Dispersions of olefin block copolymers
View Patent ↗A dispersion and methods for forming a dispersion that includes a catalytic linear multi-block olefin interpolymer, and at least one dispersing agent, wherein the catalytic linear multi-block olefin interpolymer includes at least one hard segment and at least one soft segment is disclosed. Various applications of the dispersion are also disclosed.
1. An article comprising:
(A) a frothed foam produced from a dispersion comprising:
a catalytic linear multi-block olefin interpolymer that is a linear ethylene/α-olefin multi-block copolymer with at least 50 mole percent ethylene and having a Mw/Mn from 1.7 to 3.5, a melting point, Tm, in degrees Celsius, and density, d, in grams/cubic centimeter, wherein
Tm>−2002.9+4538.5( d )−2422.2( d ) 2 ;
at least one dispersing agent comprising a polar polyolefin;
wherein the catalytic linear multi-block olefin interpolymer comprises at least one hard segment and at least one soft segment; and
the dispersion is dispersed in acrylonitrile monomer;
(B) microcavities on at least one surface of the foam; and
(C) the frothed foam has a compression set at 85° C., 20 minutes, at a pressure of 0.1 psig of less than 45 percent.
2. The article of claim 1 , wherein the catalytic linear multi-block olefin interpolymer comprises from 5 to 70 weight percent of the at least one hard segment.
3. The article of claim 1 , wherein the multi-block olefin interpolymer comprises an ethylene/octene multi-block copolymer.
4. The article of claim 1 , wherein the at least one hard segment comprises from 0 to 5 weight percent α-olefin.
5. The article of claim 1 , wherein the at least one soft segment comprises from 5 to 60 weight percent α-olefin.
6. The article of claim 1 , wherein the multi-block olefin interpolymer comprises at least one polymer fraction obtained by preparative TREF, wherein the fraction has a block index from 0.3 to 1.0.
7. The article of claim 1 , wherein the multi-block olefin interpolymer has a density from 0.875 g/cc to 0.945 g/cc and a Tm from 115° C. to 125° C.
8. The article of claim 1 wherein the dispersion comprises a dispersed particulate having an average volume diameter particle size of greater than 0 and up to about 10 micrometers.
9. The article of claim 1 , wherein the dispersion comprises a dispersed particulate having an average solids content of greater than 0 up to about 80 weight percent.
10. The article of claim 1 , wherein the dispersion is an aqueous dispersion.
11. The article of claim 1 , wherein the frothed foam has a compression set at 85° C., 20 minutes, at a pressure of 0.5 psig of less than 70 percent.
12. The article of claim 1 , comprising cells having a size ranging from about 5 micrometers diameter to about 1000 micrometers diameter.
13. The article of claim 12 , wherein the cells comprise open cells.
14. The article of claim 12 wherein the cells having a size ranging from about 5 micrometers diameter to about 1000 micrometers diameter comprise greater than about 50 percent by volume of the total cells.
15. The article of claim 1 , wherein the dispersion has a viscosity of not more than about 50,000 cP at 25° C.
16. The article of claim 1 wherein the microcavities cumulatively comprise from 5% to not more than 29% of the total volume of the frothed foam.
17. The article of claim 1 comprising particles of a water-absorbent polymer substantially constrained within the microcavities.
18. The article of claim 1 comprising:
particles of a water-absorbent polymer substantially constrained within the microcavities.
19. The article of claim 18 wherein the article is selected from the group consisting of diapers, adult incontinence pants, feminine hygiene pads, household cleaning articles, pet urine absorption pads, garbage bag liquid absorbent pads.
20. The article of claim 18 wherein the article is a diaper.
21. The article of claim 18 wherein the article is a feminine hygiene pad.
22. The article of claim 1 wherein the article is a liquid absorbent layer.
23. A diaper comprising the liquid absorbent layer of claim 22 .
24. A feminine hygiene pad comprising the liquid absorbent layer of claim 22 .