Molybdenum metal powder and production thereof
View Patent ↗Molybdenum metal powder has surface-area-to-mass-ratios in a range of between about 1.0 meters 2 /gram (m 2 /g) and about 3.0 m 2 /g, as determined by BET analysis, in combination with a particle size wherein at least 30% of the particles are larger than a size +100 standard Tyler mesh sieve. A method for producing molybdenum metal powder includes providing a supply of ammonium molybdate and a reducing gas; causing an exothermic reaction between the ammonium molybdate and the reducing gas at a first temperature to produce an intermediate reaction product and a supplemental reducing gas; causing an endothermic reaction between the intermediate reaction product and the reducing gas at a final temperature to produce the molybdenum metal powder.
1. A molybdenum metal powder, comprising:
surface-area-to-mass ratio between about 1.0 m 2 /g and about 3.0 m 2 /g, as determined by BET analysis; and
particles, wherein at least 30% of the particles have a size larger than a size +100 Tyler mesh sieve.
2. The molybdenum metal powder of claim 1 further comprising a reduced form of an ammonium molybdate precursor material.
3. The molybdenum metal powder of claim 2 wherein the molybdenum metal powder begins to sinter at about 950° C.
4. A molybdenum metal powder, comprising:
surface-area-to-mass ratio between about 1.0 m 2 /g and about 3.0 m 2 /g, as determined by BET analysis; and
particles, wherein at least 40% of the particles have a size larger than a size +100 Tyler mesh sieve.
5. The molybdenum metal powder of claim 4 , wherein the molybdenum metal powder has a flowability of between about 51 s/50 g and about 78 s/50 g as determined by a Hall Flowmeter.
6. The molybdenum metal powder of claim 4 further comprising a reduced form of an ammonium molybdate precursor material.
7. The molybdenum metal powder of claim 4 wherein the molybdenum metal powder begins to sinter at about 950° C.
8. The molybdenum metal powder of claim 1 , further comprising a final weight percent of oxygen in a range from about 0.12% to about 0.35%.
9. The molybdenum powder of claim 1 , wherein the molybdenum metal powder has a flowability of between about 51 s/50 g and about 78 s/50 g as determined by a Hall Flowmeter.
10. A method for producing molybdenum metal powder, comprising:
providing a supply of ammonium molybdate;
providing a supply of a reducing gas;
causing an exothermic reaction between the ammonium molybdate and the reducing gas at a first temperature to produce an intermediate reaction product and a supplemental reducing gas;
causing an endothermic reaction between the intermediate reaction product and at least the reducing gas at a final temperature to produce the molybdenum metal powder, the molybdenum metal powder having a surface-area-to-mass ratio between about 1.0 m 2 /g and about 3.0 m 2 /g, as determined by BET analysis, the molybdenum metal powder comprising particles wherein at least 30% of the particles have a size larger than a size +100 Tyler mesh sieve.
11. The method of claim 10 further comprising diminishing the supply of reducing gas based on the supplemental reducing gas produced.
12. The method of claim 10 wherein the ammonium molybdate is selected from the group consisting of ammonium dimolybdate, ammonium heptamolybdate and ammonium octamolybdate.
13. The method of claim 10 wherein the molybdenum metal powder begins to sinter at about 950° C.
14. The method of claim 10 wherein the supply of reducing gas comprises hydrogen.
15. The method of claim 10 , further comprising:
providing a supply of inert gas; and
using the supply of reducing gas and the supply of inert gas to maintain a substantially constant pressure during the exothermic reaction and the endothermic reaction.