Black-colored poly(arylene ether)polystyrene compositions, articles, and methods
View Patent ↗A black-colored plastic composition includes a poly(arylene ether), a polystyrene, and at least two organic dyes. The composition has a high gloss and a deep black color that is unexpectedly much more light stable that a comparable black-color plastic using a carbon black pigment. The composition is useful in the manufacture of automotive interiors, and electronic equipment including consumer electronics and particularly television bezels.
1. A black-colored thermoplastic composition, comprising:
a poly(arylene ether);
a polystyrene; and
at least two organic dyes; wherein the total concentration of the at least two organic dyes is at least 0.4 weight percent, based on the total weight of the thermoplastic composition;
wherein the composition exhibits
a 60° gloss value of at least 90 percent measured according to ASTM D523,
a CIELAB color shift, ΔE, less than or equal to 3 measured according to ASTM D2244 after 600 hours xenon arc exposure according to SAE J1885, and
a CIE lightness value, L*, less than or equal to 4 measured according to ASTM D2244 at an angle of 45° with the specular component of light excluded and using the CIE standard daylight illuminant D65,
wherein the CIE lightness value is at least 30 percent lower than a CIE lightness value of a corresponding composition in which an equal weight of carbon black has been substituted for the at least two organic dyes.
2. The black-colored thermoplastic composition of claim 1 , exhibiting at least one of
a heat deflection temperature of at least 80° C. measured according to ASTM D648 at a load of 0.455 megapascals,
a notched Izod impact strength of at least 20 Joules per meter measured according to ASTM D256 at 23° C., and
a modulus of elasticity of at about 2400 to about 3700 megapascals measured according to ASTM D638 at 23° C.
3. The black-colored thermoplastic composition of claim 1 , wherein the polystyrene is selected from the group consisting of homopolystyrene, rubber-modified polystyrene, and mixtures thereof.
4. The black-colored thermoplastic composition of claim 1 , comprising about 20 to about 80 weight percent of the poly(arylene ether) and about 20 to about 80 weight percent of the polystyrene.
5. The black-colored thermoplastic composition of claim 1 , wherein the at least two organic dyes are selected from the group consisting of anthraquinones, anthrapyridones, perylenes, anthracenes, perinones, indanthrones, quinacridones, xanthenes, thioxanthenes, oxazines, oxazolines, indigoids, thioindigoids, quinophthalones, naphthalimides, cyanines, methines, pyrazolones, lactones, coumarins, bis-benzoxazolylthiophenes, naphthalenetetracarboxylic acids, phthalocyanines, triarylmethanes, aminoketones, bis(styryl)biphenyls, azines, rhodamines, derivatives of the foregoing, and mixtures thereof.
6. The black-colored thermoplastic composition of claim 1 , comprising at least three organic dyes.
7. The black-colored thermoplastic composition of claim 1 , wherein the at least two organic dyes comprise at least one dye combination selected from the group consisting of a red dye and a green dye, a violet dye and a yellow dye, and an orange dye and a blue dye.
8. The black-colored thermoplastic composition of claim 7 , wherein the at least two organic dyes comprise at least two of the dye combinations.
9. The black-colored thermoplastic composition of claim 1 , wherein the at least two organic dyes comprise at least one dye combination selected from the group consisting of a solvent red dye and a solvent green dye, a solvent violet dye and a solvent yellow dye or disperse yellow dye, and a solvent orange dye and a solvent blue dye.
10. The black-colored thermoplastic composition of claim 9 , wherein the at least two organic dyes comprise at least two of the dye combinations.
11. The black-colored thermoplastic composition of claim 1 , wherein the composition comprises less than 0.1 weight percent of carbon black.
12. The black-colored thermoplastic composition of claim 1 , wherein the composition is free of carbon black.
13. The black-colored thermoplastic composition of claim 1 , further comprising a block copolymer of an alkenyl aromatic compound and a conjugated diene.
