, P 1 and P 2 , each having its own molecular weight distribution, the polymer P 1 possessing a most frequent molar mass M max (P 1 ) and the polymer P 2 possessing a most frequent molar mass M max (P 2 ), where M max (P 1 )>M max (P 2 ), at least the polymer P 1 being based on a monomer mixture comprising at least one monomer type selected from the group of the acrylic esters and of the methacrylic esters of the general formula H 2 C═CR 1 —COOR 2 where R 1 ═H or CH 3 and where R 2 represents an aliphatic hydrocarbon chain having 4 to 15 carbon atoms; and at least one olefinically unsaturated monomer type containing functional groups, wherein the functional groups of the at least one olefinically unsaturated monomer type are groups which are able to react for a thermal crosslinking reaction, and at least the polymer P 1 has copolymerized monomers of the olefinically unsaturated monomer type containing groups that are reactive for a thermal crosslinking reaction, and is capable under the influence of thermal energy, where appropriate with addition of a catalyst, of entering into a crosslinking reaction.
1. Polyacrylate having an at least bimodal molecular weight distribution, characterized by at least two maxima in the molar mass distribution curve, at points M 1 and M 2 , with M 1 >M 2 , in which there are at least two polymers, P 1 and P 2 , each having their own molecular weight distribution, the polymer P 1 having a weight-average molecular weight in the range of from about 800,000 g/mol to 2,000,000 g/mol, and a polydispersity of between 4 to 15 and possessing a most frequent molar mass M max (P 1 ) and the polymer P 2 having a weight-average molecular weight in the range of from about 50,000 g/mol to 250,000 g/mol, and a polydispersity of between 1.3 to 10 and possessing a most frequent molar mass M max (P 2 ), where M max (P 1 )>M max (P 2 ), at least the polymer P 1 being based on a monomer mixture comprising
(a) at least one monomer type selected from the group of the acrylic esters and of the methacrylic esters of the general formula
H 2 C═CR 1 —COOR 2
where R 1 ═H or CH 3 and where R 2 represents an aliphatic hydrocarbon chain having 4 to 15 carbon atoms;
(b) at least one olefinically unsaturated monomer type containing functional group able to react for a thermal crosslinking reaction, said functional groups selected from the group consisting of hydroxyl, epoxy, amide and isocyanate, and at least the polymer P 1 has copolymerized monomers of the olefinically unsaturated monomer type containing groups that are reactive for a thermal crosslinking reaction, and is capable under the influence of thermal energy of entering into a crosslinking reaction.
2. Polyacrylate according to claim 1 , wherein polymers P 1 and P 2 are both based on a monomer mixture of the stated composition.
3. Polyacrylate according to claim 1 wherein the reactive groups are able to react with themselves.
4. Polyacrylate according to claim 1 wherein the monomer type (b) is glycidyl methacrylate.
5. Polyacrylate according to claim 1 wherein there are at least two olefinically unsaturated monomer types, (b1) and (b2), containing groups that are reactive for a thermal crosslinking reaction, the reactive groups of one monomer type (b1) being capable, under thermal activation, of reacting with the reactive groups of the second monomer type (b2).
6. Polyacrylate according to claim 1 wherein at least one tackifying resin has been admixed with a weight fraction of 0%-50% by weight, based on the polyacrylate.