IP Library Granted Patent US 9,192,889
Granted Patent B2
US 9,192,889 · App. 11/854,781 · Granted Nov 24, 2015

Bottom ash injection for enhancing spray dryer absorber performance

Inventor: Mikhail Maryamchik (Fairlawn, OH)
Assignee: The Babcock & Wilcox Company
B01D53/505B01D53/60F23C10/10F23J15/003F23J15/02B01D2257/2045B01D2257/2047B01D2257/302B01D2257/404F23J2219/60
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Quick Facts
Patent No.
US 9,192,889
App. No.
11/854,781
Granted
Nov 24, 2015
Kind
B2
Abstract

Alkali-containing bottom ash produced by a circulating fluidized bed (CFB) boiler is recycled to downstream spray dryer absorption (SDA) apparatus to more fully utilize the unused reagent present in the ash, and/or to reduce the amount of reagent used while not increasing NO x generation.

Claims (25)

1. A system for reducing the acid gas concentration in a combustion flue gas and/or reducing acid gas sorbent consumption while not increasing NO x generation, comprising:

a reactor for producing (i) combustion flue gas containing at least one acid compound, the at least one acid compound including at least one of sulfur dioxide, sulfur trioxide, hydrochloric acid, sulfuric acid, hydrofluoric acid or mixtures thereof, and (ii) bottom ash containing alkali, the bottom ash being discharged separately from the combustion flue gas, the reactor further comprising fluid cooled enclosure walls, the walls having a membrane tube wall construction, the reactor having a lower portion, an upper portion, and an exit opening;

a first particle collection area proximate the exit opening;

heat transfer surface proximate the first particle collection area;

a second particle collection area proximate the heat transfer surface;

an economizer proximate to said second particle collection area;

a spray dryer absorber, proximate to said economizer, for receiving the combustion flue gas;

means for introducing the bottom ash into the combustion flue gas downstream of the reactor at a location upstream of and/or within the spray dryer absorber so that the alkali is available in the spray dryer absorber for reacting with the at least one acid compound; and

means for introducing a humidifying agent into the spray dryer absorber to facilitate the reaction of the alkali with the at least one acid compound to reduce the acid gas concentration in the combustion flue gas, the humidifying agent including at least one of water and an alkali-containing slurry.

2. The system of claim 1 , wherein the reactor is a fluidized bed boiler.

3. The system of claim 2 , wherein the reactor is a circulating fluidized bed boiler.

4. The system of claim 1 , further comprising a bed drain secured below the lower portion and adapted to receive debris from the lower portion.

5. The system according to claim 1 , wherein said heat transfer surface is a superheater.

6. The system according to claim 1 , wherein the first particle collection area comprises a plurality of U-beam particle separators.

7. The system according to claim 1 , wherein the second particle collection area comprises a multicyclone dust collector.

8. A system for reducing the acid gas concentration in a combustion flue gas and/or reducing acid gas sorbent consumption while not increasing NO x generation, comprising:

a reactor for producing (i) combustion flue gas containing at least one acid compound, the at least one acid compound including at least one of sulfur dioxide, sulfur trioxide, hydrochloric acid, sulfuric acid, hydrofluoric acid or mixtures thereof, and (ii) bottom ash containing alkali, the bottom ash being discharged separately from the combustion flue gas, the reactor further comprising fluid cooled enclosure walls, the walls having a membrane tube wall construction, the reactor having a lower portion, an upper portion, and an exit opening;

a first particle collection area proximate the exit opening, the first particle collection area comprising a plurality of U-beam particle separators;

heat transfer surface proximate the first particle collection area;

a second particle collection area proximate the heat transfer surface, the second particle collection area comprising a multicyclone dust collector;

an economizer proximate to said second particle collection area;

a spray dryer absorber, proximate to said economizer, for receiving the combustion flue gas;

a particle collection means proximate said spray dryer absorber;

means for introducing the bottom ash into the combustion flue gas downstream of the reactor at a location upstream of and/or within the spray dryer absorber so that the alkali is available in the spray dryer absorber for reacting with the at least one acid compound; and

means for introducing a humidifying agent into the spray dryer absorber to facilitate the reaction of the alkali with the at least one acid compound to reduce the acid gas concentration in the combustion flue gas, the humidifying agent including at least one of water and an alkali-containing slurry.

