Polypropylene resin pre-expanded particles and in-mold foamed articles prepared therefrom
View Patent ↗An object of the present invention is to provide an in-mold foamed article having good surface appearances and high rigidity produced by using a common molding machine that withstands a pressure of up to 0.4 MPa. The present invention provides polypropylene resin pre-expanded particles containing a base resin which is a resin having a melt flow rate of 5 g/10 min or more and 20 g/10 min or less and a melting point of 140° C. or higher and 155° C. or lower and satisfying the conditional formula below, and an in-mold foamed article produced from molding the pre-expanded particles: [Heat of crystal fusion (J/g)]≧1.2×[Melting point (° C.)]−96.
1. A polypropylene resin pre-expanded particle comprising a base resin that has a MFR of 5 g/10 min or more and 20 g/10 min or less and a melting point of 140° C. or higher and 155° C. or lower,
wherein the base resin is a mixture containing:
70 percent or more and 95 percent or less by weight of a polypropylene resin (A) having a MFR of 10 g/10 min or more and 30 g/10 min or less and a molecular weight distribution Mw/Mn of 6 or less, and containing 1-butene as a comonomer; and
5 percent or more and 30 percent or less by weight of a polypropylene resin (B) having a MFR of 0.1 g/10 min or more and 3 g/10 min or less, and
the base resin exhibits a relationship between a heat of crystal fusion and the resin melting point determined with a differential scanning calorimeter satisfying conditional formula (1):
[Heat of crystal fusion (J/g)]≧1.2×[Melting point (° C.)]−96 (1).
2. The polypropylene resin pre-expanded particle according to claim 1 , wherein a ratio {Qh/(Ql+Qh)}×100 of the heat at the high-temperature-side fusion peak calculated from heat of a low-temperature-side fusion peak Ql and heat of a high-temperature-side fusion peak Qh is 15% or more and 50% or less, the two fusion peaks being observed by differential scanning calorimetry.
3. An in-mold foamed article produced from the polypropylene resin pre-expanded particle according to claim 1 , wherein the article has a density of 10 kg/m 3 or more and 300 kg/m 3 or less.
4. The polypropylene resin pre-expanded particle according to claim 1 , wherein the MFR of the polypropylene resin, the polypropylene resin (A) and polypropylene resin (B) are measured with a MFR meter described in JIS-K7210, with an orifice diameter of 2.0959±0.005 mm, an orifice length of 8.000±0.025 mm, a load of 2,160 g, and a temperature of 230° C.±0.2° C.
5. The polypropylene resin pre-expanded particle according to claim 1 , wherein the polypropylene resin (B) has a MFR of 0.2 g/10 min or more and 2 g/10 min or less.