Organic powder useful as the replacement of mineral filler in composites
View Patent ↗This invention is about organic powder materials useful as the replacement of mineral or inorganic fillers in composites. The organic powder materials have particle size less than 60 μm and are visually non-differentiable in composites. The gel coat materials with the organic powder have uniform color appearance and have improved color stability when exposed to moisture.
1. An organic powder filler comprising from about 50 to 100 wt %, based on the total weight of the filler, of an organic material having a glass transition temperature above 50° C. and comprising a cured or crosslinked reaction product of at least selected from the group consisting of an unsaturated polyester resin, unsaturated polyester/polyurethane hybrid resin, cross-linkable acrylic, melamine, and a thermoplastic polymer that is neither soluble in, nor swells in, ethylenically unsaturated monomers,
wherein the cured or crosslinked reaction product has less than 10 wt % volatile content and a degree of cure above 70%, and
the organic powder filler is in the form of particles having a maximum particle size less than 60 μm.
2. The organic powder filler of claim 1 , wherein the particle size is in the range of about 0.1 to about 45 μm.
3. The organic powder filler of claim 1 , wherein the particles are visually non-differentiable from a composite matrix when the particles are incorporated into composites.
4. The organic powder filler of claim 1 , wherein the organic material has a glass transition temperature above 60° C.
5. The organic powder filler of claim 1 , wherein the cured or crosslinked reaction product has a degree of cure above 80%.
6. The organic powder filler of claim 1 , wherein the cured or crosslinked reaction product has less than 5% volatile content.
7. The organic powder filler of claim 1 , wherein the reaction product is produced by adding an initiator and promoter to the unsaturated polyester resin, unsaturated polyester/polyurethane hybrid resin, cross-linkable acrylic, or melamine to form a curable mixture, and curing the curable mixture by curing at ambient temperature, heating the mixture, exposing the mixture to UV light, or exposing the mixture to microwave; and
the cured mixture is reduced in size to form the particles of the organic powder filler.
8. The organic powder filler of claim 7 , wherein the reaction product is further post-cured at an elevated temperature to increase the degree of cure and reduce the volatile content.
9. A gel coat composition comprising an organic powder filler comprising about 50 to 100 wt % of an organic material, based on the total weight of filler in the gel coat composition, the organic material having a glass transition temperature above 50° C. and comprising a cured or crosslinked reaction product of at least selected from the group consisting of an unsaturated polyester resin, unsaturated polyester/polyurethane hybrid resin, cross-linkable acrylic, melamine, and a thermoplastic polymer that is neither soluble in, nor swells in, ethylenically unsaturated monomers,
wherein the organic powder filler is in the form of particles having a maximum particle size less than 60 μm and present in an amount from about 10 to about 50 wt %, based on the total weight of the gel coat composition.
10. The gel coat composition of claim 9 , wherein the particles are visually non-differentiable from the gel coat.
11. The gel coat composition of claim 9 , further comprising reactive ethylenically unsaturated monomers.
12. The gel coat composition of claim 9 , wherein the gel coat composition has a HAP value less than 37 wt %.
13. A gel coat obtained by curing the gel coat composition of claim 9 .
14. An article comprising the gel coat of claim 13 .