14. The black-colored thermoplastic composition of claim 1 , further comprising a flame retardant.
15. The black-colored thermoplastic composition of claim 1 , wherein the composition is free of inorganic filler.
16. The black-colored thermoplastic composition of claim 1 , wherein the composition is free of polycarbonate.
17. The black-colored thermoplastic composition of claim 1 , wherein the composition is free of any polymer having a refractive index less than 1.54 or greater than 1.62 measured according to ASTM D542 at 23° C.
18. The black-colored thermoplastic composition of claim 1 , wherein the composition is free of any polymer other than the poly(arylene ether), the polystyrene, and a block copolymer of an alkenyl aromatic compound and a conjugated diene.
19. A black-colored thermoplastic composition, comprising:
about 30 to about 65 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.35 to 0.5 deciliter per gram measured at 25° C. in chloroform;
about 15 to about 70 weight percent of a rubber-modified polystyrene; and
at least 0.4 weight percent total of at least four organic dyes, wherein the at least four organic dyes comprise a red dye, a green dye, a yellow dye, and a violet dye;
wherein all weight percents are based on the total weight of the thermoplastic composition; and
wherein the composition exhibits
a 60° gloss value of at least 94 percent, measured according to ASTM D523,
a CIE lightness value, L*, less than or equal to 2 measured according to ASTM D2244 at an angle of 45° with the specular component of light excluded and using the CIE standard daylight illuminant D65, wherein the CIE lightness value is at least 50 percent lower than a CIE lightness value of a corresponding composition in which an equal weight of carbon black has been substituted for the at least two organic dyes,
a CIELAB color shift, ΔE, less than or equal to 2 measured according to ASTM D2244 after 600 hours xenon arc exposure according to SAE J1885,
a heat deflection temperature of at least 80° C. measured according to ASTM D648 at a load of 0.455 megapascals,
a notched Izod impact strength of at least 20 Joules per meter, measured according to ASTM D256 at 23° C., and
a modulus of elasticity of at about 2400 to about 3700 megapascals measured according to ASTM D638 at 23° C.
20. The black-colored thermoplastic composition of claim 19 , further comprising about 25 to about 45 weight percent of a homopolystyrene.
21. The black-colored thermoplastic composition of claim 19 , wherein the at least four organic dyes further comprise a blue dye and an orange dye.
22. The black-colored thermoplastic composition of claim 19 , further comprising a flame retardant.
23. The black-colored thermoplastic composition of claim 19 , wherein the composition exhibits a CIE b* value of about −2.2 to about 0.
24. The black-colored thermoplastic composition of claim 19 , wherein the composition exhibits a pencil hardness of about HB to about 2H measured according to JIS K 56-5-4 at 23° C.
25. The black-colored thermoplastic composition of claim 19 , wherein the composition exhibits
a 60° gloss value of 94 to 105 percent, measured according to ASTM D523,
a CIE lightness value, L*, of 0.5 to 2 measured according to ASTM D2244 at an angle of 45° with the specular component of light excluded and using the CIE standard daylight illuminant D65, wherein the CIE lightness value is 50 to 95 percent lower than a CIE lightness value of a corresponding composition in which an equal weight of carbon black has been substituted for the at least two organic dyes,
a CIELAB color shift, ΔE, of 0.3 to 3 measured according to ASTM D2244 after 600 hours xenon arc exposure according to SAE J1885,
a heat deflection temperature of 80 to 120° C. measured according to ASTM D648 at a load of 0.455 megapascals, and
a notched Izod impact strength of 20 to 220 Joules per meter, measured according to ASTM D256 at 23° C.
26. The black-colored thermoplastic composition of claim 19 , wherein the composition exhibits at least one of
a flammability rating of V-0 measured according to the UL 94 Vertical Burning Test at a test sample thickness of 1.5 millimeters,
a glow wire ignition temperature (GWIT) of about 700 to about 750° C. measured according to UL 746A at a test sample thickness of 1.0 millimeter,
a glow wire ignition temperature (GWIT) of about 725 to about 775° C. measured according to UL 746A at a test sample thickness of 3.0 millimeters, and
a glow wire flammability index (GWFI) of about 930 to about 990° C. measured according to UL 746A at a test sample thickness of 1.0 millimeter.
