Dye-sensitized solar cell using ion-bound oligomer complex and method of manufacturing the same
A dye-sensitized solar cell using an ion-bound oligomer complex is provided. The dye-sensitized solar cell comprises an electrolyte, comprising a first oligomer having a C 5-30 heteroaryl group containing a nitrogen heteroatom as a basic functional group at both ends of the molecule, mixed with a second oligomer having an acidic functional group selected from among carboxylic acid, phosphoric acid, and sulfonic acid, at both ends of the molecule, to thus form a salt, which then leads to an ion-bound oligomer complex that constitutes the electrolyte. The solar cell exhibits excellent mechanical properties, can be manufactured conveniently, and can have a high energy conversion efficiency.
1. A dye-sensitized solar cell comprising:
a photoelectrode;
a counter electrode; and
an electrolyte layer disposed between the photoelectrode and the counter electrode, in which the electrolyte layer comprises an electrolyte comprising an ion-bound oligomer complex produced by mixing a first oligomer having a basic functional group at both ends of the molecule, with a second oligomer having an acidic functional group at both ends of the molecule; and
a redox couple.
2. The solar cell of claim 1 , wherein the basic functional group is a C 5-30 heteroaryl group containing a nitrogen heteroatom.
3. The solar cell of claim 1 , wherein the acidic functional group is selected from the group consisting of carboxylic acid, phosphoric acid, sulfonic acid and, a combination of one or more of the foregoing acidic functional groups.
4. The solar cell as set forth in claim 1 , wherein the first oligomer having a basic functional group at both ends of the molecule is represented by Formula 1 below:
R 1 —X R 2 X n R 1 [Formula 1]
wherein R 1 is a substituted or unsubstituted C 5-30 heteroaryl group or a substituted or unsubstituted C 5-30 heteroarylalkyl group, containing nitrogen as a heteroatom;
R 2 is a substituted or unsubstituted C 1-5 alkyl group or a substituted or unsubstituted C 1-5 heteroalkyl group;
X is selected from among oxygen, sulfur, selenium, and tellurium; and
n is an integer of about 3 to about 14.
5. The solar cell of claim 4 , wherein the first oligomer having a basic functional group represented by Formula 1, is selected from the group comprising oligomers represented by Formulas 2, 3, 4 and 5 below:
wherein n is an integer from about 3 to about 14;
wherein n is an integer from about 3 to about 14;
wherein n is an integer from about 3 to about 14; and
wherein n is an integer from about 3 to about 14.
6. The solar cell of claim 1 , wherein the second oligomer having an acidic functional group at both ends of the molecule is represented by Formula 6 below:
Y—R 3 —X R 2 X n R 3 —Y [Formula 6]
wherein R 2 is a substituted or unsubstituted C 1-5 alkyl group or a substituted or unsubstituted C 1-5 heteroalkyl group;
R 3 is selected from among a substituted or unsubstituted C 1-10 alkyl group, a substituted or unsubstituted C 1-10 heteroalkyl group, a substituted or unsubstituted C 6-30 aryl group, a substituted or unsubstituted C 6-30 arylalkyl group, a substituted or unsubstituted C 2-30 heteroaryl group, a substituted or unsubstituted C 2-30 heteroarylalkyl group, a substituted or unsubstituted C 5-20 cycloalkyl group, a substituted or unsubstituted C 2-30 heterocycloalkyl group, a substituted or unsubstituted C 1-30 alkylester group, a substituted or unsubstituted C 1-30 heteroalkyl ester group, a substituted or unsubstituted C 6-30 arylester group, and a substituted or unsubstituted C 2-30 heteroaryl ester group;
X is selected from among oxygen, sulfur, selenium, and tellurium;
Y is selected from among a carboxylic acid functional group, a phosphoric acid functional group, and a sulfonic acid functional group; and
n is an integer of about 1 to about 40.
7. The solar cell of claim 6 , wherein the second oligomer having an acidic functional group, represented by Formula 6, is selected from the group comprising oligomers represented by Formulas 7, 8 and 9 below:
wherein n is an integer from about 1 to about 40;
wherein n is an integer from about 1 to about 40; and
wherein n is an integer from about 1 to about 40.
8. The solar cell of claim 1 , wherein the electrolyte layer comprises the second oligomer having an acidic functional group and the first oligomer having a basic functional group mixed at a molar ratio of the acidic functional group to the basic functional group of about 1:1 to about 1:20.
9. The solar cell of claim 8 , wherein the molar ratio of the acidic functional group to the basic functional group is about 1:1.
