Hydrocracking process
A process for hydrocracking a hydrocarbon feedstock comprising components boiling above 343° C. into a middle distillate fraction in the presence of hydrogen under hydrocracking conditions, comprising contacting the hydrocarbon feedstock in a first hydrocracking zone in the presence of one or more hydrocracking catalysts and thereafter in a second hydrocracking zone in the presence of one or more hydrocracking catalysts, and recovering a middle distillate product, wherein the entire effluent from the first hydrocracking zone is passed into the second hydrocracking zone, and at least one hydrocracking catalyst in the first hydrocracking zone comprises one or more hydrogenation components on a support comprising at least one large pore zeolite having a pore diameter in the range of 0.7-1.5 nm and at least one inorganic oxide, and at least one hydrocracking catalyst in the second hydrocracking zone comprises one or more hydrogenation component on a support comprising a beta zeolite and at least one inorganic oxide.
1. A process for hydrocracking a hydrocarbon feedstock comprising components boiling above 343° C. into a middle distillate fraction in the presence of hydrogen under hydrocracking conditions, the process comprising:
contacting the hydrocarbon feedstock in a first hydrocracking zone in the presence of one or more hydrocracking catalysts and thereafter in a second hydrocracking zone in the presence of one or more hydrocracking catalysts; and
recovering a middle distillate product, wherein the entire effluent from the first hydrocracking zone is passed into the second hydrocracking zone, and at least one hydrocracking catalyst in the first hydrocracking zone comprises one or more hydrogenation components on a support comprising at least one large pore zeolite having a pore diameter in the range of 0.7-1.5 nm and at least one inorganic oxide, and at least one hydrocracking catalyst in the second hydrocracking zone comprises one or more hydrogenation components selected from sulphides of Group VIB and VIII elements of the Periodic Table on a support comprising a beta zeolite and at least one inorganic oxide.
2. Process according to claim 1 , wherein the hydrogenation components are chosen from the group of nickel and tungsten sulphides and mixtures thereof.
3. Process according to claim 1 , wherein the large pore zeolite is Y-zeolite.
4. Process according to claim 3 , wherein the Y-zeolite is hydrothermally stabilised Y-zeolite, ultrastable Y-zeolite or Y-zeolite modified by ion exchange.
5. Process of claim 3 , wherein the Y-zeolite has a molar silica to alumina ratio greater than 10.
6. Process according to claim 1 , wherein the beta zeolite has a molar silica to alumina ratio greater than 25.
7. Process according to claim 1 , wherein the beta zeolite has a molar silica to alumina ratio greater than 250.
8. Process according to claim 1 , wherein the volume ratio of the first hydrocracking catalyst to the second hydrocracking catalyst is in the range of 80:20 to 20:80.
9. Process according to claim 3 , wherein the Y-zeolite has a unit cell constant of less than 24.35 Å.