IP Library Granted Patent US 7,579,422
Granted Patent B2
US 7,579,422 · App. 11/836,644 · Granted Aug 25, 2009

Propylene random copolymer and process for the production thereof

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Quick Facts
Patent No.
US 7,579,422
App. No.
11/836,644
Granted
Aug 25, 2009
Kind
B2
Abstract

The present invention relates to a process for preparing a propylene random copolymer comprising polymerization of propylene with a comonomer, said comonomer being ethylene or an α-olefin comprising at least four carbon atoms, in the presence of a catalyst in a multistage process comprising polymerization of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerization product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerisations of propylene with a comonomer in said gas phase reactor in the presence of said first polymerization product, wherein the temperature in the gas phase reactor is at least 10° C. higher than in the slurry reactor and to a polymer obtainable by this process. Furthermore, the invention relates to a propylene random copolymer prepared by copolymerization of propylene with a comonomer wherein the distribution of the comonomer determined according to the TREF method is multimodal, preferably bimodal, a propylene random copolymer prepared by copolymerization of propylene with a comonomer wherein the copolymer is having an elution interval determined according to the TREF method of 50° C. or more, a propylene random copolymer prepared by copolymerization of propylene with a comonomer, wherein the random copolymer is a unimodal polymer and the elution interval determined by the TREF method is given by the equation Y≦4.5·m+16 wherein Y is the elution interval in ° C. and m is the percentage of ethylene in the copolymer in wt. %, and to the use of such a copolymers for the production of a film, of an article by blow moulding or injection moulding, of a fiber or of a pipe.

Claims (10)

1. A propylene random copolymer prepared by copolymerisation of propylene with ethylene, wherein the copolymer has an ethylene content to 3 wt % or more and an elution interval determined according to the TREF method of 50° C. or more; and wherein the amount of components of said copolymer eluting at temperatures of up to 90° C. determined according to the TREF method is below 50 wt % of the whole amount of copolymer.

2. A propylene random copolymer according to claim 1 having a melting temperature T m of 135° C. or higher.

3. A propylene random copolymer according to claim 2 having an ethylene content of 6 wt. % or lower.

4. A propylene random copolymer according to claim 1 wherein the xylene solubles content is from 4 to 24 wt. %.

5. A film comprising a copolymer according to claim 1 .

6. An article comprising a copolymer according to claim 1 wherein the article has been produced by blow moulding.

7. An article comprising a copolymer according to claim 1 wherein the article has been produced by injection moulding.

8. A fibre comprising a copolymer according to claim 1 .

9. A pipe comprising a copolymer according to claim 1 .

10. A method comprising forming the copolymer of claim 1 into a film, fiber or pipe, or forming an article of the copolymer by injection molding or blow molding.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 9, 2007
From: JAASKELAINEN, PIRJO; HAFNER, NORBERT; PITKANEN, PAIVI; GAHLEITNER, MARKUS, DR; TUOMINEN, OLLI; TOLTSCH, WILFRIED
To: BOREALIS TECHNOLOGY OY
Reel/Frame 019674/0957 →