Photocurable composition, micropattern-formed product and its production process
View Patent ↗A photocurable composition capable of producing a micropattern-formed product efficiently, which is excellent in physical properties such as heat resistance, chemical resistance, releasability and optical characteristics (transmittance and low refractive index), and a process for producing a micropattern-formed product, capable of highly precisely transferring a micropattern of a mold to its surface are provided. A photocurable composition which comprises from 50 to 98 mass % of a monomer containing no fluorine atom and having a viscosity at 25° C. of from 0.1 to 100 mPa·s, from 0.1 to 45 mass % of a fluoromonomer, from more than 0.1 to 20 mass % of a fluorinated surfactant and/or a fluoropolymer and from 1 to 10 mass % of a photopolymerization initiator, and contains substantially no solvent. A process for producing a micropattern-formed product comprising a cured product having a micropattern of a mold transferred on its surface, or such a micropattern-formed product integrated with a substrate, which uses the photocurable composition, a substrate and a mold having a micropattern.
1. A process for producing a micropattern-formed product, which comprises
bringing a photocurable composition which comprises from 50 to 98 mass % of a monomer containing no fluorine atom and having a viscosity at 25° C. of from 0.1 to 100 mPa·s, from 0.1 to 45 mass % of a fluoromonomer, from more than 0.1 to 20 mass % of a fluorinated surfactant and/or a fluoropolymer and from 1 to 10 mass % of a photopolymerization initiator, and contains substantially no solvent, into contact with the micropatterned surface of a mold having a micropattern formed on the surface,
photo-curing the photocurable composition in a state where it is in contact with the surface of the mold, and
separating a cured product of the photocurable composition from the mold.
2. The process for producing a micropattern-formed product according to claim 1 , wherein the micropattern of the mold is a micropattern having convex portions and concavo portions, and the average interval of the convex portions is from 1 nm to 500 μm.
3. The process of claim 1 , wherein the photocurable composition comprises an adamantyl group-containing acrylate monomer unit and a polyoxyalkylene acrylate monomer unit.
4. The method of claim 1 , wherein the photocurable composition comprises a fluoroacrylate monomer unit.
5. The method of claim 1 , wherein the photocurable composition comprises a fluoropolymer surfactant.
6. The method of claim 5 , wherein the fluoropolymer surfactant consists of C atoms, F atoms, H atoms, and O atoms.
7. A process for producing a micropattern-formed product, which comprises
carrying out the following steps A, B, C and as the case requires, step D, in this order with a photocurable composition comprising from 50 to 98 mass % of a monomer containing no fluorine atom and having a viscosity at 25° C. of from 0.1 to 100 mPa·s, from 0.1 to 45 mass % of a fluoromonomer, from more than 0.1 to 20 mass % of a fluorinated surfactant and/or a fluoropolymer and from 1 to 10 mass % of a photopolymerization initiator, and contains substantially no solvent, a substrate and a mold having a micropattern on its surface to obtain a micropattern-formed product having a micropattern on its surface or such a micropattern-formed product integrated with the substrate:
step A: a step of sandwiching and pressing the photocurable composition between the surface of the substrate and the patterned surface of the mold;
step B: a step of curing the photocurable composition by light irradiation to obtain a micropattern-formed product comprising a cured product having the micropattern of the mold transferred on its surface;
step C: a step of separating at least one of the mold and the substrate from the cured product to obtain a micropattern-formed product, a micropattern-formed product integrated with the substrate or a micropattern-formed product integrated with the mold; and
step D: a step of separating the micropattern-formed product from the mold in a case where the micropattern-formed product integrated with the mold is obtained in the step C.
8. The process of claim 7 , wherein the photocurable composition comprises an adamantyl group-containing acrylate monomer unit and a polyoxyalkylene acrylate monomer unit.
9. The method of claim 7 , wherein the photocurable composition comprises a fluoroacrylate monomer unit.
10. The method of claim 7 , wherein the photocurable composition comprises a fluoropolymer surfactant.
11. The method of claim 7 , wherein the fluoropolymer surfactant consists of C atoms, F atoms, H atoms, and O atoms.
12. A process for producing a micropattern-formed product, which comprises
bringing a photocurable composition which comprises from 50 to 98 mass % of a monomer containing no fluorine atom and having a viscosity at 25° C. of from 0.1 to 100 mPa·s, from 0.1 to 45 mass % of a fluoromonomer, from more than 0.1 to 20 mass % of a fluorinated surfactant and/or a fluoropolymer and from 1 to 10 mass % of a photopolymerization initiator, and contains substantially no solvent, into contact with the micropatterned surface of a mold having a micropattern formed on the surface,
separating the mold to produce a molded product of the photocurable composition having the micropattern of the mold transferred on its surface, and
photo-curing the molded product of the photocurable composition.
13. The process of claim 12 , wherein the photocurable composition comprises an adamantyl group-containing acrylate monomer unit and a polyoxyalkylene acrylate monomer unit.
14. The method of claim 12 , wherein the photocurable composition comprises a fluoroacrylate monomer unit.
15. The method of claim 12 , wherein the photocurable composition comprises a fluoropolymer surfactant.
16. The method of claim 12 , wherein the fluoropolymer surfactant consists of C atoms, F atoms, H atoms, and O atoms.
17. A process for producing a micropattern-formed product, which comprises carrying out the following steps E, F, G and as the case requires, step H, in this order with a photocurable composition comprising from 50 to 98 mass % of a monomer containing no fluorine atom and having a viscosity at 25° C. of from 0.1 to 100 mPa·s, from 0.1 to 45 mass % of a fluoromonomer, from more than 0.1 to 20 mass % of a fluorinated surfactant and/or a fluoropolymer and from 1 to 10 mass % of a photopolymerization initiator, and contains substantially no solvent, a substrate and a mold having a micropattern on its surface to obtain a micropattern-formed product having a micropattern on its surface or such a micropattern-formed product integrated with the substrate:
step E: a step of pressing the photocurable composition between the surface of the substrate and the patterned surface of the mold;
step F: a step of separating the mold from the photocurable composition to obtain a molded product of the photocurable composition having the micropattern of the mold transferred on its surface, integrated with the substrate;
step G: a step of curing the molded product of the photocurable composition by light irradiation to obtain a micropattern-formed product comprising a cured product having the micropattern of the mold transferred on its surface, integrated with the substrate; and
step H: a step of separating the micropattern-formed product from the substrate.
18. The process for producing a micropattern-formed product according to claim 17 , wherein the micropattern of the mold is a micropattern having convex portions and concavo portions, and the average interval of the convex portions is from 1 nm to 500 μm.
19. The process of claim 17 , wherein the photocurable composition comprises an adamantyl group-containing acrylate monomer unit and a polyoxyalkylene acrylate monomer unit.
20. The method of claim 17 , wherein the photocurable composition comprises a fluoroacrylate monomer unit.
21. The method of claim 17 , wherein the photocurable composition comprises a fluoropolymer surfactant.
22. The method of claim 17 , wherein the fluoropolymer surfactant consists of C atoms, F atoms, H atoms, and O atoms.