Wear resistant lead free alloy bushing and method of making
View Patent ↗A bearing having improved wear resistance has a bearing material of a copper-tin-bismuth alloy which may also include phosphorus which has excellent strength, due to the solid solution of copper, tin and phosphorus (when used), attached to a steel backing shell. The material also has good lubricity as a result of the presence of the bismuth which also promotes tin mobilization and formation of a layer of tin on the bearing surface upon use of the bearing. The addition of small amounts of relatively small hard particles in the copper-tin-matrix, particularly Fe 3 P, MoSi 2 or a mixture thereof, provides a suitable hard surface artifact to improve the wear resistance of the bearing material. The bearing includes a sintered powder compact bearing material of a copper-tin-bismuth alloy powder and a metal compound powder which is bonded to a steel backing shell, wherein the metal compound powder has an average particle size of less than 10 μm.
1. A bearing comprising:
a sintered powder compact material bonded to a steel backing shell,
said sintered powder compact material including a copper-tin-bismuth alloy and a metal compound powder,
said copper-tin-bismuth alloy including a matrix of copper and tin and including bismuth in the form of islands spaced from one another by said matrix,
said metal compound powder dispersed throughout said matrix, and wherein said metal compound powder comprises Fe 3 P powder and MoSi 2 powder and has an average particle size of less than 10 μm.
2. The bearing of claim 1 , wherein said metal compound powder is selected from a group consisting of metal boride, metal silicide, metal oxide, metal nitride, metal carbide, metal phosphide and intermetallic compounds.
3. The bearing of claim 1 , wherein said copper-tin-bismuth alloy comprises, by weight: 8-15% tin, 1-30% bismuth and the balance essentially copper.
4. The bearing of claim 3 , wherein said copper-tin-bismuth alloy comprises, by weight: 8-12% tin, 1-<5% bismuth and the balance essentially copper.
5. The bearing of claim 3 , further comprising phosphorus as an alloy constituent, wherein said phosphorus comprises, by weight, 0.03-0.8% of the copper-tin-bismuth alloy powder.
6. The bearing of claim 1 , further comprising phosphorus as an alloy constituent of the copper-tin-bismuth alloy powder.
7. The bearing of claim 6 , further comprising a molybdenum phosphorus compound as a reaction product of said MoSi 2 powder and at least one of said Fe 3 P powder or said phosphorus.
8. The bearing of claim 1 , wherein said MoSi 2 powder comprises 0.1-0.5% by weight of the compact bearing material.
9. The bearing of claim 1 , wherein said metal compound powder comprises 0.1-10% by volume of the compact bearing material.
10. The bearing of claim 9 , wherein said metal compound powder comprises 1-2% by volume of the compact bearing material.
11. The bearing of claim 1 , wherein said copper-tin-bismuth alloy powder comprises a mixture of a gas atomized powder and a water atomized powder.
12. A bearing comprising:
a sintered powder compact material bonded to a steel backing shell,
said sintered powder compact material including a copper-tin-bismuth alloy and a metal compound powder,
said copper-tin-bismuth alloy including by weight 8-15% tin, 1-30% bismuth and the balance essentially copper,
said copper-tin-bismuth alloy including a matrix of copper and tin and including bismuth in the form of islands spaced from one another by said matrix, and
said metal compound powder comprising Fe 3 P powder and MoSi 2 powder and having an average particle size of less than 10 μm.