Poly(arylene ether) composition and article
View Patent ↗A composition includes specific amounts of a high molecular weight poly(arylene ether), a rubber-modified polystyrene, and a hydrogenated block copolymer. The use of the high molecular weight poly(arylene ether) unexpectedly provides substantially improved durability to articles molded from the composition. The composition is particularly useful for molding hot water pipes and fittings.
1. A composition, comprising:
50 to 90 weight percent of a poly(arylene ether); wherein the poly(arylene ether) consists of poly(arylene ether) having a weight average molecular weight of 85,000 to 120,000 atomic mass units;
10 to 30 weight percent of a rubber-modified polystyrene comprising 80 to 96 weight percent polystyrene and 4 to 20 weight percent polybutadiene; and
2 to 10 weight percent of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene, wherein the hydrogenated block copolymer has a poly(alkenyl aromatic) content of 10 to 40 weight percent;
wherein all weight percents are based on the total weight of the composition; and
wherein an article molded from the composition exhibits
a tensile stress at yield of at least 65 megapascals measured at 23° C. according to ISO 527,
a notched Izod impact strength of at least 15 kilojoules/meter 2 measured at 23° C. according to ISO 180/A1,
a tensile fatigue resistance of at least 100,000 cycles measured at 23° C., 25 megapascals, and 5 Hertz, and
a creep rupture resistance of at least 150 hours measured at a hoop stress of 18 megapascals according to ISO 1167.
2. The composition of claim 1 , wherein an article molded from the composition exhibits
a tensile stress at yield of 65 to 70 megapascals measured at 23° C. according to ISO 527,
a notched Izod impact strength of 15 to 24 kilojoules/meter 2 measured at 23° C. according to ISO 180/A1,
a tensile fatigue resistance of 100,000 to 180,000 cycles measured at 23° C., 25 megapascals, and 5 Hertz, and
a creep rupture resistance of 150 to 250 hours measured at a hoop stress of 18 megapascals according to ISO 1167.
3. The composition of claim 1 , wherein an article molded from the composition exhibits a flexural stress of at least 80 to 110 megapascals measured at 23° C. according to ISO 178.
4. The composition of claim 3 , wherein the flexural stress is 80 to 110 megapascals measured at 23° C. according to ISO 178.
5. The composition of claim 1 , wherein an article molded from the composition exhibits a tensile knitline strength at yield of 50 to 61 megapascals measured on a double-gated tensile bar at 23° C. according to ISO 527.
6. The composition of claim 1 , wherein the rubber-modified polystyrene comprises 88 to 94 weight percent polystyrene and about 6 to about 12 weight percent polybutadiene.
7. The composition of claim 1 , wherein the hydrogenated block copolymer is a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer having a weight average molecular weight of 250,000 to 450,000 atomic mass units.
8. The composition of claim 1 ,
wherein the composition comprises 66 to 74 weight percent of the poly(arylene ether);
wherein the poly(arylene ether) consists of poly(2,6-dimethyl-1,4-phenylene ether) having a weight average molecular weight of 88,000 to 92,000 atomic mass units;
wherein the composition comprises 20 to 25 weight percent of the rubber-modified polystyrene;
wherein the rubber-modified polystyrene comprises 88 to 94 weight percent polystyrene and about 6 to about 12 weight percent polybutadiene;
wherein the composition comprises 3 to 7 weight percent of the hydrogenated block copolymer;
wherein the hydrogenated block copolymer is a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer having a weight average molecular weight of 250,000 to 450,000 atomic mass units; and
wherein an article molded from the composition exhibits
a tensile stress at yield of 65 to 70 megapascals measured at 23° C. according to ISO 527,
a notched Izod impact strength of 15 to 21 kilojoules/meter 2 measured at 23° C. according to ISO 180/A1,
a tensile fatigue resistance of 100,000 to 180,000 cycles measured at 23° C., 25 megapascals, and 5 Hertz, and
a creep rupture resistance of 150 to 250 hours measured at a hoop stress of 18 megapascals according to ISO 1167.
9. The composition of claim 8 , wherein the composition consists of
the poly(arylene ether);
the rubber-modified polystyrene;
the hydrogenated block copolymer; and
optionally, less than or equal to 5 weight percent of an additive selected from the group consisting of stabilizers, mold release agents, processing aids, flame retardants, drip retardants, nucleating agents, UV blockers, dyes, pigments, antioxidants, anti-static agents, blowing agents, mineral oil, metal deactivators, antiblocking agents, and the like, and combinations thereof.
10. An article comprising a composition comprising:
50 to 90 weight percent of a poly(arylene ether) consisting of poly(arylene ether) having a weight average molecular weight of 85,000 to 95,000 atomic mass units;
10 to 30 weight percent of a rubber-modified polystyrene comprising 80 to 96 weight percent polystyrene and 4 to 20 weight percent polybutadiene; and
2 to 10 weight percent of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene, wherein the hydrogenated block copolymer has a poly(alkenyl aromatic) content of 10 to 40 weight percent;
wherein all weight percents are based on the total weight of the composition; and
wherein an article molded from the composition exhibits
a tensile stress at yield of at least 65 megapascals measured at 23° C. according to ISO 527,
a notched Izod impact strength of at least 15 kilojoules/meter 2 measured at 23° C. according to ISO 180/A1,
a tensile fatigue resistance of at least 100,000 cycles measured at 23° C., 25 megapascals, and 5 Hertz, and
a rupture resistance of at least 150 hours measured at a hoop stress of 18 megapascals according to ISO 1167.
11. The article of claim 10 , wherein the article is a hot water fitting.
12. The article of claim 10 ,
wherein the composition comprises 66 to 74 weight percent of the poly(arylene ether);
wherein the poly(arylene ether) consists of poly(2,6-dimethyl-1,4-phenylene ether) having a weight average molecular weight of 88,000 to 92,000 atomic mass units;
wherein the composition comprises 20 to 25 weight percent of the rubber-modified polystyrene;
wherein the rubber-modified polystyrene comprises 88 to 94 weight percent polystyrene and about 6 to about 12 weight percent polybutadiene;
wherein the composition comprises 3 to 7 weight percent of the hydrogenated block copolymer;
wherein the hydrogenated block copolymer is a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer having a weight average molecular weight of 250,000 to 450,000 atomic mass units; and
wherein an article molded from the composition exhibits
a tensile stress at yield of 65 to 70 megapascals measured at 23° C. according to ISO 527,
a notched Izod impact strength of 15 to 21 kilojoules/meter 2 measured at 23° C. according to ISO 180/A1,
a tensile fatigue resistance of 100,000 to 180,000 cycles measured at 23° C., 25 megapascals, and 5 Hertz, and
a creep rupture resistance of 150 to 250 hours measured at a hoop stress of 18 megapascals according to ISO 1167.
13. The article of claim 12 , wherein the article is a hot water fitting.
14. A method of increasing the tensile fatigue resistance of a hot water fitting comprising a poly(arylene ether) composition, comprising:
fabricating a hot water fitting from a poly(arylene ether) composition; and
employing a poly(arylene ether) consisting of poly(arylene ether) having a weight average molecular weight of 85,000 to 120,000 atomic mass units in the poly(arylene ether) composition;
wherein the poly(arylene ether) composition comprises
50 to 90 weight percent of the poly(arylene ether),
10 to 30 weight percent of a rubber-modified polystyrene comprising 80 to 96 weight percent polystyrene and 4 to 20 weight percent polybutadiene, and
2 to 10 weight percent of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene, wherein the hydrogenated block copolymer has a poly(alkenyl aromatic) content of 10 to 40 weight percent;
wherein all weight percents are based on the total weight of the composition; and
wherein an article molded from the composition exhibits
a tensile fatigue resistance of at least 100,000 cycles measured at 23° C., 25 megapascals, and 5 Hertz,
a notched Izod impact strength of 15 to 21 kilojoules/meter 2 measured at 23° C. according to ISO 180/A1,
a tensile stress at yield of at least 65 megapascals measured at 23° C. according to ISO 527, and
a creep rupture resistance of at least 150 hours measured at a hoop stress of 18 megapascals according to ISO 1167.