IP Library Granted Patent US 7,749,402
Granted Patent B2
US 7,749,402 · App. 11/833,492 · Granted Jul 6, 2010

Methods of preventing frost formation and facilitating the removal of winter precipitation relative to a windshield and compositions for use therein

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Quick Facts
Patent No.
US 7,749,402
App. No.
11/833,492
Granted
Jul 6, 2010
Kind
B2
Abstract

Disclosed herein is a winter precipitation barrier composition, comprising: a retaining agent, a solvent, and optionally, an auxiliary component, such as a rheology/viscosity modifier, surfactant, detergent, foaming/defoaming additive, humectant, dye, colorant, fragrance, or a combinations thereof. In one embodiment, the retaining agent comprises a primarily hydrophobic monomer or a hydrophilic monomer.

Claims (28)

1. A winter precipitation barrier composition comprising:

a retaining agent comprising a unit derived from a glycerol monomer and

a solvent comprising a mixture of methanol and propylene glycol.

2. The winter precipitation barrier composition of claim 1 , wherein the retaining agent comprises a primarily hydrophobic monomer or a hydrophilic monomer.

3. The winter precipitation barrier composition of claim 1 , wherein the retaining agent comprises both a hydrophobic monomer and a hydrophilic monomer.

4. The winter precipitation barrier composition of claim 1 , wherein the retaining agent comprises an ethylene oxide monomer.

5. The winter precipitation barrier composition of claim 1 , wherein the retaining agent comprises a propylene oxide monomer.

6. The winter precipitation barrier composition of claim 1 , wherein the retaining agent comprises a copolymer comprising ethylene oxide, propylene oxide, and glycerol.

7. The winter precipitation barrier composition of claim 1 , wherein the retaining agent comprises a polymer or copolymer having a molecular weight of from about 100 unified atomic mass units to about 10,000 unified atomic mass units.

8. The winter precipitation barrier composition of claim 7 , wherein the retaining agent comprises a polymer or copolymer having a the molecular weight of from about 2,000 unified atomic mass units to about 3,000 unified atomic mass units.

9. The winter precipitation barrier composition of claim 8 , wherein the retaining agent comprises a polymer or copolymer having a molecular weight of about 2600 unified atomic mass units.

10. The winter precipitation barrier composition of claim 1 , wherein the composition has a freezing point of less than 0 degrees Celsius.

11. The winter precipitation barrier composition of claim 10 , wherein the composition has a freezing point of less than −30 degrees Celsius.

12. The winter precipitation barrier composition of claim 1 , wherein the composition has a viscosity of greater than 0.1 cSt.

13. The winter precipitation barrier composition of claim 12 , wherein the composition has a boiling point of greater than 20 degree Celsius.

14. The winter precipitation barrier composition of claim 1 , comprising about 1 weight % to about 99.9 weight % solvent.

15. The winter precipitation barrier composition of claim 1 , wherein the composition comprises about 0.1 weight % to about 99 weight % retaining agent.

16. The winter precipitation barrier composition of claim 1 , wherein the composition comprises about 65% weight methanol, about 30% weight propylene glycol, and about 5 weight % retaining agent.

17. A winter precipitation barrier composition consisting essentially of:

a retaining agent comprising a polymer having both hydrophilic and hydrophobic monomers; and

a solvent comprising a monoalcohol and propylene glycol,

wherein the composition is free of any components comprising a silicon atom.

18. The winter precipitation barrier composition of claim 17 wherein the monoalcohol is methanol.

19. A method for impeding ice formation on a windshield, wherein the winter precipitation barrier composition of claim 17 is applied to a windshield such that the composition both reduces a rate of frost deposition on the windshield and reduces the adhesion strength between winter precipitation and the windshield.

20. A method for impeding ice formation on a windshield, wherein a winter precipitation barrier composition winter precipitation barrier composition comprising: a retaining agent comprising a unit derived from a glycerol monomer and

a solvent comprising glycol is applied to a windshield such that the composition both reduces a rate of frost deposition on the windshield and reduces the adhesion strength between winter precipitation and the windshield.

21. The method of claim 20 wherein the applied composition remains on the windshield for a period of at least one hour.

22. The method of claim 20 wherein the composition is applied to a windshield that has not been precleaned or pretreated.