27. A black-colored thermoplastic composition, comprising:
about 40 to about 70 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.28 to 0.38 deciliter per gram measured at 25° C. in chloroform;
about 15 to about 45 weight percent of a rubber-modified polystyrene; and
at least 0.4 weight percent of at least four organic dyes, wherein the at least four organic dyes comprise a red dye, a green dye, a yellow dye, and a violet dye;
wherein all weight percents are based on the total weight of the thermoplastic composition; and
wherein the composition exhibits
a 60° gloss value of at least 94 percent measured according to ASTM D523,
a CIE lightness value, L*, less than or equal to 2 measured according to ASTM D2244 at an angle of 45° with the specular component of light excluded and using the CIE standard daylight illuminant D65, wherein the CIE lightness value is at least 50 percent lower than a CIE lightness value of a corresponding composition in which an equal weight of carbon black has been substituted for the at least two organic dyes,
a CIELAB color shift, ΔE, less than or equal to 3 measured according to ASTM D2244 after 600 hours xenon arc exposure according to SAE J1885,
a heat deflection temperature of at least 80° C. measured according to ASTM D648 at a load of 0.455 megapascals,
a notched Izod impact strength of at least 20 Joules per meter measured according to ASTM D256 at 23° C., and
a modulus of elasticity of at about 2400 to about 3700 megapascals measured according to ASTM D638 at 23° C.
28. The black-colored thermoplastic composition of claim 27 , wherein the at least four organic dyes further comprise a blue dye and an orange dye.
29. The black-colored thermoplastic composition of claim 27 , further comprising about 10 to about 30 weight percent of a homopolystyrene.
30. The black-colored thermoplastic composition of claim 27 , further comprising a flame retardant.
31. The black-colored thermoplastic composition of claim 27 , wherein the composition exhibits a CIE b* value of about −2.2 to about 0.
32. The black-colored thermoplastic composition of claim 27 , wherein the composition exhibits a pencil hardness of about HB to about 2H measured according to JIS K 56-5-4 at 23° C.
33. The black-colored thermoplastic composition of claim 27 , wherein the composition exhibits
a 60° gloss value of 94 to 105 percent, measured according to ASTM D523,
a CIE lightness value, L*, of 0.5 to 2 measured according to ASTM D2244 at an angle of 45° with the specular component of light excluded and using the CIE standard daylight illuminant D65, wherein the CIE lightness value is 50 to 95 percent lower than a CIE lightness value of a corresponding composition in which an equal weight of carbon black has been substituted for the at least two organic dyes,
a CIELAB color shift, ΔE, of 0.3 to 3 measured according to ASTM D2244 after 600 hours xenon arc exposure according to SAE J1885,
a heat deflection temperature of 80 to 100° C. measured according to ASTM D648 at a load of 0.455 megapascals, and
a notched Izod impact strength of 20 to 100 Joules per meter, measured according to ASTM D256 at 23° C.
34. The black-colored thermoplastic composition of claim 27 , wherein the composition exhibits at least one of
a flammability rating of V-0 measured according to the UL 94 Vertical Burning Test at a test sample thickness of 1.5 millimeters,
a glow wire ignition temperature (GWIT) of about 700 to about 750° C. measured according to UL 746A at a test sample thickness of 1.0 millimeter,
a glow wire ignition temperature (GWIT) of about 725 to about 775° C. measured according to UL 746A at a test sample thickness of 3.0 millimeters, and
a glow wire flammability index (GWFI) of about 930 to about 990° C. measured according to UL 746A at a test sample thickness of 1.0 millimeter.
