IP Library Granted Patent US 7,550,735
Granted Patent B2
US 7,550,735 · App. 11/824,094 · Granted Jun 23, 2009

GaTe semiconductor for radiation detection

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Quick Facts
Patent No.
US 7,550,735
App. No.
11/824,094
Granted
Jun 23, 2009
Kind
B2
Abstract

GaTe semiconductor is used as a room-temperature radiation detector. GaTe has useful properties for radiation detectors: ideal bandgap, favorable mobilities, low melting point (no evaporation), non-hygroscopic nature, and availability of high-purity starting materials. The detector can be used, e.g., for detection of illicit nuclear weapons and radiological dispersed devices at ports of entry, in cities, and off shore and for determination of medical isotopes present in a patient.

Claims (41)

1. A gamma radiation detector comprising a single crystal of GaTe semiconductor as a medium to detect a high-energy ionization event.

2. The detector of claim 1 , further comprising a plurality of electrodes deposited on said GaTe semiconductor, wherein when a voltage is applied across said electrodes and a gamma photon generates carriers in said GaTe semiconductor, a measurable current will be produced.

3. The detector of claim 2 , wherein said GaTe semiconductor comprises a c axis that is oriented perpendicular to the direction of said voltage.

4. The detector of claim 2 , wherein said voltage is within a range from 100-10,000 V/cm.

5. The detector of claim 2 , wherein said electrodes exhibit Schottky or Ohmic behavior.

6. The detector of claim 2 , wherein at least one electrode of said electrodes comprise indium.

7. The detector of claim 1 , wherein said GaTe semiconductor has a dimension of 0.1-10 cm.

8. The detector of claim 1 , wherein said GaTe semiconductor is grown by crystal growth method selected from the group consisting of physical vapor transport, chemical vapor transport, Czochralski technique, vertical Bridgman technique and horizontal Bridgman technique.

9. The detector of claim 1 , wherein said GaTe semiconductor is grown with a Te excess.

10. The detector of claim 1 , wherein said GaTe semiconductor is grown with at least one dopant.

11. The detector of claim 1 , wherein said GaTe semiconductor is grown with a Te excess and with at least one dopant.

12. The detector of claim 1 , wherein said semiconductor exhibits a resistivity of >10 8 Ω cm.

13. The detector of claim 1 , wherein said GaTe semiconductor comprises selenium.

14. A gamma photon detector, comprising:

a single crystal of GaTe;

a first metal contact in operative contact with said single crystal of GaTe;

a second metal contact in operative contact with said single crystal of GaTe; and

means for applying a voltage across said single crystal of GaTe wherein when a gamma photon generates carriers in said single crystal of GaTe, a measurable current will be produced.

15. The detector of claim 14 , further comprising means for measuring and characterizing said current.

16. The detector of claim 14 , wherein said single crystal of GaTe comprises a c axis that is oriented perpendicular to the direction of said voltage.

17. The detector of claim 14 , wherein said voltage is within a range from 100-10,000 V/cm.

18. The detector of claim 14 , wherein said single crystal of GaTe has a dimension of 0.1-10 cm.

19. The detector of claim 14 , wherein said single crystal of GaTe is grown by a crystal growth method selected from the group consisting of physical vapor transport, chemical vapor transport, Czochralski technique, vertical Bridgman technique and horizontal Bridgman technique.

20. The detector of claim 14 , wherein said single crystal of GaTe is grown with a configuration selected from the group consisting of (i) with a Te excess, (ii) with at least one dopant and (iii) with a Te excess and with at least one a dopant.

21. The detector of claim 14 , wherein at least one of said first metal contact or said second metal contact exhibits Schottky or Ohmic behavior.

22. The detector of claim 14 , wherein said single crystal exhibits a resistivity of >10 8 Ω cm.

23. The detector of claim 14 , wherein at least one of said first metal contact or said second metal contact comprises indium.

24. The detector of claim 14 , wherein said single crystal of GaTe comprises selenium.

25. A method for detecting gamma photons, comprising:

providing a single crystal of GaTe with a first metal contact and a second metal contact in contact with said single crystal of GaTe; and

applying a voltage across said single crystal of GaTe, wherein when a gamma photon generates carriers in said single crystal of GaTe, a measurable current will be produced; and

measuring said current.

26. The method of claim 25 , wherein said single crystal of GaTe comprises a c axis that is oriented perpendicular to the direction of said voltage.

27. The method of claim 25 , wherein said voltage is within a range from 100-10,000 V/cm.

28. The method of claim 25 , wherein said single crystal of GaTe has a dimension of 0.1-10 cm.

29. The method of claim 25 , wherein said single crystal of GaTe is grown by a crystal growth method selected from the group consisting of physical vapor transport, chemical vapor transport, Czochralski technique, vertical Bridgman technique and horizontal Bridgman technique.

30. The method of claim 25 , wherein said single crystal of GaTe is grown with a configuration selected from the group consisting of (i) with a Te excess, (ii) with at least one dopant and (iii) with a Te excess and with at least one dopant.

31. The method of claim 25 , wherein at least one of said first metal contact or said second metal contact exhibits Schottky or Ohmic behavior.

32. The method of claim 25 , wherein said crystal exhibits a resistivity of >10 8 Ω cm.

33. The method of claim 25 , wherein at least one of said first metal contact or said second metal contact comprises indium.

34. The method of claim 25 , wherein said single crystal of GaTe comprises selenium.

Assignments (5)
CONFIRMATORY LICENSE Recorded Dec 10, 2015
From: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 037256/0934 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 9, 2014
From: BURGER, ARNOLD
To: FISK UNIVERSITY
Reel/Frame 033274/0488 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2014
From: PAYNE, STEPHEN A.
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 032121/0054 →
CONFIRMATORY LICENSE Recorded Oct 9, 2007
From: REGENTS IF THE UNIVERSITY OF CALIFORNIA
To: US DEPARTMENT OF ENERGY
Reel/Frame 019939/0257 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 4, 2007
From: REGENTS OF THE UNIVERSITY OF CALIFORNIA, THE
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 020012/0032 →