Rubber part having an aluminum-based metal component and method of producing the same
View Patent ↗A rubber part having an aluminum-based metal component including the metal component, a chemical film A formed on an outer peripheral surface of the metal component which is transformable following a squeezing of the metal component, an adhesive layer B formed on an outer peripheral surface of the chemical film A, and the rubber part formed on an outer peripheral surface of the adhesive layer B. The chemical film A includes zinc fluoride, molybdenum and aluminum fluoride, in which zinc of the zinc fluoride, the molybdenum and aluminum of the aluminum fluoride are present in a content ratio of zinc/molybdenum/aluminum=4.0 to 5.5/3.0 to 5.0/0.5 to 1.5 on a mass basis.
1. A method of producing a rubber part having an aluminum-based metal component and a rubber component, said aluminum-based metal component being made of aluminum or an aluminum alloy, the method comprising steps of:
forming a chemical film A on a surface of the metal component by bringing a treatment agent into contact with the surface; and
integrating the metal component and the rubber component through the chemical film A,
the chemical film (A) comprising zinc fluoride, molybdenum and aluminum fluoride, wherein zinc of the zinc fluoride, the molybdenum and aluminum of the aluminum fluoride are present in the chemical film in a content ratio of zinc/molybdenum/aluminum=4.0 to 5.5/3.0 to 5.0/ 0.5 to 1.5 on a mass basis,
the treatment agent comprising: (a) zinc sulfate aqueous solution containing 13 to 17% by weight of zinc sulfate heptahydrate; (b) ammonium fluoride aqueous solution containing 8 to 12% by weight of ammonium fluoride; and (c) sodium molybdate aqueous solution containing 3 to 7% by weight of sodium molybdate dihydrate, which are mixed in a mass ratio of (a)/(b)/(c)=5.25 to 8.75/2.25 to 3.75/1.50 to 2.50,
the treatment agent containing 4.55 to 17.85 g/liter of zinc sulfate heptahydrate, 1.2 to 5.4 g/liter of ammonium fluoride and 0.3 to 2.1 g/liter of sodium molybdate dihydrate.
2. The method as set forth in claim 1 , wherein the metal component has a cylindrical shape, and the method further comprises a step of reducing a diameter of the cylindrical metal component after forming the chemical film A on the surface of the cylindrical metal component.
3. The method as set forth in claim 1 , wherein the treatment agent has a temperature of 50 to 60° C. and the surface of the aluminum-based metal component is kept in contact with the treatment agent for a period of 1 to 10 minutes.
4. The method as set forth in claim 3 , wherein the metal component has a cylindrical shape, and the method further comprises a step of reducing a diameter of the cylindrical metal component after forming the chemical film A on the surface of the cylindrical metal component.