Staged addition of non-fluorinated anionic surfactant to reduced fluorosurfactant fluoropolymer dispersion
View Patent ↗A process for reducing fluorosurfactant content of a fluorosurfactant-containing aqueous fluoropolymer dispersion stabilized with nonionic surfactant. The process includes reducing the fluorosurfactant content of the stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion to a predetermined level to provide a reduced surfactant dispersion, adding non-fluorinated anionic surfactant to the reduced fluorosurfactant dispersion, and concentrating the reduced fluorosurfactant dispersion. The non-fluorinated anionic surfactant is added in stages wherein a first portion is added to the dispersion prior to concentrating and a second portion of the non-fluorinated anionic surfactant is added to the dispersion after concentrating.
1. A process for reducing fluorosurfactant content of a fluorosurfactant-containing aqueous fluoropolymer dispersion stabilized with nonionic surfactant comprising:
reducing the fluorosurfactant content of said stabilized fluorosurfactant—containing aqueous fluoropolymer dispersion to provide a reduced surfactant dispersion;
adding non-fluorinated anionic surfactant to said reduced fluorosurfactant dispersion; and
concentrating said reduced fluorosurfactant dispersion by heating to a temperature within an operable temperature range for the nonionic surfactant at an operable surfactant level range which causes the dispersion to separate into upper and lower phases and recovering the lower phase as concentrated dispersion;
a first portion of said non-fluorinated anionic surfactant being added to said dispersion prior to concentrating in an amount sufficient to increase said operable temperature range, said operable surfactant level range or both during concentration; and
a second portion of said non-fluorinated anionic surfactant being added to said dispersion after said concentrating in an amount sufficient to control viscosity.
2. The process of claim 1 wherein said first portion of non-fluorinated anionic surfactant is added in an amount of about 20 to about 500 ppm based on weight of said dispersion.
3. The process of claim 1 wherein said first portion of non-fluorinated anionic surfactant is added in an amount of about 30 to about 400 ppm based on weight of said dispersion.
4. The process of claim 1 wherein the addition of said first portion of non-fluorinated anionic surfactant increases said operable temperature range by at least about 3° C.
5. The process of claim 1 wherein said second portion of non-fluorinated anionic surfactant is added in an amount sufficient to decrease viscosity to less than 30 cps at room temperature.
6. The process of claim 1 wherein said second portion of non-fluorinated anionic surfactant is added in an amount sufficient to provide a Needle Skinning Test value (NST) of no greater than 1.
7. The process of claim 1 wherein said second portion of non-fluorinated anionic surfactant is added in an amount which combined with said first portion provides a total non-fluorinated anionic surfactant content in said dispersion of about 30 to about 500 ppm based on weight of said dispersion.
8. The process of claim 1 wherein said stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion has a solids content of about 15 to about 60 wt %.
9. The process of claim 1 wherein said stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion has a solids content of about 25 to about 55 wt %.
10. The process of claim 1 wherein said stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion has a solids content of about 35 to about 50 wt %.
11. The process of claim 1 wherein said concentrating produces a dispersion having a solids content of about 25 to about 70 wt %.
12. The process of claim 1 wherein said nonionic surfactant is present in said fluorosurfactant-containing dispersion an amount of about 1 to about 5% based the weight of the dispersion.
13. The process of claim 1 wherein said reducing the fluorosurfactant content of said stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion comprises:
contacting said stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with an anion exchange resin; and
separating said anion exchange resin from said dispersion after the fluorosurfactant content has been reduced.
14. The process of claim 13 wherein said contacting said stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with anion exchange resin reduces fluorosurfactant content to less than about 300 ppm.
15. The process of claim 13 wherein said contacting said stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with anion exchange resin reduces fluorosurfactant content to less than about 100 ppm.
16. The process of claim 13 wherein said contacting said stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with anion exchange resin reduces fluorosurfactant content to less than about 50 ppm.