Use of oil-soluble surfactants as breaker enhancers for VES-gelled fluids
View Patent ↗Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of an internal breaker composition that contains at least one mineral oil, at least one polyalphaolefin oil, at least one saturated fatty acid and/or at least one unsaturated fatty acid. The internal breaker may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the internal breaker, e.g. mineral oil, is added to the fluid after it has been substantially gelled. An oil-soluble surfactant is present to enhance or accelerate the reduction of viscosity of the gelled aqueous fluid.
1. A method for breaking the viscosity of aqueous fluids gelled with a viscoelastic surfactant (VES) comprising
adding to an aqueous fluid at least one VES in an amount effective to increase the viscosity thereof;
adding to the aqueous fluid before or after the VES at least one internal breaker in an amount effective to reduce the viscosity of the gelled aqueous fluid, where the internal breaker is selected from the group consisting of polyenoic acids and monoenoic acids; and
adding to the fluid before, during or after adding the internal breaker, at least one oil-soluble surfactant breaker enhancer in an amount effective to accelerate reduction of viscosity of the gelled aqueous fluid.
2. The method of claim 1 , where the oil-soluble surfactant breaker enhancer is selected from the group consisting of sorbitan fatty acid esters, saponified hard oils, saponified hydrogenated fatty acid oils, long chain alcohols, long chain fatty acid alcohols, long chain fatty amines, long chain sulfates, long chain sulfonates, phospholipids, and lignins.
3. The method of claim 1 where
the internal breaker is present in an amount from about 100 to about 20,000 ppm based on the total fluid; and
the breaker enhancer is present in an amount from about 0.001 to about 10 wt % based on the total fluid.
4. The method of claim 1 where the internal breaker is a polyenoic acid selected from the group consisting of linoleic acid, omega-3 fatty acids, omega-6 fatty acids, stearidonic acid, eleostearic acid, eicosadienoic acid, eicosatrienoic acid, arachidonic acid or eicosatetraenoic acid, eicosapentaenoic acid, docosapentaenoic acid, docosahexaenoic acid, cis-linoleic acid, cis-linolenic acid, gamma-linolenic acid, and conjugated polyenes.
5. The method of claim 1 where the internal breaker is a monoenoic acids selected from the group consisting of obtusilic acid, caproleic acid, lauroleic acid, linderic acid, myristoleic acid, physeteric acid, tsuzuic acid, palmitoleic acid, petroselinic acid, oleic acid, vaccenic acid, gadoleic acid, gondoic acid, cetoleic acid, nervonic acid, erucic acid, elaidic acid, and t-vaccenic acid.
6. The method of claim 1 where the internal breaker is present in an oil-soluble internal phase of the aqueous fluid.
7. The method of claim 1 where the viscosity is broken within about 1 to about 16 hours at a temperature from about 25° C. to about 150° C.
8. A method for breaking the viscosity of aqueous fluids gelled with a viscoelastic surfactant (VES) comprising
adding to an aqueous fluid at least one VES in an amount effective to increase the viscosity thereof;
adding to the aqueous fluid before or after the VES at least one internal breaker in an amount effective to reduce the viscosity of the gelled aqueous fluid, where the internal breaker is selected from the group consisting of polyenoic acids and monoenoic acids; and
adding to the fluid before, during, or after adding the internal breaker, from about 0.001 to about 10 wt % based on the total fluid of at least one oil-soluble surfactant breaker enhancer, where the oil-soluble surfactant breaker enhancer is selected from the group consisting of sorbitan fatty acid esters, saponified hard oil, saponified hydrogenated fatty acid oils, long chain alcohols, long chain fatty acid alcohols, long chain fatty amines, long chain sulfates, long chain sulfonates, phospholipids, and lignins.
9. The method of claim 8 where the internal breaker is present in an amount from about 100 to about 20,000 ppm based on the total fluid.
10. The method of claim 8 where the internal breaker is present in an oil-soluble internal phase of the aqueous fluid.
11. The method of claim 8 where the viscosity is broken within about 1 to about 16 hours at a temperature from about 25° C. to about 150° C.