Assignments (23)
GRANT OF SECURITY INTEREST IN PATENT RIGHTS Recorded Sep 8, 2024
From: PRESTONE PRODUCTS LLC
To: GOLDMAN SACHS MIDDLE MARKET LENDING CORP. II
Reel/Frame 068892/0272 →
GRANT OF SECURITY INTEREST IN PATENT RIGHTS Recorded Aug 15, 2024
From: PRESTONE PRODUCTS LLC
To: GOLDMAN SACHS MIDDLE MARKET LENDING CORP. II, AS COLLATERAL AGENT
Reel/Frame 068630/0147 →
RELEASE/TERMINATION OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 8, 2024
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: BIO-LAB, INC.; KIK CUSTOM PRODUCTS INC.; NC BRANDS, L.P.; PRESTONE PRODUCTS CORPORATION
Reel/Frame 068220/0306 →
RELEASE AND TERMINATION OF INTELLECTUAL PROPERTY SECURITY INTEREST Recorded Jul 8, 2024
From: BARCLAYS BANK PLC
To: AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS, INC.; KIK INTERNATIONAL, LLC; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC; JAMES AUSTIN COMPANY; NC BRANDS L.P.; CYGNUS CORPORATION
Reel/Frame 068220/0455 →
ENTITY CONVERSION Recorded Jun 25, 2024
From: PRESTONE PRODUCTS CORPORATION
To: PRESTONE PRODUCTS LLC
Reel/Frame 067826/0319 →
PARTIAL RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Jun 18, 2024
From: BARCLAYS BANK PLC, AS COLLATERAL AGENT
To: PRESTONE PRODUCTS CORPORATION
Reel/Frame 067777/0634 →
PARTIAL RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Jun 18, 2024
From: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
To: PRESTONE PRODUCTS CORPORATION
Reel/Frame 067777/0649 →
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Jun 18, 2024
From: BARCLAYS BANK PLC, AS COLLATERAL AGENT
To: PRESTONE PRODUCTS CORPORATION
Reel/Frame 067777/0671 →
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Jun 18, 2024
From: BARCLAYS BANK PLC, AS COLLATERAL AGENT
To: PRESTONE PRODUCTS CORPORATION
Reel/Frame 067777/0751 →
SECURITY AGREEMENT Recorded Dec 27, 2021
From: AQUA CLEAR INDUSTRIES, LLC; ASEPIS, INC.; BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC; JAMES AUSTIN COMPANY; CYGNUS CORPORATION; NC BRANDS L.P.
To: BARCLAYS BANK PLC
Reel/Frame 058592/0835 →
RELEASE OF INTELLECTUAL PROPERTY SECURITY INTEREST Recorded Jul 29, 2021
From: BARCLAYS BANK PLC, AS COLLATERAL AGENT
To: BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; JAMES AUSTIN COMPANY; KIK INTERNATIONAL LLC; NC BRANDS L.P.; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC
Reel/Frame 057650/0125 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (NOTES) Recorded Dec 22, 2020
From: BIO-LAB, INC.; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; JAMES AUSTIN COMPANY; CYGNUS CORPORATION; NC BRANDS L.P.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; HI-LEX LLC; HOMECARE LABS, INC.; SUNBELT POOL PRODUCTS, LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 055327/0754 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (2019) Recorded Jan 28, 2019
From: APG, INC.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS INC.; KIK CUSTOM PRODUCTS, INC; KIK INTERNATIONAL LLC; MARIETTA CORPORATION; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC; JAMES AUSTIN COMPANY; CBI LABORATORIES, INC.; CYGNUS CORPORATION; NC BRANDS L.P.
To: BARCLAYS BANK PLC, AS AGENT
Reel/Frame 048180/0101 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (TERM LOAN) Recorded Jan 23, 2019
From: PRESTONE PRODUCTS CORPORATION
To: BARCLAYS BANK PLC
Reel/Frame 049517/0967 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (ABL) Recorded Jan 23, 2019
From: PRESTONE PRODUCTS CORPORATION
To: BARCLAYS BANK PLC
Reel/Frame 049518/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 14, 2016
From: BARCLAYS BANK PLC
To: APG, INC.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; CYGNUS CORPORATION; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS INC.; KIK CUSTOM PRODUCTS, INC; KIK INTERNATIONAL LLC; MARIETTA CORPORATION; SOLSKYN PERSONAL CARE LLC; KIK NEW JERSEY, LLC; PRESTONE PRODUCTS CORPORATION
Reel/Frame 040031/0793 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Apr 5, 2016
From: APG, INC.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; CYGNUS CORPORATION; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS, INC. (TEXAS); KIK CUSTOM PRODUCTS INC. (DELAWARE); KIK INTERNATIONAL LLC; MARIETTA CORPORATION; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; KIK NEW JERSEY, LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 038354/0938 →
TERM AND REL OF SEC INT IN PATS-2ND LIEN Recorded Apr 4, 2016
From: CREDIT SUISSE AG, AS COLLATERAL AGENT; PRESTONE PRODUCTS CORPORATION
To: FRAM GROUP IP LLC
Reel/Frame 038337/0762 →
TERM AND REL OF SEC INT IN PATS-1ST LIEN Recorded Apr 4, 2016
From: CREDIT SUISSE AG, AS COLLATERAL AGENT; PRESTONE PRODUCTS CORPORATION
To: FRAM GROUP IP LLC
Reel/Frame 038337/0741 →
SECURITY AGREEMENT Recorded Aug 12, 2011
From: FRAM GROUP IP LLC; PRESTONE PRODUCTS CORPORATION
To: CREDIT SUISSE AG, AS SECOND LIEN COLLATERAL AGENT
Reel/Frame 026740/0089 →
SECURITY AGREEMENT Recorded Aug 11, 2011
From: FRAM GROUP IP LLC; PRESTONE PRODUCTS CORPORATION
To: CREDIT SUISSE AG, AS FIRST LIEN COLLATERAL AGENT
Reel/Frame 026732/0670 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 29, 2011
From: HONEYWELL INTERNATIONAL INC.
To: PRESTONE PRODUCTS CORPORATION
Reel/Frame 026671/0823 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 20, 2007
From: FENWICK, ANDREW E.; MARSHALL, REBECCA A.; BALOG, DAVID L.
To: HONEYWELL INTERNATIONAL, INC.
Reel/Frame 020139/0103 →