Electroluminescent device with iridium complex
View Patent ↗An iridium complex Ir(III)L 1L2L3 for emitting light with a central iridium ion Ir(III), with a ligand L3 as dionate from the group comprising pentane-2,4-dionate (acac), 2,2,6,6-tetramethyl-3,5-heptandionate (thd), 7,7-dimethyl-1,1,1,2,2,3,3-heptyfluoro-4,6-octandionate (fod), 4,4,4-trifluorol-(2-thienyl)butane-1,3-dionate (ttfa), 1,3-diphenylpropane-1,3-dionate (dbm), 4,4,4-trifluoro-1-(2-naphthyl)butane-1,3-dionate (tfnb) or 4,4,4-trifluoro-1-(1-naphthyl)butane-1,3-dionate and with two rigid aromatic ligands L1 and L2 with one nitrogen and one carbon atom, sharing in the ligand bond, preferably dibenzo[f,h]chinoline, benzo[h]chinoline or 5,6-dihydro-benzo[h]chinoline, characterized in that the iridium complex Ir(III)L1L2L3 is a first isomer (71), in which the nitrogen atom of the ligand L1 sharing in the ligand bonding and the nitrogen atom of the ligand L2 sharing in the ligand bonding are juxtaposed relative to the central iridium ion. The invention further relates to a method for the separation of the first isomer (71,81) of the iridium complexes ( 7,8 ) and an electroluminescent device with an electroluminescent layer ( 4 ) comprising light-emitting materials, wherein the component of the first isomer (71,81) in the total quantity of the light-emitting materials is greater than 90%, preferably greater than 95%.
1. An electroluminescent device with an organic electroluminescent layer comprising a light-emitting material including a first isomer of an iridium complex in a quantity higher than 90%, in relation to the total quantity of the light-emitting material, wherein the iridium complex comprises an iridium complex Ir(III)L1L2L3 for emitting light with a central iridium ion Ir(III), with a ligand L3 as a dionate selected from the group consisting of: pentane-2,4-dionate (acac), 2,2,6,6-tetramethyl-3,5-heptandionate (thd), 7,7-dimethy-1,1,1,2,2,3,3-heptyfluoro-4,6-octandionate (fod), 4,4,4-trifluorol-(2-thienyl)butane-1,3-dionate (ttfa), 1,3-diphenylpropane-1,3- dionate (dbm), 4,4,4-trifluoro-1-(2-naphthyl)butane-1,3-dionate (tfnb) or 4,4,4-trifluoro-1-(1-naphthyl)butane-1,3-dionate and with two rigid aromatic ligands L1 and L2 with one nitrogen and carbon atom, sharing in the ligand bond, each, wherein the iridium complex Ir(III)L1L2L3 is present as a first isomer, in which the nitrogen atom of the ligand L1 sharing in the ligand bonding and the nitrogen atom of the ligand L2 sharing in the ligand bonding are juxtaposed relative to the central iridium ion, wherein
L1 an L2 are dibenzo[f,h] chinoline and L3 is pentane-2,4-dionate (acac).
2. An electroluminescent device as claimed in claim 1 , wherein light-emitting material is embedded in a hole- and electron-conducting matrix material, wherein the first isomers (71,81) of an iridium complex have a weight component between 1 wt. % and 50 wt. % relative to the matrix material.