Process for the production of sugar alcohols
View Patent ↗Disclosed is a method for producing polyalcohols in the form of sugar alcohols from the group comprising sorbitol and mannitol and other optional C 2 to C 6 polyols. According to said method, a monosaccharide, disaccharide, oligosaccharide, or polysaccharide containing at least one glucose unit and/or at least one fructose unit is continuously reacted with hydrogen at an elevated temperature and at a great pressure in an aqueous phase in the presence of a hydrogenating catalyst based on ruthenium or ruthenium oxide so as to obtain the inventive polyalcohols. The minimum temperature is set at 100° C. while the minimum pressure is set at 150 bar and the maximum dwell time of the reactants during catalytic hydrogenation is set at 600 s. The inventive method is particularly suitable for producing the sugar alcohols sorbitol and/or mannitol or C 2 to C 6 polyols from glucose, fructose, or disaccharides, oligosaccharides, or polysaccharides containing glucose units or fructose units, especially saccharose, practically all the used saccharides being reacted without turning into caramel. Furthermore, the yield of said sugar alcohols or C 2 to C 6 polyols is exceptionally high while the selectivity for the desired products can be varied in a simple manner within broad boundaries.
1. A method for the production of polyalcohols in the form of sugar alcohols from the group sorbitol and/or mannitol and optionally further C 6 and/or C 4 and/or C 3 and/or C 2 polyols, the method comprising the step of:
continuously reacting at least one mono-, di-, oligo- and/or polysaccharide containing at least one glucose and/or at least one fructose unit in the presence of a hydrogenating catalyst being ruthenium (Ru) and/or ruthenium oxide in aqueous phase, at elevated temperature and elevated pressure with hydrogen, to obtaining the polyols, wherein the temperature is between 120° and 280° C., the pressure at least 150 bar, and a dwell time of the reactants during catalytic hydrogenation is at most 400 s, the temperature, pressure and dwell time being adjusted to effect at least 98% educt conversion.
2. The method of claim 1 , wherein the dwell time is 5 to 360 s.
3. The method of claim 1 , wherein the pressure is at least 200 bar.
4. The method of claim 1 , wherein product proportions of the sorbitol and mannitol sugar alcohols and/or the C 6 and/or C 4 and/or C 3 and/or C 2 polyols are affected by varying the setting of at least one of the temperature, the pressure, the dwell time, and/or hydrogen or educt concentration.
5. The method of claim 1 , wherein an educt is glucose and/or fructose and/or a di-, oligo- or polysaccharide containing at least one glucose unit and also at least one fructose unit, saccharose and/or raffinose.
6. The method of claim 1 , wherein an educt concentration is between 1 and 50 mass %, based on a total flow.
7. The method of claim 1 , wherein the catalyst is mixed ruthenium/ruthenium oxide.
8. The method of claim 1 , wherein the catalyst is immobilized on at least one carrier.
9. The method of claim 8 , wherein the catalyst carrier is aluminium oxide (Al 2 O 3 ).
10. The method of claim 3 , wherein the pressure is at least 220 bar.
11. The method of claim 6 , wherein an educt concentration is between 2 and 40 mass %, based on the total flow.