Optimized liquid-phase oxidation
View Patent ↗Disclosed is an optimized process and apparatus for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.
1. In a bubble column reactor for reacting a predominately liquid-phase stream with a predominately gas-phase stream, the improvement comprising:
a vessel shell defining an elongated reaction zone extending along a normally-upright central shell axis, wherein said reaction zone has a maximum length (L) measured parallel to said shell axis, a maximum diameter (D) measured perpendicular to said shell axis, and an L:D ratio in the range of from about 6:1 to about 30:1;
a plurality of liquid openings for introducing said liquid-phase stream into said reaction zone, wherein at least two of said liquid openings are axially spaced from one another by at least about 0.5 D; and
a plurality of gas openings for introducing said gas-phase stream into said reaction zone, wherein said reaction zone presents first and second opposite ends spaced from one another by said maximum length (L), wherein a majority of the cumulative open area defined by all of said gas openings is located within about 0.25 D of said first end of said reaction zone,
wherein at least about 25 percent of the cumulative open area defined by all of said liquid openings is attributable to liquid openings located in a preferred feed zone, wherein said preferred feed zone is defined by a theoretical upright annulus having an outer diameter of 0.9 D and an inner diameter of 0.2 D, wherein said upright annulus is substantially centered in said reaction zone.
2. The bubble column reactor of claim 1 wherein at least about 50 percent of the cumulative open area defined by all of said liquid openings is attributable to liquid openings located in said preferred feed zone.
3. The bubble column reactor of claim 1 wherein said L:D ratio is in the range of from about 8:1 to about 20:1, wherein at least two of said liquid feed openings are axially spaced from one another by at least about 1.5 D, wherein a majority of the cumulative open area defined by all of said gas openings is located within about 0.2 D of said first end of said reaction zone, wherein at least about 30 percent of the cumulative open area defined by all of said liquid openings is attributable to liquid openings located within about 1.5 D of the gas opening located closest to said first end.
4. The bubble column reactor of claim 1 wherein said reactor further comprises an elevated outlet axially spaced at least about 1 D from said first end.
5. The bubble column reactor of claim 4 wherein said elevated outlet is axially spaced at least about 2 D from said first end.
6. The bubble column reactor of claim 1 wherein when said reaction zone is theoretically partitioned into 4 vertical quadrants of equal volume by a pair of intersecting vertical planes, not more than about 80 percent of the cumulative open area defined by all of said liquid openings is attributable to liquid openings located in a single one of said vertical quadrants.
7. The bubble column reactor of claim 5 wherein not more than about 60 percent of the cumulative open area defined by all of said liquid openings is attributable to liquid openings located in a single one of said vertical quadrants.
8. The bubble column reactor of claim 1 wherein at least a portion of said reaction zone is defined by one or more upright sidewalls of said reactor, wherein at least about 25 percent of the cumulative open area defined by all of said liquid openings is attributable to liquid openings spaced inwardly at least 0.05 D from said upright sidewalls.
9. The bubble column reactor of claim 8 wherein at least about 50 percent of the cumulative open area defined by all of said liquid openings is attributable to liquid openings spaced inwardly at least 0.05 D from said upright sidewalls.