A grind resin, a pigment dispersion, and a coating composition are provided. The grind resin comprises a reaction product of a dibasic acid, optionally a polybasic acid, a diol, optionally a polyol, and a fatty compound. The fatty compound has a fatty chain and two reactive groups reactive with at least one of the dibasic acid and the diol provided that ≦5% of all acid groups are provided by the polybasic acid and <20% of all hydroxyl groups are provided by the polyol. The reaction product is substantially free from branching comprising the reaction product of acid groups or hydroxyl groups and the dibasic acid, polybasic acid, diol, polyol, or fatty compound. The pigment dispersion comprises a pigment and the grind resin. The coating composition comprises a vehicle resin, the pigment, the grind resin, and a cross-linking agent reactive with the vehicle resin and/or the grind resin.
1. A grind resin comprising a reaction product of:
(a) a dibasic acid;
(b) optionally a polybasic acid;
(c) a diol;
(d) optionally a polyol; and
(e) a fatty compound having a fatty chain and two reactive groups reactive with at least one of said dibasic acid and said diol;
provided that less than or equal to 5% of all acid groups are provided by said polybasic acid, when present, and provided that less than 20% of all hydroxyl groups are provided by said polyol, when present;
wherein said fatty compound is present in an amount of from 5 to 20 parts by weight based on 100 parts by weight of all components before reaction to form said reaction product; wherein said dibasic acid is present in an amount of from 30 to 40 parts by weight based on 100 parts by weight of all components before reaction to form said reaction product;
wherein said reaction product is substantially free from branching comprising the reaction product of acid groups or hydroxyl groups and components (a), (b), (c), (d), or (e).
2. A grind resin as set forth in claim 1 wherein said fatty compound has from 18 to 60 carbon atoms.
3. A grind resin as set forth in claim 2 wherein said fatty compound has from 22 to 36 carbon atoms.
4. A grind resin as set forth in claim 1 wherein said fatty compound is selected from the group of dimer fatty acids, cyclic fatty acids, aromatic fatty acids, trimer fatty acids, and combinations thereof.
5. A grind resin as set forth in claim 1 wherein said fatty compound is selected from the group of dimer fatty diols, cyclic fatty diols, aromatic fatty diols, trimer fatty diols, and combinations thereof.
6. A grind resin as set forth in claim 1 wherein said dibasic acid is selected from the group of isophthalic acid, phthalic anhydride, adipic acid, hexahydrophthalic anhydride, and combinations thereof.
7. A grind resin as set forth in claim 1 wherein said polybasic acid has an average of from 2 to 4 acid groups per molecule.
8. A grind resin as set forth in claim 1 wherein said diol is selected from the group of neopentyl glycol, 2-methyl 1,3-propanediol, 1,6 hexanediol, 1,4 cyclohexane dimethol, and combinations thereof.
9. A grind resin as set forth in claim 1 wherein said diol is present in a stoichiometric excess on a molar basis.
10. A grind resin as set forth in claim 1 wherein said polyol has an average of from 2 to 4 hydroxyl groups per molecule.
11. A grind resin as set forth in claim 1 wherein said reaction product has an average of less than two branches per molecule resulting from reaction of acid groups or hydroxyl groups and said dibasic acid, said polybasic acid, said diol, said polyol, or said fatty compound.
12. A pigment dispersion for use in a coating composition comprising:
a pigment; and
a grind resin comprising a reaction product of:
(a) a dibasic acid;
(b) optionally a polybasic acid;
(c) a diol;
(d) optionally a polyol; and
(e) a fatty compound having a fatty chain and two reactive groups reactive with at least one of said dibasic acid and said diol;
provided that less than or equal to 5% of all acid groups are provided by said polybasic acid, when present, and provided that less than 20% of all hydroxyl groups are provided by said polyol, when present;
wherein said fatty compound is present in an amount of from 5 to 20 parts by weight based on 100 parts by weight of all components before reaction to form said reaction product; wherein said dibasic acid is present in an amount of from 30 to 40 parts by weight based on 100 parts by weight of all components before reaction to faun said reaction product;
wherein said reaction product is substantially free from branching comprising the reaction product of acid groups or hydroxyl groups and components (a), (b), (c), (d), or (e).
13. A pigment dispersion as set forth in claim 12 wherein said fatty compound has from 18 to 60 carbon atoms.
14. A pigment dispersion as set forth in claim 12 wherein said fatty compound has from 22 to 36 groups per molecule.
15. A pigment dispersion as set forth in claim 12 wherein the pigment is present in an amount of from 30 to 70 parts by weight based on 100 parts by weight of all components in said pigment dispersion.
16. A pigment dispersion as set forth in claim 12 having a change in viscosity of less than or equal to 15% after aging for fourteen days.
17. A pigment dispersion as set forth in claim 12 wherein the reaction product comprising the grind resin has an average of less than two branches per molecule resulting from reaction of acid groups or hydroxyl groups and said dibasic acid, said polybasic acid, said diol, said polyol, or said fatty compound.
18. A coating composition comprising:
a vehicle resin;
a pigment dispersion comprising:
a pigment; and
a grind resin comprising a reaction product of:
(a) a dibasic acid;
(b) optionally a polybasic acid;
(c) a diol;
(d) optionally a polyol; and
(e) a fatty compound having a fatty chain and two reactive groups reactive with at least one of said dibasic acid and said diol;
provided that less than or equal to 5% of all acid groups are provided by said polybasic acid, when present, and provided that less than 20% of all hydroxyl groups are provided by said polyol, when present;
wherein said fatty compound is present in an amount of from 5 to 20 parts by weight based on 100 parts by weight of all components before reaction to form said reaction product;
wherein said dibasic acid is present in an amount of from 30 to 40 parts by weight based on 100 parts by weight of all components before reaction to form said reaction product; and
a cross-linking agent reactive with said vehicle resin and/or said grind resin;
wherein said reaction product is substantially free from branching comprising the reaction product of acid groups or hydroxyl groups and components (a), (b), (c), (d), or (e).
19. A coating composition as set forth in claim 18 wherein the wherein the reaction product comprising the grind resin has an average of less than two branches per molecule resulting from reaction of acid groups or hydroxyl groups and said dibasic acid, said polybasic acid, said diol, said polyol, or said fatty compound.