Automated Process for Performing Consecutive Reaction Involving Weighting of Material
This invention relates to an automated process for performing two or more consecutive reactions in a reaction vessel, said reaction vessel comprising an outlet at the base of said reaction vessel, and said process comprising: i) performing a first reaction is said reaction vessel, said first reaction comprising reacting one or more first reactants in the presence of a first catalyst, ii) uploading the reaction vessel of material therein through the outlet at the base of said reaction vessel and into a collecting vessel, iii) weighing the collecting vessel with the material therein, iv) calculating the mass of material collected, v) comparing the expected mass of material from the reaction to the value from step (iv), and vi) if the values correlate, subsequently performing a second reaction in said reaction vessel, said second reaction comprising reacting one or more second reactants in the presence of a second catalyst.
1 - 7 . (canceled)
8 . An automated process for performing two or more consecutive reactions in a reaction vessel, said reaction vessel comprising an outlet at the base of said reaction vessel, and said process comprising:
i) performing a first reaction is said reaction vessel, said first reaction comprising reacting one or more first reactants in the presence of a first catalyst,
ii) unloading the reaction vessel of material therein through the outlet at the base of said reaction vessel and into a collecting vessel,
iii) weighing the collecting vessel with the material therein,
iv) calculating the mass of material collected,
v) comparing the expected mass of material from the reaction to the value from step (iv), and
vi) if the values correlate, subsequently performing a second reaction in said reaction vessel, said second reaction comprising reacting one or more second reactants in the presence of a second catalyst.
9 . The process according to claim 8 , wherein the expected mass of material from the reaction and the value from step (iv) correlate if the weighed mass of material collected is from 80% to 120% of that expected.
10 . The process according to claim 8 , wherein the first and second reactions are the same type of reaction.
11 . The process according to claim 10 , wherein the first and second reactions are the same type of reaction, and one or more of the catalyst, one or more reactants or one or more other reaction variables, such as temperature, pressure or reaction time, are different for the second reaction.
12 . The process according to claim 8 , wherein the first reaction and the second reaction are polymerisation reactions, and the reaction vessel is a polymerisation reaction vessel for performing gas phase or slurry phase polymerisation reactions.
13 . The process according to claim 8 , wherein the reaction vessel is one of a plurality (an array) of high throughput reaction vessels which can operate reactions in parallel.
14 . The process according to claim 8 , wherein the reaction vessel is one of a plurality of high throughput reaction vessels for performing polymerisation reactions, and the polymer samples from the (each) reaction vessel are generally less than 50 g (washed and dried weight), and more typically less than 25 g. such as in the range 2-25 g, preferably in the range 10-20.