Assemblies of anisotropic nanoparticles
A composition of matter, includes a plurality of anisotropic nanoparticles that are in physical contact with one another, each of the plurality of anisotropic nanoparticles having a) a first dimension that is substantially different than both a second dimension and a third dimension and b) a non-random nanoparticle crystallographic orientation that is substantially aligned with the first direction. The plurality a anisotropic nanoparticles are substantially aligned with respect to each other to define a substantially close packed dense layer having a non-random shared crystallographic orientation that is substantially aligned with a basal plane of the substantially close packed dense layer. The plurality of anisotropic nanoparticles includes a member selected from the group consisting of (In,Ga) y (S,Se) 1-y , an In 2 Se 3 stable wurtzite structure that defines a hexagonal rod nanoparticle, Cu x (Se) 1-x and Cu(In,Ga) y (S,Se) 1-y .
1. A composition of matter, comprising:
a plurality of anisotropic nanoparticles that are in physical contact with one another, wherein the plurality of nanoparticles includes a member selected from the group consisting of (In,Ga) y (S.Se) 1-y , an In 2 Se 3 stable wurtzite structure that defines a hexagonal rod nanoparticle, Cu x (Se) 1-x , and Cu(In,Ga) 1-y (S,Se) 1-y , each of the plurality of anisotropic nanoparticles having a) a first dimension that is substantially different than both a second dimension and a third dimension and b) a non-random nanoparticle crystallographic orientation that is substantially aligned with the first dimension,
wherein the plurality of anisotropic nanoparticles are substantially aligned with respect to each other to define a substantially close packed dense layer having a non-random shared crystallographic orientation that is substantially aligned with a basal plane of the substantially close packed dense layer,
wherein the plurality of anisotropic nanoparticles are arranged to define an order having one-dimensional translational periodicity and a rotational symmetry selected from the group consisting of 8-fold, 10-fold and 12-fold with respect to a normal to the basal plane of the substantially close packed dense layer.
2. The composition of matter of claim 1 , wherein the substantially close packed dense layer is characterized by a packing factor that is within at least 10% of a maximum packing factor.
3. The composition of matter of claim 1 , further comprising a plurality of isotropic nanoparticles coupled to the plurality of anisotropic nanoparticles.
4. The composition of matter of claim 1 , wherein each of the plurality of anisotropic nanoparticles defines a platelet a) having an aspect ratio of less than approximately 0.20 and b) defining a principle plane that is substantially parallel to the basal plane.
5. The composition of matter of claim 1 , wherein the plurality of anisotropic nanoparticles includes a first set of anisotropic nanoparticles and a second set of anisotropic nanoparticles, wherein the first set of anisotropic nanoparticles and the second set of anisotropic nanoparticles are different from one another with regard to at least one state variable selected from the group consisting of principle plane plan, minor plane profile, impurity presence, electrostatic edge charge, electrostatic surface charge, edge acidity, surface acidity, edge hydrophilicity and surface hydrophilicity.
6. The composition of matter of claim 1 , wherein the rotational symmetry is 10-fold with respect to a normal to the basal plane of the substantially close packed dense layer, the one-dimensional translational periodicity is perpendicular to the basal plane, and the plurality of anisotropic nanoparticles are ordered with respect to basal spatial location on a scale that is substantially a multiple of approximately five nanometers.
7. The composition of matter of claim 1 , wherein the plurality of anisotropic nanoparticles are arranged to define an order having three-dimensional translational periodicity and a rotational symmetry selected from the group consisting of 4-fold and 6-fold, with respect to a normal to the basal plane of the substantially close packed dense layer.
8. The composition of matter of claim 1 , wherein each of the plurality of anisotropic nanoparticles includes (In,Ga) y (S,Se) 1-y .
9. The composition of claim 8 , wherein each of the plurality of anisotropic nanoparticles includes an In 2 Se 3 stable wurtzite structure that defines a hexagonal rod nanoparticle.
10. The composition of matter of claim 1 , wherein each of the plurality of anisotropic nanoparticles includes Cu x (Se) 1-x .
11. The composition of matter of claim 1 , wherein each of the plurality of anisotropic nanoparticles includes Cu(In,Ga) y (S,Se) 1-y .
12. The composition of matter of claim 1 , wherein the plurality of anisotropic nanoparticles include an impurity and have a local impurity concentration by volume of no more than 25% different than an average impurity concentration by volume with respect to the substantially close packed dense layer.
13. The composition of matter of claim 12 , wherein the local impurity concentration is sodium per unit volume.
14. The composition of matter of claim 1 , further comprising a substrate coupled to the substantially close packed dense layer.
15. The composition of matter of claim 1 , wherein the plurality of anisotropic nanoparticles are fused.
16. The composition of matter of claim 1 , wherein the plurality of anisotropic nanoparticles are recrystallized.