Acetaldehyde scavenger in polyester articles
View Patent ↗A polymer composition is disclosed for containers for beverages, films and sheets for food. The composition comprises (a) polyester, (b) an acetaldehyde scavenger, (c) an acid absorber, and (d) an antioxidant. The acetaldehyde scavenger is characterized as small molecules, such as anthranilamide, that include at least two hydrogen-substituted heteroatoms bonded to carbons of the organic additive compound such that the organic additive compound is reactive with acetaldehyde in the polyester to form water and a resulting organic compound comprising an unbridged 5- or 6-member ring including the at least two heteroatoms. The acid absorber is a hydrotalcite-like composition. The polymer compound can be concentrated in a masterbatch or fully let-down. Optional ingredients include colorants, and optical brighteners. Discoloration of the polyester is reduced during the performance of acetaldehyde scavenging.
1. A polymer compound, comprising:
(a) carrier
(b) an acetaldehyde scavenger,
(c) an acid absorber, and
(d) an antioxidant.
2. The compound of claim 1 , wherein the antioxidant is a phenolic antioxidant.
3. The compound of claim 1 , further comprising (e) a blue colorant.
4. The compound of claim 1 , further comprising (f) an optical brightener.
5. The compound of claim 1 , wherein
the carrier is present in an amount ranging from about 20 to about 98 weight percent;
the acetaldehyde scavenger is present in an amount ranging from about 1 to about 52 weight percent;
the acid absorber is present in an amount ranging from about 0.1 to about 13 weight percent, and
the antioxidant is present in amount ranging from about 0.1 to about 13 weight percent,
wherein all weight percents are to the total weight of the compound, and wherein the compound is a masterbatch.
6. The compound of claim 1 , wherein
the carrier includes polyester and is present in an amount ranging from about 95 to about 98 weight percent;
the acetaldehyde scavenger is present in an amount ranging from about 0.01 to about 1 weight percent;
the acid absorber is present in an amount ranging from about 0.005 to about 1.5 weight percent, and
the antioxidant is present in amount ranging from about 0.005 to about 1.5 weight percent,
wherein all weight percents are to the total weight of the compound, and wherein the compound is a let-down compound suitable for molding or extruding into a polymer article.
7. An article made from a compound of claim 1 , wherein the article is selected from the group consisting of a polymeric pre-form, a beverage container, a film, and a sheet.
8. The article of claim 7 , wherein the article is a beverage container.
9. The article of claim 7 wherein the article is a polymeric pre-form.
10. The article of claim 7 , wherein the antioxidant in the compound is a phenolic antioxidant.
11. The article of claim 7 , wherein the compound further comprises (e) a blue colorant.
12. The article of claim 7 , wherein the compound further comprises (f) an optical brightener.
13. The article of claim 7 , wherein, in the compound,
the carrier includes polyester and is present in an amount ranging from about 95 to about 98 weight percent;
the acetaldehyde scavenger is present in an amount ranging from about 0.01 to about 1 weight percent;
the acid absorber is present in an amount ranging from about 0.005 to about 1.5 weight percent, and
the antioxidant is present in amount ranging from about 0.005 to about 1.5 weight percent,
wherein all weight percents are to the total weight of the compound.
14. A method for scavenging acetaldehyde from polyester while minimizing discoloration of the polyester, comprising forming an article using a compound of claim 1 .
15. The method of claim 14 , wherein the antioxidant in the compound is a phenolic antioxidant.
16. The method of claim 14 , wherein the compound further comprises (e) a blue colorant.
17. The method of claim 14 , wherein the compound further comprises (f) an optical brightener.
18. The method of claim 14 , wherein, in the compound,
the carrier includes polyester and is present in an amount ranging from about 95 to about 98 weight percent;
the acetaldehyde scavenger is present in an amount ranging from about 0.01 to about 1 weight percent;
the acid absorber is present in an amount ranging from about 0.005 to about 1.5 weight percent, and
the antioxidant is present in amount ranging from about 0.005 to about 1.5 weight percent,
wherein all weight percents are to the total weight of the compound.