Ceramic discharge vessel having an opaque zone and method of making same
View Patent ↗An opaque zone in the polycrystalline (PCA) discharge vessel of a high intensity discharge lamp may be made by creating residual pores in predetermined regions of the final-sintered discharge vessel. The control over the placement of the opaque zone is achieved by forming a carbonaceous residue in a specific region of the discharge vessel prior to final sintering. During sintering, the carbonaceous material causes residual porosity in the sintered PCA. The higher emissivity of the opaque PCA provides localized cooling in order to provide more control over the condensate behavior in the discharge vessel.
1. A method for forming an opaque zone in a ceramic discharge vessel, the method comprising:
(a) forming a discharge vessel from a mixture of alumina and an organic binder;
(b) firing the discharge vessel shape to remove the organic binder and form a prefired discharge vessel;
(c) applying a solution of an organic compound to a surface of the prefired discharge vessel in a predetermined region;
(d) firing the prefired discharge vessel in a nitrogen or inert gas atmosphere to form a carbonaceous residue in the predetermined region; and
(e) sintering the prefired discharge vessel to form an opaque zone in the predetermined region.
2. The method of claim 1 wherein the organic compound is polyvinyl alcohol.
3. The method of claim 2 wherein the solution contains 10 weight percent polyvinyl alcohol.
4. The method of claim 1 wherein after the solution is applied in multiple applications wherein the solution is allowed to dry between applications.
5. The method of claim 1 wherein firing in step (d) is performed in a nitrogen atmosphere.
6. The method of claim 1 wherein the firing in step (d) is performed at a temperature from about 700° C. to about 1400° C.
7. The method of claim 5 wherein the firing in step (d) is at 900° C.
8. The method of claim 1 wherein the sintering in step (e) is performed at a temperature from about 1750° C. to about 1950° C. in a hydrogen-containing atmosphere.
9. The method of claim 6 wherein the sintering in step (e) is performed at a temperature from about 1750° C. to about 1950° C. in a hydrogen-containing atmosphere.
10. The method of claim 9 wherein the organic compound is polyvinyl alcohol.
11. The method of claim 10 wherein the solution contains 10 weight percent polyvinyl alcohol.