10. The solar cell of 1 , wherein the first oligomer having a basic functional group at both ends of the molecule, and the second oligomer having an acidic functional group at both ends of the molecule, have a radius of gyration of about 6 to about 50 Å.
11. The solar cell of claim 1 , wherein the redox couple is one or more metal salts selected from the group consisting of lithium iodide, sodium iodide, potassium iodide, lithium bromide, sodium bromide and potassium bromide, imidazolium iodides, and a combination of one or more of the foregoing metal salts.
12. A method of manufacturing a dye-sensitized solar cell comprising:
a photoelectrode,
a counter electrode, and
an electrolyte layer disposed between the photoelectrode and the counter electrode; the method comprising,
preparing a homogeneous solution by mixing a first oligomer having a basic functional group at both ends of the molecule, with a second oligomer having an acidic functional group at both ends of the molecule, at a molar ratio of the acidic functional group to the basic functional group of about 1:1 to about 1:20;
adding the prepared solution with a redox couple, to thus prepare an electrolyte; and
injecting the prepared electrolyte between the photoelectrode and the counter electrode.
13. The method of claim 12 , wherein the basic functional group is a C 5-30 heteroaryl group containing a nitrogen heteroatom.
14. The method of claim 12 , wherein the acidic functional group is selected from the group consisting of carboxylic acid, phosphoric acid, sulfonic acid and, a combination of one or more of the foregoing acidic functional groups.
15. The method of claim 12 , wherein the first oligomer having a basic functional group at both ends of the molecule, is represented by Formula 1:
R 1 —X R 2 X n R 1 [Formula 1]
wherein R 1 is a substituted or unsubstituted C 5-30 heteroaryl group or a substituted or unsubstituted C 5-30 heteroarylalkyl group, containing nitrogen as a heteroatom;
R 2 is a substituted or unsubstituted C 1-5 alkyl group or a substituted or unsubstituted C 1-5 heteroalkyl group;
X is selected from a group consisting of oxygen, sulfur, selenium, and tellurium; and
n is an integer from about 3 to about 14.
16. The method of claim 15 , wherein the first oligomer having a basic functional group represented by Formula 1, is selected from the group comprising oligomers represented by Formulas 2, 3, 4 and 5 below:
wherein n is an integer from about 3 to about 14;
wherein n is an integer from about 3 to about 14;
wherein n is an integer from about 3 to about 14; and
wherein n is an integer from about 3 to about 14.
17. The method of claim 12 , wherein the second oligomer having an acidic functional group at both ends of the molecule, is represented by Formula 6 below:
Y—R 3 —X R 2 X n R 3 —Y [Formula 6]
wherein R 2 is a substituted or unsubstituted C 1-5 alkyl group or a substituted or unsubstituted C 1-5 heteroalkyl group; R 3 is selected from among a substituted or unsubstituted C 1-10 alkyl group, a substituted or unsubstituted C 1-10 heteroalkyl group, a substituted or unsubstituted C 6-30 aryl group, a substituted or unsubstituted C 6-30 arylalkyl group, a substituted or unsubstituted C 2-30 heteroaryl group, a substituted or unsubstituted C 2-30 heteroarylalkyl group, a substituted or unsubstituted C 5-20 cycloalkyl group, a substituted or unsubstituted C 2-30 heterocycloalkyl group, a substituted or unsubstituted C 1-30 alkylester group, a substituted or unsubstituted C 1-30 heteroalkyl ester group, a substituted or unsubstituted C 6-30 arylester group, and a substituted or unsubstituted C 2-30 heteroaryl ester group; X is selected from among oxygen, sulfur, selenium, and tellurium;
Y is selected from among a carboxylic acid functional group, a phosphoric acid functional group, and a sulfonic acid functional group; and
n is an integer of about 1 to about 40.
18. The method of claim 17 , wherein the second oligomer having an acidic functional group represented by Formula 6, is selected from the group comprising oligomers represented by Formulas 7, 8 and 9 below:
wherein n is an integer from about 1 to about 40;
wherein n is an integer from about 1 to about 40; and
wherein n is an integer from about 1 to about 40.
19. The method of claim 12 , wherein the molar ratio of the acidic functional group to the basic functional group is 1:1.
20. The method of claim 12 , wherein the first oligomer having a basic functional group at both ends of the molecule, and the second oligomer having an acidic functional group at both ends of the molecule, have a radius of gyration of about 6 to about 50 Å.
21. The method as set forth in claim 12 , wherein the redox couple is one or more metal salts selected from the group consisting of lithium iodide, sodium iodide, potassium iodide, lithium bromide, sodium bromide and potassium bromide, imidazolium iodides, and a combination of one or more of the foregoing metal salts.