Systems and methods for nanowire growth and harvesting
View Patent ↗The present invention is directed to systems and methods for nanowire growth and harvesting. In an embodiment, methods for nanowire growth and doping are provided, including methods for epitaxial oriented nanowire growth using a combination of silicon precursors. In a further aspect of the invention, methods to improve nanowire quality through the use of sacrificial growth layers are provided. In another aspect of the invention, methods for transferring nanowires from one substrate to another substrate are provided.
1. A method for producing nanowires comprising:
(a) providing a substrate material having one or more nucleating particles deposited thereon in a reaction chamber;
(b) introducing a precursor gas mixture into the reaction chamber to initiate nanowire growth, wherein the precursor gas mixture comprises SiCl 4 or SiH 2 Cl 2 ;
(c) introducing an independent chlorine gas species separate from the precursor gas mixture into the reaction chamber to control etching to promote oriented nanowire growth; and
(c) growing nanowires at the site of the nucleating particles.
2. The method of claim 1 , wherein said introduction of the precursor gas mixture occurs at a temperature less than about 800° C.
3. The method of claim 1 , further comprising introducing one or more dopant gases into the reaction chamber during said growing of the nanowires.
4. Nanowires produced by the process of claim 1 .
5. An electronic circuit comprising nanowires produced by the process of claim 1 .