Flexible photo-detectors
View Patent ↗Apparatus including flexible line extending along a length. Flexible line includes first charge carrier-transporting body, photosensitive body over first charge carrier-transporting body, and second charge carrier-transporting body over photosensitive body. Each of first and second charge carrier-transporting bodies and photosensitive body extend along at least part of length of flexible line. Photosensitive body is capable of near-infrared or visible light-induced generation of charge carrier pairs. Second charge carrier-transporting body is at least semi-transparent to near-infrared light or visible light.
1. An apparatus, comprising:
a flexible line extending along a length, the flexible line including:
a first charge carrier-transporting body extending along at least a part of the length of the flexible line;
a photosensitive body over the first charge carrier-transporting body and extending along at least a part of the length of the flexible line, the photosensitive body capable of near-infrared light-induced or visible light-induced generation of charge carrier pairs; and
a second charge carrier-transporting body over the photosensitive body and extending along at least a part of the length of the flexible line, the second charge carrier-transporting body being at least semi-transparent to near-infrared light or visible light; and
wherein the photosensitive body includes a conductive polymer having dispersed quantum dots or rods, the quantum dots or rods being photosensitive to visible or near-infrared light.
2. The apparatus of claim 1 , wherein the flexible line includes a flexible fiber extending along at least a part of the length of the flexible line, and the first charge carrier-transporting body is an inner charge carrier-transporting layer over the fiber and extending along at least a part of the length of the flexible line.
3. The apparatus of claim 2 , wherein the photosensitive body is a photosensitive layer over the inner charge carrier-transporting layer and extending along at least a part of the length of the flexible line.
4. The apparatus of claim 3 , wherein the second charge carrier-transporting body is an outer charge carrier-transporting layer over the photosensitive layer and extending along at least a part of the length of the flexible line.
5. The apparatus of claim 4 , wherein the fiber has a circumference at a selected point along the length of the flexible line, and the inner charge carrier-transporting layer, the photosensitive layer, and the outer charge carrier-transporting layer each are over only a part of the circumference at the point.
6. The apparatus of claim 1 , wherein the first charge carrier-transporting body and the second charge carrier-transporting body each include a p-doped semiconductor or an n-doped semiconductor.
7. The apparatus of claim 6 , wherein the photosensitive body is an intrinsic body, and wherein the flexible line includes a junction selected from a group consisting of a p-i-n junction, an n-i-n junction, and a p-i-p junction, the junction including the first and second charge carrier-transporting bodies and the photosensitive body.
8. The apparatus of claim 1 , wherein the photosensitive body has a composition including a photosensitive organic polymer capable of near-infrared light-induced or visible light-induced generation of charge carrier pairs.
9. The apparatus of claim 8 , wherein the photosensitive organic polymer includes a moiety selected from a group consisting of a paraphenylene vinylene, a fluorene, and a thiophene.
10. The apparatus of claim 1 , wherein the conductive polymer includes a member selected from a group consisting of poly(aniline), poly(acetylene), poly(pyrrole), and poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate).
11. A fabric including the apparatus of claim 1 .
12. A method, comprising:
providing a flexible line extending along a length, the flexible line including a first charge carrier-transporting body, a photosensitive body over the first charge carrier-transporting body, and a second charge carrier-transporting body over the photosensitive body, each of the first and second charge carrier-transporting bodies and the photosensitive body extending along at least a part of the length of the flexible line, the photosensitive body being capable of near-infrared light-induced or visible light-induced generation of charge carrier pairs, and the second charge carrier-transporting body being at least semi-transparent to near-infrared light or visible photosensitive body including a conductive polymer having dispersed quantum dots or rods, the quantum dots or rods being photosensitive to visible or near-infrared light;
providing an electrical circuit including the first and second charge carrier-transporting bodies and the photosensitive body, and a current detector; and
detecting current generated by exposure of the flexible line to near-infrared light or visible light.
13. The method of claim 12 , wherein providing the flexible line includes providing a flexible fiber extending along at least a part of the length of the flexible line, and includes providing, as the first charge carrier-transporting body, an inner charge carrier-transporting layer over the fiber and extending along at least a part of the length of the flexible line.
14. The method of claim 13 , wherein providing the flexible line includes providing, as the photosensitive body, a photosensitive layer over the inner charge carrier-transporting layer and extending along at least a part of the length of the flexible line.
15. The method of claim 14 , wherein providing the flexible line includes providing, as the second charge carrier-transporting body, an outer charge carrier-transporting layer over the photosensitive layer and extending along at least a part of the length of the flexible line.
16. The method of claim 12 , wherein providing the flexible line includes providing, as each of the first and second charge carrier-transporting bodies, a p-doped semiconductor or an n-doped semiconductor.
17. The method of claim 12 , wherein providing the flexible line includes providing a junction selected from a group consisting of a p-i-n junction, an n-i-n junction, and a p-i-p junction, the junction including the first and second charge carrier-transporting bodies and the photosensitive body.
18. The method of claim 12 , wherein the photosensitive body has a composition including a photosensitive organic polymer capable of near-infrared light-induced or visible light-induced generation of charge carrier pairs.
19. The method of claim 12 , wherein the photosensitive organic polymer includes a moiety selected from a group consisting of a paraphenylene vinylene, a fluorene, and a thiophene.
20. The method of claim 12 , wherein the conductive polymer includes a member selected from a group consisting of poly(aniline), poly(acetylene), poly(pyrrole), and poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate).