IP Library Granted Patent US 7,499,605
Granted Patent B1
US 7,499,605 · App. 11/855,457 · Granted Mar 3, 2009

Fiber Bragg grating for high temperature sensing

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Quick Facts
Patent No.
US 7,499,605
App. No.
11/855,457
Granted
Mar 3, 2009
Kind
B1
Abstract

A method of fiber core material band gap engineering for artificially modifying fiber material properties is provided. The method includes doping the fiber core material with one or more atoms for enhancing photosensitivity to the fiber material. The method also includes co-doping the fiber core material with one or more ions for enhancing an amorphous network crosslink mean coordination number. The method further includes thermally annealing the fiber core material for widening the band gap of the fiber core material.

Claims (44)

1. A method of fiber core material band-gap engineering for artificially modifying fiber material properties comprising:

doping the fiber core material with one or more atoms for enhancing photosensitivity to the fiber material;

co-doping the fiber core material with one or more ions for enhancing an amorphous network crosslink mean coordination number; and

thermally annealing the fiber core material for widening the band gap of the fiber core material.

2. The method of claim 1 , wherein the doping comprises doping with one or more atoms selected from a group consisting of germanium, boron, erbium and phosphorus.

3. The method of claim 1 , wherein the co-doping comprises co-doping with one or more ions selected from a group consisting of hydrogen, chlorine, bromine and iodine.

4. A method of fabrication of a thermally stabilized fiber Bragg grating-based temperature sensing device comprising:

doping a fiber core material for enhancing photosensitivity;

co-doping the fiber core material for increasing a mean coordination number;

inscribing a periodic or quaisperiodic modulated refractive index structure in the fiber core as a Type-I-like grating;

performing a band-gap engineering of the Type-I-like grating to prompt a growth of a Type IIA-like grating; and

structural processing of the Type-IIA-like grating and annealing to form a nanophase tetrahedral Type II-like grating structure.

5. The method of claim 4 , further comprising using a thermal band-gap engineering process after the inscribing to form a thermally stable intermediate phase structure.

6. The method of claim 4 , further comprising structural processing after the forming of the nanophase Type-II-like grating structure.

7. The method of claim 4 , wherein the inscribing comprises inscribing via a phase mask technique.

8. The method of claim 7 , wherein the phase mask technique comprises using a pulsed high-power UV laser or a near infrared femtosecond laser light.

9. The method of claim 4 , wherein the inscribing comprises using ultraviolet light to enable a photon-condensation process.

10. The method of claim 4 , wherein performing the band-gap engineering comprises thermally post-treating the Type-I-like grating for at least about 100 minutes to about 1000 minutes.

11. The method of claim 4 , wherein performing the band-gap engineering of the Type-I-like grating comprises thermal processing at a temperature of at least about 1000 K.

12. The method of claim 4 , wherein the structural processing of the Type-IIA-like grating comprises thermal post-treating at a temperature of at least about 1300 K.

13. The method of claim 4 , wherein performing the band-gap engineering comprises using an athermal process.

14. The method of claim 13 , wherein using the athermal process comprises using a laser.

15. A thermally stabilized fiber Bragg grating based sensor comprising:

a fiber core having a plurality of Bragg grating elements wherein, the grating elements comprise:

a periodic or a quasiperiodic modulated tetrahedral structure; and

an apodized grating profile;

a depressed cladding comprising at least one dopant disposed about the fiber core and configured to confine the at least one dopant within the fiber core; and

a cladding disposed around the depressed cladding.

16. The sensor of claim 15 , wherein the fiber core comprises a non-photosensitive fused quartz single mode fiber.

17. The sensor of claim 15 , wherein the fiber core comprises silicon dioxide doped with germanium dioxide.

18. The sensor of claim 15 , wherein the depressed cladding comprises silicon dioxide doped with at least one of chlorine, boron, phosphorous, erbium and fluorine.

19. The sensor of claim 15 , wherein the cladding comprises silicon dicoxide.

20. The sensor of claim 15 , wherein the fiber core is hydrogen loaded.

21. The sensor of claim 15 , wherein the sensor can sense temperatures upto at least about 1300 K.

22. The sensor of claim 15 , wherein the fiber core comprises a depressed cladding doped with at least one of fluorine or chlorine.

23. The sensor of claim 15 , wherein the fiber core is doped with germanium and hydrogen loaded.

24. The sensor of claim 15 , wherein the sensor senses a temperature based upon an associated temperature sensitivity for temperatures less than about 1200 K.

25. The sensor of claim 15 , wherein the sensor senses a temperature based upon an associated temperature sensitivity rate for temperatures more than 1200 K.

26. The sensor of claim 15 , wherein the apodized grating profile comprises a Gaussian profile.

27. The sensor of claim 15 , wherein the apodized grating profile comprises a cosine profile.

28. The sensor of claim 15 , wherein the fiber core comprises a periodic modulated nanophase structure.

29. The sensor of claim 15 , wherein the apodized grating profile comprises alternative constrained tetrahedral structure below a threshold of percolation in a low refractive index area of the fiber core and an overconstrained tetrahedral structure that is above a threshold of percolation in a high refractive index area of the fiber core.

30. The sensor of claim 29 , wherein the underconstrained structure and the overconstrained tetrahedral structure comprise a Type-IIA-like grating.

31. The sensor of claim 29 , wherein the constrained and the overconstrained tetrahedral structure comprise a Type-II-like grating.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 22, 2019
From: GENERAL ELECTRIC COMPANY
To: AIR PRODUCTS AND CHEMICALS, INC.
Reel/Frame 050786/0768 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 17, 2007
From: XIA, HUA; MCCARTHY, KEVIN THOMAS; DENG, KUNG-LI JUSTIN; LOPEZ, FULTON JOSE; AVAGLIANO, AARON JOHN
To: GENERAL ELECTRIC COMPANY
Reel/Frame 019833/0720 →