35. A method of preparing a black-colored thermoplastic composition, comprising:
melt-kneading a composition comprising
a poly(arylene ether),
a polystyrene, and
at least two organic dyes
to form a black-colored thermoplastic composition;
wherein the total concentration of the at least two organic dyes is at least 0.4 weight percent, based on the total weight of the black-colored thermoplastic composition; and
wherein the black-colored thermoplastic composition exhibits
a 60° gloss value of at least 90 percent, measured according to ASTM D523,
a CIELAB color shift, ΔE, less than or equal to 3 measured according to ASTM D2244 after 600 hours xenon arc exposure according to SAE J1885, and
a CIE lightness value, L*, less than or equal to 4 measured according to ASTM D2244 at an angle of 45° with the specular component of light excluded and using the CIE standard daylight illuminant D65,
wherein the CIE lightness value is at least 30 percent lower than a CIE lightness value of a corresponding composition in which an equal weight of carbon black has been substituted for the at least two organic dyes.
36. A method of preparing a black-colored thermoplastic composition, comprising:
melt-kneading a composition comprising
about 30 to about 50 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.35 to 0.5 deciliter per gram measured at 25° C. in chloroform,
about 15 to about 70 weight percent of a rubber-modified polystyrene, and
at least 0.4 weight percent total of at least four organic dyes, wherein the at least four organic dyes comprise a red dye, a green dye, a yellow dye, and a violet dye
to form a black-colored thermoplastic composition;
wherein all weight percents are based on the total weight of the black-colored thermoplastic composition; and
wherein the black-colored thermoplastic composition exhibits a 60° gloss value of at least 94 percent measured according to ASTM D523,
a CIE lightness value, L*, less than or equal to 2 measured according to ASTM D2244 at an angle of 45° with the specular component of light excluded and using the CIE standard daylight illuminant D65, wherein the CIE lightness value is at least 50 percent lower than a CIE lightness value of a corresponding composition in which an equal weight of carbon black has been substituted for the at least two organic dyes,
a CIELAB color shift, ΔE, less than or equal to 3 measured according to ASTM D2244 after 600 hours xenon arc exposure according to SAE J1885,
a heat deflection temperature of at least 80° C. measured according to ASTM D648 at a load of 0.455 megapascals,
a notched Izod impact strength of at least 20 Joules per meter, measured according to ASTM D256 at 23° C., and
a modulus of elasticity of at about 2400 to about 3700 megapascalsm megapascals measured according to ASTM D638 at 23° C.
37. A method of preparing a black-colored thermoplastic composition, comprising:
melt-kneading a composition comprising
about 40 to about 60 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.28 to 0.38 deciliter per gram measured at 25° C. in chloroform,
about 15 to about 45 weight percent of a rubber-modified polystyrene, and
at least 0.4 weight percent of at least four organic dyes, wherein the at least four organic dyes comprise a red dye, a green dye, a yellow dye, and a violet dye
to form a black-colored thermoplastic composition;
wherein all weight percents are based on the total weight of the black-colored thermoplastic composition; and
wherein the black-colored thermoplastic composition exhibits
a 60° gloss value of at least 94 percent measured according to ASTM D523,
a CIE lightness value, L*, less than or equal to 2 measured according to ASTM D2244 at an angle of 45° with the specular component of light excluded and using the CIE standard daylight illuminant D65, wherein the CIE lightness value is at least 50 percent lower than a CIE lightness value of a corresponding composition in which an equal weight of carbon black has been substituted for the at least two organic dyes,
a CIELAB color shift, ΔE, less than or equal to 3 measured according to ASTM D2244 after 600 hours xenon arc exposure according to SAE J1885,
a heat deflection temperature of at least 80° C. measured according to ASTM D648 at a load of 0.455 megapascals,
a notched Izod impact strength of at least 20 Joules per meter measured according to ASTM D256 at 23° C., and
a modulus of elasticity of at about 2400 to about 3700 megapascals measured according to ASTM D638 at 23° C.
38. An article comprising the composition of claim 1 .
39. An article comprising the composition of claim 19 .
40. An article comprising the composition of claim 27 .