Method of making heat treated coated article using diamond-like carbon (DLC) coating and protective film
View Patent ↗There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. The method may include heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) or other type of carbon, with a protective film thereon. In certain example embodiments, the protective film may be of or include a layer of or including SnO x prior to HT. Optionally, a release layer of a material such as zinc oxide may be provided between the SnO x and the DLC. Following and/or during heat treatment the SnO x transforms into SnO y (y>x) so that stress is created due to the SnO x to SnO y transition. Then, during quenching, stress relief may occur which causes the layer to buckle, creating cracks which may act as liquid channels that permit the sacrificial film to be easily removed via washing or the like.
1. A method of making a heat treated coated article, the method comprising:
providing a glass substrate;
forming at least a layer comprising carbon on the glass substrate;
forming a protective film on the glass substrate over at least the layer comprising carbon, the protective film including a layer comprising SnO x , where x is from about 0.75 to 1.5, and a layer comprising substoichiometric zinc oxide ZnO t where t is from 0.1 to 0.8, wherein in the protective film the layer comprising zinc oxide ZnO t is located between and contacting the layer comprising carbon and the layer comprising SnO x ;
heat treating the glass substrate with the layer comprising carbon and the protective film thereon so that during the heat treating the protective film prevents significant burnoff of the layer comprising carbon, wherein the heat treating comprises heating the glass substrate to temperature(s) sufficient for thermal tempering, heat strengthening, and/or heat bending;
wherein during the heat treating the layer comprising SnO x transforms into a layer comprising SnO y , where y is from about 1.6 to 2.2, wherein y is greater than x; and
exposing the protective film to a release liquid and removing at least part of the protective film after said heat treating.
2. The method of claim 1 , further comprising quenching the glass substrate with the layer comprising carbon and the protective film thereon after said heat treating, said quenching comprising using at least cool air and/or cool liquid to quench the glass substrate.
3. The method of claim 1 , wherein x is from about 0.8 to 1.3.
4. The method of claim 1 , wherein x is from about 0.9 to 1.2.
5. A method of making a heat treated coated article, the method comprising:
having a coated article comprising a glass substrate, at least one layer comprising diamond-like carbon (DLC) on the glass substrate, a protective film on the glass substrate over at least the layer comprising DLC, the protective film including a layer comprising SnO x where x is from about 0.75 to 1.5, and a layer comprising substoichiometric zinc oxide ZnO t where t is no greater than 0.9, the layer comprising zinc oxide ZnO t located between and contacting the layer comprising DLC and the layer comprising SnO x ;
heat treating said coated article so that during the heat treating the protective film prevents significant burnoff of the layer comprising DLC, wherein the heat treating comprises heating the glass substrate to temperature(s) sufficient for thermal tempering, heat strengthening, and/or heat bending;
wherein during the heat treating the layer comprising SnO x transforms into a layer comprising SnO y where y is from about 1.6 to 2.2, and wherein y is greater than x; and
exposing the protective film to a release liquid and removing at least part of the protective film after said heat treating.
6. The method of claim 5 , further comprising quenching the glass substrate with the layer comprising DLC and the protective film thereon after said heat treating, said quenching comprising using at least cool air and/or cool liquid to quench the glass substrate.
7. The method of claim 5 , wherein x is from about 0.8 to 1.3.
8. The method of claim 5 , wherein x is from about 0.9 to 1.2.
9. The method of claim 5 , wherein y is from about 1.7 to 2.1.
10. The method of claim 5 , wherein y is from about 1.9 to 2.05.
11. The method of claim 5 , wherein t is from about 0.1 to 0.8.
12. The method of claim 5 , further comprising forming the layer comprising DLC via an ion beam.
13. The method of claim 5 , further comprising forming the protective film via sputtering.
14. The method of claim 5 , further comprising forming a barrier layer comprising silicon oxide and/or silicon nitride so as to be located between at least the glass substrate and the layer comprising DLC.
15. The method of claim 5 , wherein the heat treating comprises heating the glass substrate with the layer comprising DLC and the protective film thereon using at least temperature(s) of at least 550 degrees C.
16. The method of claim 5 , wherein the layer comprising DLC comprises amorphous DLC and has more sp 3 carbon-carbon bonds than sp 2 carbon-carbon bonds.
17. The method of claim 5 , wherein the layer comprising DLC has an average hardness of at least 10 GPa.
18. The method of claim 5 , wherein the layer comprising DLC has a density of at least about 2.7 gm/cm 3 .
19. The method of claim 5 , wherein the layer comprising DLC is hydrogenated.
20. The method of claim 5 , wherein the coated article is substantially transparent and is used as a shower door.
21. The method of claim 5 , wherein after said removing step at least part of the layer comprising DLC is exposed so as to be an outermost layer of the coated article.