Catalyst for polyester polycondensation and method for producing polyester resin using the same
View Patent ↗The invention provides: a polycondensation catalyst for polyester production, which contains titanium atoms, alkaline earth metal atoms and phosphorus atoms, has high reactivity and excellent long-term storage stability, can be easily produced industrially, and has an advantage in cost; a polyester resin obtained with the catalyst; and a molded article. These are: a polymerization catalyst for polyester production containing titanium atoms, alkaline earth metal atoms and phosphorus atoms and having a specific constitution; a polyester resin obtained with the catalyst; and a molded article.
1. A polycondensation catalyst comprising one or more titanium atoms, one or more alkaline earth metal atoms, one or more phosphorus atoms, and one or more carbon atoms, said polycondensation catalyst obtained by a process comprising
forming a mixture comprising at least one monohydric alcohol, at least one titanium compound, at least one alkaline earth metal compound and at least one acid phosphoric ester compound, and
concentrating the mixture,
wherein
at least part of the carbon atoms are derived from an aliphatic carboxylic acid and/or an aliphatic carboxylate which is derived from an aliphatic carboxylic acid salt of the one or more alkaline earth metal atoms,
the content of the titanium atoms T (on weight basis) is 4-20% by weight of the polycondensation catalyst,
the content of the aliphatic carboxylic acid and/or the aliphatic carboxylate L (on mole basis), the content of the alkaline earth metal atoms M (on mole basis), the content of the titanium atoms T (on weight basis), the content of the phosphorus atoms P (on mole basis), and the content of the carbon atoms C (on weight basis) satisfy expressions (1), (2), and (3):
0.8 ≦L/M (molar ratio)≦1.8 (1)
0.05 ≦T/C (weight ratio)≦0.50 (2)
0.5 ≦M/P (molar ratio)≦3.0 (3); and
with the proviso that the at least one titanium compound has not been previously treated with an aromatic polycarboxylic acid, and
wherein, when the polycondensation catalyst is dissolved in ethylene glycol, the titanium atoms are present in a concentration of 10,000 ppm to 100,000 ppm.
2. The polycondensation catalyst according to claim 1 , wherein a ratio (W 1 /W 0 ) of the weight (W 1 ) of the polycondensation catalyst to the total weight (W 0 ) of the mixture of the at least one titanium compound, the at least one alkaline earth metal compound and the at least one acid phosphoric ester compound is from 0.45 to 0.85.
3. The polycondensation catalyst according to claim 1 , wherein the at least one alkaline earth metal compound is an organic acid salt of an alkaline earth metal and/or a hydrate of the salt.
4. The polycondensation catalyst according to claim 1 , comprising a basic structure represented by formula (III)
wherein T is a titanium atom, M is an alkaline earth metal atom, O is an oxygen atom, P is a phosphorus atom, R 1 is an alkyl group having 1-6 carbon atoms, a cyclohexyl group, an aryl group, or a 2-hydroxyethyl group, and R 2 is an alkyl group having 1-3 carbon atoms.
5. The polycondensation catalyst according to claim 1 , wherein said catalyst is solid.
6. The polycondensation catalyst according to claim 1 , wherein the monohydric alcohol is ethanol.