Dot size controlling primer coating for radiation curable ink jet inks
View Patent ↗The present invention provides a printing method for printing radiation-curable ink jet ink printing comprising a clear coat primer composition comprising: a low surface tension monofunctional alkyl acrylate monomer with a surface tension in the range of 23 to 31 dynes/cm in which the alkyl group has at least 8 carbon atoms; a photoinitiator; and other UV curable monomers and oligomers. The clear coat primer composition is applied first onto a substrate and cured with actinic radiation or cationic curable ink jet ink is printed on the surface of the clear coat primer coating.
1. A method for printing an image on a surface of a substrate, the method comprising the steps of:
applying a primer composition onto at least a portion of the surface of the substrate to conform to the image to be printed, wherein the primer composition comprises
a first part comprising a monofunctional alkyl acrylate monomer having a surface tension in the range of 23 to 31 dynes/cm, in which the alkyl group has at least 8 carbon atoms;
a second part comprising a photoinitiator; and
a curable third part comprising any of an oligomer, an acrylate monomer, or a mixture thereof, wherein at least a portion of the third part of the primer composition is multifunctional, and wherein the acrylate monomer is selected from the group consisting of alkoxylated diacrylates, alkoxylated triacrylates, amino acrylates, monofunctional acrylate monomers, and multifunctional acrylate monomers;
curing the applied primer composition; and
printing a UV curable ink jet ink on top of the surface of the cured primer composition;
wherein the first part of the primer composition is included in an amount that is selectably adjusted to produce a desired dot size of the printed UV curable ink jet ink.
2. The method of claim 1 , wherein the alkyl group of the alkyl acrylate is branched.
3. The method of claim 1 , wherein the alkyl acrylate is selected from the group consisting of isodecyl acrylate, isooctyl acrylate, 3,3,5-trimethylcyclohexyl acrylate and mixtures thereof.
4. The method of claim 1 , wherein the primer composition is unpigmented.
5. A method for printing an image on a surface of a substrate, the method comprising the steps of:
(a) applying a primer composition onto at least a portion of the surface of the substrate to conform to the image to be printed, wherein the primer composition comprises
a first part comprising a monofunctional alkyl acrylate having a surface tension of less than 30 dynes/cm, in which the alkyl group has at least 8 carbon atoms,
a second part comprising a photoinitiator, and
a third curable part comprising any of an oligomer, an acrylate monomer, or a mixture thereof, wherein at least a portion of the third part of the primer composition is multifunctional, and wherein the acrylate monomer is selected from the group consisting of alkoxylated diacrylates, alkoxylated triacrylates, amino acrylates, monofunctional acrylate monomers, and multifunctional acrylate monomers;
(b) curing the applied primer composition; and
(c) printing a radiation curable ink jet ink on top of the surface of the cured primer composition;
wherein the first part of the primer composition is included in an amount that is selectably adjusted to produce a desired dot size of the printed radiation curable ink jet ink.
6. The method of claim 5 , wherein the monofunctional alkyl acrylate comprises isodecyl acrylate, isooctyl acrylate, 3,3,5-trimethylcyclohexyl acrylate and mixtures thereof.
7. The method of claim 5 , wherein the radiation curable ink jet is a Grayscale ink, the method further comprising the step of:
adjusting the level of the first part of the primer composition to adjust the drop diameter of Grayscale ink.
8. The method of claim 5 , wherein the primer composition is unpigmented.
9. A method for printing an image on a surface of a substrate, the method comprising the steps of:
applying a clear primer composition onto at least a portion of the surface of the substrate to conform to the image to be printed, wherein the primer composition comprises
a first part comprising a monofunctional alkyl acrylate monomer having a surface tension in the range of 23 to 31 dynes/cm, in which the alkyl group has at least 8 carbon atoms;
a second part comprising a photoinitiator; and
a curable third part comprising any of an oligomer, an acrylate monomer, or a mixture thereof, wherein at least a portion of the third part of the primer composition is multifunctional, and wherein the acrylate monomer is selected from the group consisting of alkoxylated diacrylates, alkoxylated triacrylates, amino acrylates, monofunctional acrylate monomers, and multifunctional acrylate monomers;
curing the applied clear primer composition with actinic radiation; and
printing a UV curable ink jet ink at 300 DPI with a grey scale printhead on top of the surface of the cured clear primer composition, wherein the grey scale printhead has eight grey levels;
wherein the first part of the primer composition is included in an amount that is selectably adjusted to produce a desired dot size of the printed UV curable ink jet ink with the grey scale printhead without inhibiting the curing step, while comprising up to 30 percent by weight of the clear primer composition based on the total of radiation curable components in the clear primer composition.