Assignments (16)
SECURITY INTEREST Recorded Jul 18, 2025
From: BABCOCK & WILCOX ENTERPRISES, INC.; THE BABCOCK & WILCOX COMPANY; DIAMOND POWER INTERNATIONAL, LLC; BABCOCK & WILCOX SPIG, INC.; BABCOCK & WILCOX CANADA CORP.; BABCOCK & WILCOX FPS INC.
To: B. RILEY FINANCIAL, INC.
Reel/Frame 072053/0943 →
SECURITY INTEREST Recorded May 23, 2025
From: BABCOCK & WILCOX ENTERPRISES, INC.; THE BABCOCK & WILCOX COMPANY; DIAMOND POWER INTERNATIONAL, LLC; BABCOCK & WILCOX SPIG, INC.; BABCOCK & WILCOX CANADA CORP.; BABCOCK & WILCOX FPS INC.
To: GLAS TRUST COMPANY LLC
Reel/Frame 071371/0835 →
SECURITY INTEREST Recorded Mar 3, 2025
From: BABCOCK & WILCOX ENTERPRISES, INC.; THE BABCOCK & WILCOX COMPANY; DIAMOND POWER INTERNATIONAL, LLC; BABCOCK & WILCOX SPIG, INC.; BABCOCK & WILCOX CANADA CORP.; BABCOCK & WILCOX FPS INC.
To: PENSION BENEFIT GUARANTY CORPORATION
Reel/Frame 070380/0647 →
RELEASE OF SECURITY INTEREST Recorded Sep 13, 2024
From: MSD PCOF PARTNERS XLV, LLC
To: THE BABCOCK & WILCOX COMPANY; DIAMOND POWER INTERNATIONAL, LLC; AMERICON LLC
Reel/Frame 069017/0362 →
SECURITY INTEREST Recorded Jan 19, 2024
From: BABCOCK & WILCOX ENTERPRISES, INC.; THE BABCOCK & WILCOX COMPANY; DIAMOND POWER INTERNATIONAL, LLC; BABCOCK & WILCOX SPIG, INC.; BABCOCK & WILCOX CANADA CORP.; BABCOCK & WILCOX FPS INC.
To: AXOS BANK, AS ADMINISTRATIVE AGENT
Reel/Frame 066354/0765 →
SECURITY INTEREST Recorded Jul 22, 2021
From: THE BABCOCK & WILCOX COMPANY (F/K/A BABCOCK & WILCOX POWER GENERATION GROUP, INC.); BABCOCK & WILCOX SPIG, INC.; BABCOCK & WILCOX TECHNOLOGY, LLC; DIAMOND POWER INTERNATIONAL, LLC (F/K/A DIAMOND POWER INTERNATIONAL, INC.)
To: MSD PCOF PARTNERS XLV, LLC, AS AGENT
Reel/Frame 056962/0486 →
RELEASE OF SECURITY INTEREST Recorded Jul 1, 2021
From: BANK OF AMERICA, N.A.
To: DIAMOND POWER INTERNATIONAL, LLC (F/K/A DIAMOND POWER INTERNATIONAL, INC.); MEGTEC TURBOSONIC TECHNOLOGIES, INC.; THE BABCOCK & WILCOX COMPANY (F/K/A BABCOCK & WILCOX POWER GENERATION GROUP, INC.); BABCOCK & WILCOX SPIG, INC.; BABCOCK & WILCOX TECHNOLOGY, LLC (F/K/A MCDERMOTT TECHNOLOGY, INC.); SOFCO-EFS HOLDINGS LLC; BABCOCK & WILCOX MEGTEC, LLC
Reel/Frame 057337/0823 →
RELEASE OF SECURITY INTEREST Recorded May 17, 2018
From: LIGHTSHIP CAPITAL LLC
To: BABCOCK & WILCOX ENTERPRISES, INC.; THE BABCOCK & WILCOX COMPANY; DIAMOND POWER INTERNATIONAL, LLC; BABCOCK & WILCOX MEGTEC, LLC; MEGTEC TURBOSONIC TECHNOLOGIES, INC.; BABCOCK & WILCOX UNIVERSAL, INC.; BABCOCK & WILCOX TECHNOLOGY, LLC
