IP Library Granted Patent US 7,493,800
Granted Patent B2
US 7,493,800 · App. 11/823,188 · Granted Feb 24, 2009

Sampling method

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Quick Facts
Patent No.
US 7,493,800
App. No.
11/823,188
Granted
Feb 24, 2009
Kind
B2
Abstract

A method for sampling a host liquid in a vessel to detect the presence of an undesired liquid in the host liquid and removing host liquid that contains undesired liquid from the vessel, wherein an electrical capacitance probe is employed to detect the presence of the undesired liquid, and the liquid that is passed by the capacitance probe is fed to an incinerator.

Claims (7)

1. In a method for detecting the presence of at least one undesired liquid in a host liquid in a collection vessel for said host liquid, said vessel having in a lower part thereof at least one sump having an interior in fluid communication with said collection vessel, said at least one sump having at least one drain line that has an open interior in fluid communication with said at least one sump interior, the improvement comprising providing at least one electrical capacitance probe in communication with said at least one drain line interior, said probe having a set point for indicating essentially pure host liquid, employing a first valve in said at least one drain line upstream of and close to said probe, employing a second valve in said at least one drain line downstream of said probe, initially closing both said first and second valves so that said at least one drain line downstream of said first valve contains vapor and is empty of said host liquid, opening said first valve and cracking said second valve to remove said vapor from said at least one drain line downstream of said first valve until said host liquid is in communication with said probe and said host liquid fills said at least one drain line downstream of said first valve and upstream of said second valve at which time said second valve is closed, if no undesired liquid is detected by said probe keeping said first valve closed and opening said second valve, if undesired liquid is detected by said probe leaving said first and second valves open until no undesired liquid is detected by said probe at which time said first valve is closed, and passing said host liquid and any other of said liquid drained from said sump to a combustor to incinerate same, whereby a minimal amount of said host liquid that is free of said undesired liquid is passed to said combustor.

2. The method of claim 1 wherein said undesired liquid is at least water.

3. The method of claim 1 wherein said combustor is at least one incinerating flare.

4. The method of claim 1 wherein said host liquid is at least one hydrocarbon.

5. The method of claim 4 wherein said vessel is a holding tank in an ethylene polymerization plant that employs a hydrocarbon as the solvent in the ethylene polymerization step, said host liquid is said hydrocarbon solvent, said undesired liquid is water, and said combustor is a flare.

6. The method of claim 5 wherein said host liquid is at least one of n-hexane and cyclohexane.

7. The method of claim 5 wherein said ethylene polymerization plant employs a solution phase polymerizing process to produce high density polyethylene.

Assignments (19)
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032112/0786 →
APPOINTMENT OF SUCCESSOR ADMINISTRATIVE AGENT Recorded Jan 22, 2014
From: UBS AG, STAMFORD BRANCH
To: BANK OF AMERICA, N.A.
Reel/Frame 032112/0863 →
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: CITIBANK, N.A.
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032113/0644 →
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: DEUTSCHE BANK TRUST COMPANY AMERICAS
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032113/0684 →
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: BANK OF AMERICA, N.A.
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032113/0730 →
SECURITY AGREEMENT Recorded May 19, 2010
From: EQUISTAR CHEMICALS, LP
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 024402/0655 →
SECURITY AGREEMENT Recorded May 18, 2010
From: EQUISTAR CHEMICALS, LP
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 024397/0861 →
SECURITY AGREEMENT Recorded May 7, 2010
From: EQUISTAR CHEMICALS. LP
To: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
Reel/Frame 024351/0001 →
SECURITY AGREEMENT Recorded May 6, 2010
From: EQUISTAR CHEMICALS, LP
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
Reel/Frame 024342/0443 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0856 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0705 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0157 →
RELEASE OF SECURITY INTEREST Recorded May 4, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, LP; EQUISTAR CHEMICALS, LP
Reel/Frame 024329/0581 →
SECURITY AGREEMENT Recorded Oct 30, 2009
From: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
To: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
Reel/Frame 023438/0965 →
CORRECTIVE ASSIGNMENT TO CORRECT THE CONVEYING AND RECEIVING PARTIES, PREVIOUSLY RECORDED ON REEL 022542 FRAME 0295. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT. Recorded May 5, 2009
From: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT AND COLLATERAL AGENT
Reel/Frame 022634/0251 →
SECURITY AGREEMENT Recorded Apr 14, 2009
From: CITIBANK, N.A., AS ADMINISTRATIVE AGENT AND COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP; HOUSTON REFINING LP; BASELL USA INC.; MILLENNIUM CHEMICALS INC.; MILLENNIUM PETROCHEMICALS INC.
Reel/Frame 022542/0295 →
SECURITY AGREEMENT Recorded Aug 4, 2008
From: BASELL POLYOLEFINE GMBH; ARCO CHEMICAL TECHNOLOGY L.P.; ARCO CHEMICAL TECHNOLOGY, INC.; ATLANTIC RICHFIELD COMPANY; BASELL NORTH AMERICA, INC.; BASELL POLYOLEFIN GMBH; LYONDELL CHEMICAL COMPANY; EQUISTAR CHEMICALS, L.P.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 021354/0708 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS AND PATENT APPLICATIONS Recorded Mar 26, 2008
From: BASELL POLYOLEFINE GMBH; ARCO CHEMICAL TECHNOLOGY L.P.; ARCO CHEMICAL TECHNOLOGY, INC.; ATLANTIC RICHFIELD COMPANY; BASELL NORTH AMERICA, INC.; EQUISTAR CHEMICALS. LP.; LYONDELL CHEMICAL COMPANY; LYONDELL CHEMICAL TECHNOLOGY, L.P.; LYONDELL PETROCHEMICAL COMPANY; NATIONAL DISTILLERS AND CHEMICAL CORPORATION; OCCIDENTAL CHEMICAL CORPORATION; OLIN CORPORATION; QUANTUM CHEMICAL CORPORATION; BASELL POLYOLEFIN GMBH
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 020704/0562 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2007
From: ZAMANIAN, AHMAD; DVORAK, LAWRENCE W.; REED, BRIAN K.
To: EQUISTAR CHEMICALS, LP
Reel/Frame 019539/0128 →