Lithium-ion capacitor
View Patent ↗The invention provides a negative electrode material for use with a lithium-ion capacitor, which is high in energy density, output density and excellent in durability. When graphite of which an average distance between 002 lattice planes thereof is within a range from 0.335 nm to 0.337 nm is used for an active material of a negative electrode of a lithium-ion capacitor, the energy density of the capacitor is increased. The output characteristic and the cycle durability can be improved when D 10 , D 50 and D 90 are set within predetermined ranges.
1. A lithium-ion capacitor comprising a positive electrode, a negative electrode and an electrolyte having an aprotic organic solvent of a lithium salt, wherein a negative electrode active material is graphite defined by the following formula:
( D 90 −D 10 )≦7.0 μm
wherein a capacitance of the negative electrode per unit weight is equal to or larger than three times as large as a capacitance of the positive electrode per unit weight, and the weight of the positive electrode active material is larger than that of the negative electrode active material.
2. The lithium-ion capacitor according to claim 1 , wherein D 50 of the graphite is given by D 50 ≦4.0 μm.
3. The lithium-ion capacitor according to claim 2 , wherein the positive electrode active material allows lithium ions and/or anions to be reversibly doped thereinto and de-doped therefrom,
the negative electrode active material allows lithium ions to be reversibly doped thereinto and de-doped therefrom, and
a potential of the positive electrode when the positive electrode and the negative electrode are shortcircuited is 2 V (vs. Li/Li + ) or lower.
4. The lithium-ion capacitor according to claim 1 , wherein an average distance between 002 lattice planes of the graphite, as measured by X-ray diffraction, is within a range from 0.335 nm to 0.337 nm.
5. The lithium-ion capacitor according to claim 1 , wherein the doping of lithium ions is performed when the negative electrode and/or the positive electrode is electrochemically contacted with a lithium ion source, which is located facing the negative electrode and/or positive electrode.
6. The lithium-ion capacitor according to claim 1 , wherein the positive electrode and the negative electrode include current collectors having through holes.