Composition for a desulfurizer with a high sulfur capacity and the process of making the same
View Patent ↗The present invention discloses a composition for a desulfurizer with a high sulfur capacity and a process for making the same. The composition comprises the active components of three kinds of iron oxides and is used in the desulfurizer to remove hydrogen sulfide from the gaseous and liquid state feed stocks. The process for preparing the composition comprises the following steps: (1) mixing a solid ferrous compound with a solid hydroxide at a molar ratio of iron to hydroxyl being in the range from 1:2 to 1:3; (2) kneading the mixture feeds obtained in step (1) and making them react completely; (3) drying the products obtained in step (2) in the air; (4) washing and filtering the feeds obtained in the step (3); (5) naturally drying or baking the solids obtained in step (4) to form a composition for a desulfurizer with a high sulfur capacity.
1. A process for preparing a composition for a desulfurizer, wherein the composition comprises three kinds of iron oxides which are ferroferric oxide in the form of cubic crystalline phase (Fe 3 O 4 ), amorphous ferric oxide (Fe 2 O 3 ) and amorphous ferric oxide monohydrate (Fe 2 O 3 .H 2 O), wherein the contents of the iron oxides in said composition are: 3.0 wt % to 3.5 wt % of Fe 3 O 4 , 28 wt % to 30 wt % of Fe 2 O 3 , 60 wt % to 62 wt % of Fe 2 O 3 .H 2 O, the balance being water and residual by-products of this reaction, the above percentages are based on the total weight of said compositions, the process comprising the following steps:
(1) mixing a solid ferrous compound with a solid hydroxide at a molar ratio of iron to hydroxyl in the range from 1:2 to 1:3;
(2) kneading the mixture feeds obtained in step (1) and making them react completely;
(3) drying the products obtained in step (2) in the air;
(4) washing and filtering the feeds obtained instep (3); and
(5) drying at ambient temperature or baking the solids obtained in step (4) to form the composition for a desulfurizer.
2. The process for preparing the composition according to claim 1 , characterized in that said solid ferrous compound in step (1) is selected from ferrous sulfate (FeSO 4 ), ferrous nitrate (Fe(NO 3 ) 2 ) or ferrous chloride (FeCl 2 ), and said solid hydroxide is selected from sodium hydroxide (NaOH), potassium hydroxide (KOH) or calcium hydroxide (Ca(OH) 2 ).
3. The process for preparing the composition according to claim 2 , characterized in that said solid ferrous compound is ferrous sulfate (FeSO 4 ), and said solid hydroxide is sodium hydroxide (NaOH).
4. The process for preparing the composition according to claim 1 , characterized in that said kneading in step (2) is accomplished with a kneader, and the kneading time for the completion of the reaction is at least 15 minutes.
5. The process for preparing the active components based on claim 4 , characterized in that said kneading is accomplished with a kneader, and the kneading time for the completion of the reaction is in the range from 15 minutes to 30 minutes.
6. The process for preparing the composition according to claim 1 , characterized in that the drying in step (5) is drying at a temperature of between 5° C. and 45° C.
7. The process for preparing the composition according to claim 1 , characterized in that the drying in step (5) is baking, and the baking temperature is at most 90° C.
8. The process for preparing the composition according to claim 7 , characterized in that the baking temperature in step (5) is between 70° C. and 90° C.