High heat polycarbonates, methods of making, and articles formed therefrom
View Patent ↗Disclosed herein is a polymer blend comprising a first polycarbonate comprising a first structural unit derived from a 2-aryl-3,3-bis(4-hydroxyaryl)phthalimidine and a second structural unit derived from a dihydroxy aromatic compound, wherein the second structural unit is not identical to the first structural unit, and a second polycarbonate comprising a structural unit derived from a dihydroxy aromatic compound, wherein the polymer blend has a glass transition temperature of 155 to 200° C.; and wherein a test auricle having a thickness of 3.2 mm and molded from the blend has a haze of less than or equal to 3.0 measured in accordance with ASTM D1003-00. A method of making the polymer blend, and articles prepared from the blend, are also disclosed.
1. A thermoplastic composition comprising a polymer blend comprising:
a first polycarbonate comprising a first structural unit derived from a dihydroxy aromatic compound having the formula (10):
wherein R 3 is an aryl group having 6 to 25 carbon atoms, and R 2 is selected from the group consisting of a hydrogen, a C 1-25 hydrocarbyl group, and a halogen, and
a second structural unit derived from a dihydroxy aromatic compound, where the second structural unit is not identical to the first structural unit, wherein the first polycarbonate has a weight averaged molecular weight of less than 32,000 g/mol as measured according to gel permeation chromatography calibrated to polycarbonate standards, and
a second polycarbonate, different than the first polycarbonate, derived from dihydroxy aromatic compounds not identical to formula (10);
an acid additive, and
an epoxy additive;
wherein the polymer blend has a glass transition temperature of 155 to 200° C.;
wherein the first polycarbonate has greater than 25 and less than 35 mol % of the first structural unit, based on the total moles of first and second structural units in the first polycarbonate, and the first polycarbonate is present in the blend in an amount of 10 to 90 wt % based on the total weight of the first polycarbonate and the second polycarbonate; and
wherein a test article having a thickness of 3.2 mm and molded from the blend has a haze of less than or equal to 2.6% measured in accordance with ASTM D1003-00.
2. The thermoplastic composition of claim 1 , wherein the acid additive has a pKa of less than or equal to 4.5.
3. The thermoplastic composition of claim 2 , wherein the acid additive is p-toluenesulfonic acid.
4. The thermoplastic composition of claim 1 , wherein the acid additive is present in an amount of up to 50 ppm by weight based on the weight of the polymer blend.
5. The thermoplastic composition of claim 4 , wherein the acid additive is present in an amount of 0.1 to 20 ppm by weight based on the weight of the polymer blend.
6. The thermoplastic composition of claim 2 , wherein the acid additive is phosphorous acid.
7. The thermoplastic composition of claim 1 , wherein the epoxy additive is a styrene-acrylate-epoxy polymer, or an epoxy carboxylate oligomer or polymer, or a combination of a styrene-acrylate-epoxy polymer, or an epoxy carboxylate oligomer or polymer.
8. The thermoplastic composition of claim 7 , wherein the epoxy additive is present in an amount of 0.001 to 1.0 wt %, based on the weight of polymer blend.
9. The thermoplastic composition of claim 1 , wherein a molded article having a thickness of 3.2 millimeters and consisting of the polymer blend, acid additive, and epoxy additive has a yellowness index (YI) of less than or equal to 10 measured according to ASTM D1925-70.
10. The thermoplastic composition of claim 9 , wherein a molded article having a thickness of 3.2 millimeters and consisting of the polymer blend, acid additive, and epoxy additive has a yellowness index (YI) of less than or equal to 5 measured according to ASTM D1925-70.
11. The thermoplastic composition of claim 1 , wherein a molded article having a thickness of 3.2 millimeters and comprising the thermoplastic composition exhibits a reduction in weight averaged molecular weight (Mw) for the component polycarbonates of less than or equal to 12%, on exposure to combined heat and moisture conditions of 80° C. and 80% relative humidity for 1 week.
12. A transparent thermoplastic composition comprising a polymer blend comprising:
a polycarbonate comprising a first structural unit derived from a dihydroxy aromatic compound having the formula (10):
wherein R 3 is an aryl group having 6 to 25 carbon atoms, and R 2 is selected from the group consisting of a hydrogen, a C 1-25 hydrocarbyl group, and a halogen, and
a second structural unit derived from a dihydroxy aromatic compound, and the second structural unit is not identical to the first structural unit; wherein the polycarbonate has greater than 25 and less than 35 mol % of the first structural unit, based on the total moles of first and second structural units in the polycarbonate;
an acid additive wherein the acid additive has a pKa of less than or equal to 4.5, and
an epoxy additive wherein the epoxy additive is a styrene-acrylate-epoxy polymer, or a combination of a styrene-acrylate-epoxy polymer and an epoxy carboxylate oligomer or polymer;
wherein the polymer blend has a glass transition temperature of 155 to 200° C., and wherein a molded article having a thickness of 3.2 millimeters and comprising the thermoplastic composition exhibits a reduction in weight averaged molecular weight (Mw) for the component polycarbonates of less than or equal to 12%, on exposure to combined heat and moisture conditions of 80° C. and 80% relative humidity for 1 week.
13. The composition of claim 12 , wherein the first polycarbonate is an interfacial polymerized polycarbonate.