Methods of preparing supported catalysts from metal loaded carbon nanotubes
View Patent ↗A new method for preparing a supported catalyst is herein provided. Carbon nanotubes are functionalized by contacting them with an oxidizing agent to form functionalized carbon nanotubes. A metal catalyst is then loaded or deposited onto the functionalized carbon nanotubes. The mixture is then extruded to form the supported catalyst comprising a carbon nanotube structure containing metal catalyst more evenly dispersed within the internal structure of the carbon nanotube structure.
1. A method for preparing a supported catalyst comprising:
de-aggregating aggregates of multiwalled carbon nanotubes to provide de-aggregated multiwalled carbon nanotubes;
loading metal catalysts or metal catalyst precursors onto the de-aggregated multiwalled carbon nanotubes to form metal-loaded de-aggregated multiwalled carbon nanotubes; and
forming a carbon nanotube structure from the metal-loaded de-aggregated multiwalled carbon nanotubes.
2. The method of claim 1 , wherein the metal catalysts or metal catalyst precursors are selected from the group consisting of ruthenium, osmium, rhodium, iridium, palladium, platinum, silver, gold, and mixtures thereof.
3. The method of claim 1 , wherein the metal catalysts or metal catalyst precursors comprise palladium.
4. The method of claim 1 , wherein the metal catalysts or metal catalyst precursors are selected from the group consisting of oxides, halides, carbides, nitrides, phosphides and sulfides of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, La, Ce, W, and combinations thereof.
5. The method of claim 1 , further comprising:
functionalizing the de-aggregated multiwalled carbon nanotubes with a functionalizing agent to form functionalized de-aggregated multiwalled carbon nanotubes prior to loading metal catalysts or metal catalyst precursors onto the functionalized de-aggregated multiwalled carbon nanotubes to form metal-loaded de-aggregated multiwalled carbon nanotubes.
6. The method of claim 5 , wherein the functionalizing agent comprises an oxidizing agent selected from the group consisting of potassium chlorate, sulfuric acid, HNO 3 , persulfate, H 2 O 2 , CO 2 , O 2 , steam, N 2 O, NO, NO 2 , O 3 , and ClO 2 .
7. The method of claim 1 , wherein the supported catalyst has essentially no loss in metal catalyst dispersion.
8. A method for preparing a supported catalyst comprising:
de-aggregating aggregates of single-walled carbon nanotubes to provide de-aggregated single-walled carbon nanotubes;
loading metal catalysts or metal catalyst precursors onto the de-aggregated single-walled carbon nanotubes to form metal-loaded de-aggregated single-walled carbon nanotubes; and
forming a carbon nanotube structure from the metal-loaded de-aggregated single-walled carbon nanotubes.
9. The method of claim 8 , wherein the metal catalysts or metal catalyst precursors are selected from the group consisting of ruthenium, osmium, rhodium, iridium, palladium, platinum, silver, gold, and mixtures thereof.
10. The method of claim 8 , wherein the metal catalysts or metal catalyst precursors comprise palladium.
11. The method of claim 8 , wherein the metal catalysts or metal catalyst precursors are selected from the group consisting of oxides, halides, carbides, nitrides, phosphides and sulfides of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, La, Ce, W, and combinations thereof.
12. The method of claim 8 , further comprising:
functionalizing the de-aggregated single-walled carbon nanotubes with a functionalizing agent to form functionalized de-aggregated single-walled carbon nanotubes prior to loading metal catalysts or metal catalyst precursors onto the functionalized de-aggregated single-walled carbon nanotubes to form metal-loaded de-aggregated single-walled carbon nanotubes.
13. The method of claim 12 , wherein the functionalizing agent comprises an oxidizing agent selected from the group consisting of potassium chlorate, sulfuric acid, HNO 3 , persulfate, H 2 O 2 , CO 2 , O 2 , steam, N 2 O, NO, NO 2 , O 3 , and ClO 2 .
14. The method of claim 8 , wherein the supported catalyst has essentially no loss in metal catalyst dispersion.
15. A method for preparing a supported catalyst comprising:
de-aggregating aggregates of carbon nanotubes to provide de-aggregated carbon nanotubes;
loading metal catalysts or metal catalyst precursors onto the de-aggregated carbon nanotubes to form metal-loaded de-aggregated carbon nanotubes; and
forming a carbon nanotube structure from the metal-loaded de-aggregated carbon nanotubes;
wherein the carbon nanotubes are a mixture of multiwalled and single-walled carbon nanotubes.
16. The method of claim 15 , wherein the metal catalysts or metal catalyst precursors are selected from the group consisting of ruthenium, osmium, rhodium, iridium, palladium, platinum, silver, gold, and mixtures thereof.
17. The method of claim 15 , wherein the metal catalysts or metal catalyst precursors comprise palladium.
18. The method of claim 15 , wherein the metal catalysts or metal catalyst precursors are selected from the group consisting of oxides, halides, carbides, nitrides, phosphides and sulfides of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, La, Ce, W, and combinations thereof.
19. The method of claim 16 , further comprising:
functionalizing the de-aggregated carbon nanotubes with a functionalizing agent to form functionalized de-aggregated carbon nanotubes prior to loading metal catalysts or metal catalyst precursors onto the functionalized de-aggregated carbon nanotubes to form metal-loaded de-aggregated carbon nanotubes.
20. The method of claim 19 , wherein the functionalizing agent comprises an oxidizing agent selected from the group consisting of potassium chlorate, sulfuric acid, HNO 3 , persulfate, H 2 O 2 , CO 2 , O 2 , steam, N 2 O, NO, NO 2 , O 3 , and ClO 2 .