IP Library Granted Patent US 8,821,784
Granted Patent B2
US 8,821,784 · App. 11/793,510 · Granted Sep 2, 2014

Bottles prepared from compositions of polypropylene and inorganic nucleating agents

Inventors: Valerie Smits (Lobbes, BE); Emmanuel Humbeeck (Feluy, BE); Kristien Roegiers (Wolvertem, BE)
Assignee: Total Research & Technology Feluy
C08K5/0083B29B2911/14713B29B2911/14886B29B2911/14026B29B2911/14133B29B11/14B29K2025/00B29K2023/12B29K2067/00B29C49/0005B29B2911/1404B29B11/08B29B2911/14726B29B2911/14333B29C49/12B29B2911/14693B29B2911/14033B29K2105/258B29B2911/14106B29C49/6445B29K2023/06B29B2911/1402B29B2911/1476B29C49/06B29B2911/14753B29B2911/1488B29B2911/1444B29B2911/14686B29K2027/06B29B2911/14466B29B2911/14326
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,821,784
App. No.
11/793,510
Granted
Sep 2, 2014
Kind
B2
Abstract

This invention discloses bottles and pre-forms prepared by injection-stretch-blow-molding (ISBM) from a composition comprising polypropylene and an inorganic non-sorbitol nucleating agent.

Claims (17)

1. A process for preparing bottles with a two-machine system comprising the steps of:

a. providing a composition comprising polypropylene, prepared with a Ziegler-Natta catalyst system and a non-sorbitol nucleating or clarifying agent comprising aluminum hydroxybis{2,2′-methylenebis[4,6-di(tert-butyl)phenyl]phosphate};

b. preparing a pre-form by injection moulding on a multi-cavity mould at injection temperature of 215° C.;

c. cooling the pre-form at room temperature;

d. transporting the pre-form to the blow-moulding machine;

e. re-heating the pre-form in the blow-moulding machine to a temperature of from 90 to 140° C., following a pre-determined temperature profile;

f. passing the re-heated pre-form through an equilibrium zone;

g. stretching the pre-form axially with a centre rod having a speed of 1400 to 1800 mm/s;

h. blowing the stretched pre-form radially with high-pressure air;

i. retrieving bottles having low haze values.

2. The process of claim 1 wherein the resin has a melt flow rate of from 10 to 20 dg/min.

3. The process of claim 1 wherein the amount of non-sorbitol nucleating or clarifying agent is of up to 10000 ppm.

4. The process of claim 3 wherein the amount of non-sorbitol nucleating or clarifying agent is of up to 2000 ppm.

5. The process of claim 1 wherein the polypropylene is a homo- or a co-polymer of propylene.

6. The process of claim 5 wherein the polypropylene is a copolymer of propylene, wherein the comonomer is ethylene and wherein the amount of comonomer is of up to 20 wt % based on the weight of the polymer for block copolymers.

7. The process of claim 5 wherein the polypropylene is a copolymer of propylene, wherein the comonomer is ethylene and wherein the amount of comonomer is of up to 10 wt %, preferably up to 4 wt %, based on the weight of the polymer, for random copolymers.

8. The process of claim 1 , wherein the bottle is adapted for hot-fill applications.

Assignments (2)
CHANGE OF NAME Recorded Mar 28, 2014
From: TOTAL PETROCHEMICALS RESEARCH FELUY
To: TOTAL RESEARCH & TECHNOLOGY FELUY
Reel/Frame 032553/0832 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 11, 2008
From: SMITS, VALERIE; HUMBEECK, EMMANUEL; ROEGIERS, KRISTIEN
To: TOTAL PETROCHEMICALS RESEARCH FELUY
Reel/Frame 021368/0872 →
Priority Claims (1)
EP 04106762 · Dec 21, 2004 · regional
Continuity (1)
Related Publication 20080246193A1 · Oct 9, 2008