Organic recycling with metal addition
View Patent ↗The invention is directed to methods for producing a granular nitrogen fertilizer from an organic material comprising adding a metallic salt to said organic material to form a slurry. Preferably the organic material comprises dewatered biosolids and contains water from a scrubber. Metallic salts that can be used comprise a salt of iron, zinc, or a mixture thereof. Preferred iron salts comprises ferric sulfate or ferric oxide, and preferred zinc salts comprises zinc sulfate or zinc oxide. Preferably, the metallic salt is mixed with an acid such as sulfuric acid to form an acidified metal salt. Slurry pH ranges from approximately 2-2.5. The acidified metal salt is added to the organic material in sufficient quantity to lower viscosity of the slurry such that the resulting fluid does not hinder fluid flow during operation. When the metallic salt comprises acidified ferric sulfate or ferrous sulfate, sufficient iron can be present to produce a fertilizer product with 0.1 weight percent to 10 weight percent iron sulfate calculated on a dry weight basis. The invention is also directed to fertilizer products made by the methods of the invention. Preferred products are granules and the metallic salt increases product hardness. Fertilizer granules preferably contain metal that is bioavailable to a plant when used as a fertilizer. Solubility of the metal of the product in water is enhanced, and the product is low staining.
1. A process for preparing conditioned biosolids for use in producing fertilizer, the process comprising:
introducing biosolids into a receiving bin;
conveying the biosolids to a pump;
introducing a combination of sulfuric acid and an iron oxide having a pH of about 2 to about 2.5 into the biosolids to create a mixture;
pumping said mixture to a shear mix tank;
introducing sulfuric acid into the mixture; and
shear mixing the mixture to form conditioned biosolids, wherein the pH of the conditioned biosolids is 3 to 4.
2. A process according to claim 1 further comprising passing the biosolids through a lump breaker prior to pumping the mixture.
3. A process according to claim 2 further comprising introducing water into the biosolids prior to passing through the lump breaker.
4. A process according to claim 1 , wherein the sulfuric acid is introduced into the mixture at a rate of about 1.75% by weight of the mixture.
5. A process according to claim 1 , wherein the iron oxide is ferrous oxide.
6. A process according to claim 1 , wherein the iron oxide is ferric oxide.
7. A process for creating fertilizer comprising:
mixing biosolids with a combination of sulfuric acid and an iron oxide having a pH of about 2 to about 2.5 to create a mixture;
pumping said mixture to a shear mix tank;
introducing sulfuric acid into the mixture; and
shear mixing the mixture to form conditioned biosolids, wherein the pH of the conditioned biosolids is 3 to 4;
mixing the conditioned biosolids, an acid and a base in a pipe cross reactor to form a hot melt;
processing the hot melt in a granulator to form granulated particles; and
drying the granulated particles to form granules of fertilizer, wherein the granules have a hardness greater than about 6 pounds.
8. A process according to claim 7 , wherein the acid comprises sulfuric acid and the base comprises ammonia.