Reel/Frame 046182/0829 →
SECURITY INTEREST Recorded Aug 10, 2017
From: THE BABCOCK & WILCOX COMPANY; DIAMOND POWER INTERNATIONAL, LLC; BABCOCK & WILCOX MEGTEC, LLC; MEGTEC TURBOSONIC TECHNOLOGIES, INC.; BABCOCK & WILCOX UNIVERSAL, INC.; BABCOCK & WILCOX TECHNOLOGY, LLC
To: LIGHTSHIP CAPITAL LLC
Reel/Frame 043515/0001 →
CHANGE OF NAME Recorded Oct 1, 2015
From: BABCOCK & WILCOX POWER GENERATION GROUP, INC.
To: THE BABCOCK & WILCOX COMPANY
Reel/Frame 036703/0187 →
SECURITY INTEREST Recorded Jul 28, 2015
From: BABCOCK & WILCOX POWER GENERATION GROUP, INC. (TO BE RENAMED THE BABCOCK AND WILCOX COMPANY)
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 036201/0598 →
CHANGE OF NAME Recorded Jul 31, 2014
From: THE BABCOCK & WILCOX COMPANY
To: BABCOCK & WILCOX POWER GENERATION GROUP, INC.
Reel/Frame 033452/0607 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Sep 30, 2010
From: BABCOCK & WILCOX POWER GENERATION GROUP, INC. (F.K.A. THE BABCOCK & WILCOX COMPANY)
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 025066/0080 →
RELEASE OF SECURITY INTEREST Recorded Aug 3, 2010
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: THE BABCOCK & WILCOX COMPANY; AMERICON EQUIPMENT SERVICES, INC.; AMERICON, INC.; APPLIED SYNERGISTICS, INC.; B & W SERVICE COMPANY; BABCOCK & WILCOX CHINA HOLDINGS, INC.; BABCOCK & WILCOX CONSTRUCTION CO., INC.; BABCOCK & WILCOX DENMARK HOLDINGS, INC.; BABCOCK & WILCOX EBENSBURG POWER, INC.; BABCOCK & WILCOX EQUITY INVESTMENTS, INC.; BABCOCK & WILCOX INTERNATIONAL SALES AND SERVICE CORPORATION; BABCOCK & WILCOX INTERNATIONAL, INC.; DIAMOND OPERATING CO., INC.; DIAMOND POWER AUSTRALIA HOLDINGS, INC.; DIAMOND POWER CHINA HOLDINGS, INC.; DIAMOND POWER EQUITY INVESTMENTS, INC.; DIAMOND POWER INTERNATIONAL, INC.; PALM BEACH RESOURCE RECOVERY CORPORATION; POWER SYSTEMS OPERATIONS, INC.; REVLOC RECLAMATION SERVICE, INC.; NATIONAL ECOLOGY COMPANY; NORTH COUNTY RECYCLING, INC.
Reel/Frame 024776/0693 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 4, 2008
From: MARYAMCHIK, MIKHAIL
To: THE BABCOCK & WILCOX COMPANY
Reel/Frame 021480/0328 →
AFTER-ACQUIRED INTELLECTUAL PROPERTY SECURITY AGREEMENT (THIRD SUPPLEMENTAL FILING) Recorded Apr 24, 2008
From: BABCOCK & WILCOX POWER GENERATION GROUP, INC. (FORMERLY KNOWN AS THE BABCOCK & WILCOX COMPANY)
To: CREDIT SUISSE, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 020857/0001 →
Continuity (1)
Related Publication 20090074629A1 · Mar 19, 2009