Coating including silica based material with pendent functional groups
View Patent ↗A coating including a silica-based material having pendent functional groups.
1. A method comprising:
mixing one part by weight of 1 N aqueous hydrochloric acid added to two parts N-(triethoxysilylpropyl) urea and one part tetramethoxysilane into a first solution;
allowing the solution to sit to allow hydrolysis to occur to form a sol-gel solution;
applying the sol-gel solution to a fuel cell component to provide a sol-gel film on the fuel cell component and curing the sol-gel film to provide a coating on the fuel cell component, and activating the coating comprising exposing the coating to water.
2. A method as set forth in claim 1 wherein the applying comprises diluting the first solution with water and spraying the sol-gel solution onto the fuel cell component to a thickness ranging from 2 to 20 μm.
3. A method as set forth in claim 1 further comprising curing the sol-gel solution in air at a temperature ranging from about 85-120° C.
4. A method as set forth in claim 1 further comprising curing the sol-gel solution at a temperature about room temperature to form a cured coating and activating the cured coating comprising immersing the coated component in water bath for at least one hour.
5. A method as set forth in claim 1 wherein the:
coating comprising a silica-based material including plurality of functional pendent groups.
6. A method as set forth in claim 5 wherein at least one of the plurality of functional pendent groups comprises a urea group.
7. A method as set forth in claim 5 wherein at least one of the plurality of functional pendent groups comprises a propylurea group.
8. A method as set forth in claim 5 wherein the coating is a urea-silica coating.
9. A method as set forth in claim 5 wherein each one of the plurality of the functional pendent groups comprises an ionic or ionizable group.
10. A method as set forth in claim 5 wherein each one of the plurality of the functional pendent groups comprises an hydroxyl, ether, ester, carbonyl, amide, amino, ammonium, sulfonate, sulfonyl, sulfate, sulfite, sulfonamide, carboxylate, phosphate, phosphonate, or halide group.
11. A method as set forth in claim 4 wherein the fuel cell component comprises a fuel cell bipolar plate.
12. A method as set forth in claim 4 wherein the fuel cell component comprises a fuel cell bipolar plate and wherein the coating is selectively deposited over portions of the fuel cell bipolar plate.
13. A method as set forth in claim 4 wherein the fuel cell component comprises a fuel cell bipolar plate comprising a first face defining a reactant gas flow field including a plurality of lands and channels and wherein the coating is selectively deposited over the channels of the fuel cell bipolar plate.
14. A method as set form in claim 4 wherein the fuel cell component comprises a fuel cell gas diffusion media and coating is on a surface of the gas diffusion media.
15. A method as set forth in claim 4 further comprising placing a fuel cell bipolar plate over the coating wherein the fuel cell bipolar plate includes a reactant gas flow field defined in a surface of the plate, and wherein the surface of the plate having the reactant gas flow field defined therein is adjacent the coating.
16. A method comprising:
mixing one part by weight of 1 N aqueous hydrochloric acid added to two parts N-(triethoxysilylpropyl) urea and one part tetramethoxysilane into a first solution;
allowing the solution to sit to allow hydrolysis to occur to form a sol-gel solution;
applying the sol-gel solution to a fuel cell component to provide a sol-gel film on the fuel cell component and curing the sol-gel film to provide a coating on the fuel cell component, and activating the coating comprising exposing the coating to water wherein the coating is porous.
17. A method as set forth in claim 1 further comprising curing the sol-gel solution at a temperature about room temperature to form a cured coating and activating the cured coating comprising immersing the coated component in water.