Hydrophobically modifed poly[ethylene glycol] for use in pitch and stickies control in pulp and papermaking processes
Methods for inhibiting the depositions of organic contaminants from pulp in pulp and papermaking systems are disclosed. Hydrophobically modified poly[ethylene glycol] are added to the pulp or applied to deposition-prone surfaces of a papermaking system.
1. A method of inhibiting the deposition of organic contaminants in pulp or papermaking systems comprising adding to the pulp or papermaking system an effective deposition inhibiting amount of a hydrophobically modified poly[ethylene glycol] composition comprising the formula:
(R 1 —) x —O—[—CH 2 —CH 2 —O—] n —(—R 2 ) y —Z
wherein R 1 and R 2 are a hydrophobic moiety, or blocks of hydrophobic moieties of x and y repeat units, covalently bonded to poly[ethylene glycol]; n is 10 to 700; x is 1 to 4; y is 0 to 4; Z is only present when y=0 and is hydrogen; the sum of x and y is greater than or equal to 2 and not greater than 5.5, and
wherein said hydrophobically modified poly[ethylene glycol] composition is derived from the reaction of a polyethylene glycol and a hydrophobic reagent, the reagent selected from the group consisting of a ketene dimer, a glycidyl ether and alkenyl succinic anhydride; and
wherein the viscosity of a 5 wt % concentration of the hydrophobically modified poly[ethylene glycol] composition is from about 1 cP to about 10,000 cP.
2. The method of claim 1 wherein the hydrophobically modified poly[ethylene glycol] composition is added to the pulp in an amount of at least about 0.1 ppm based on the amount of pulp in the system.
3. The method of claim 1 wherein the hydrophobically modified poly[ethylene glycol] composition is added as an aqueous solution.
4. The method of claim 1 wherein the hydrophobically modified poly[ethylene glycol] composition is added as a dispersion in an aqueous salt solution.
5. The method of claim 4 wherein the salt is sodium formate.
6. The method of claim 3 wherein the solution contains a viscosity modifier adjunct.
7. The method according to claim 6 wherein the viscosity modifier adjunct is a cyclodextrin and/or a surfactant.
8. The method of claim 1 wherein the organic contaminants are stickies deposits.
9. The method of claim 1 wherein the organic contaminants are pitch deposits.
10. The method of claim 1 wherein said hydrophobically modified poly[ethylene glycol] composition has the formula:
wherein n is 10 to 700; R 4 and R 5 are linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having from 4 to 20 carbon atoms, or mixtures thereof; x is 1 to 4; y is 0 to 4; the sum of x and y is from 2 to 5.5.
11. The method of claim 1 wherein the hydrophobically modified poly[ethylene glycol] is applied to the surfaces of papermaking machinery and equipment.
12. The method of claim 11 wherein the surfaces are selected from the group consisting of the wire, press felts, and press rolls.
13. The method of claim 11 wherein the hydrophobically modified poly[ethylene glycol] composition is in an aqueous solution.
14. The method of claim 11 wherein the hydrophobically modified poly[ethylene glycol] composition is applied in the form of a dispersion in an aqueous salt solution.
15. The method of claim 13 wherein the solution contains a viscosity modifier adjunct.
16. The method according to claim 15 wherein the viscosity modifier adjunct is a cyclodextrin and/or a surfactant.
17. The method of claim 11 wherein the organic contaminants are stickies deposits.
18. The method of claim 11 wherein the organic contaminants are pitch deposits.
19. The method of claim 11 wherein said hydrophobically modified poly[ethylene glycol] composition is derived by the reaction of polyethylene glycol with a glycidyl ether to yield a compound with the following formula:
wherein n is 10 to 700; R 4 and R 5 are linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having from 4 to 20 carbon atoms, or mixtures thereof; x is 1 to 4; y is 0 to 4; the sum of x and y is from 2 to 5.5.
20. A method of inhibiting the deposition of organic contaminants in pulp or papermaking systems comprising adding to the pulp or papermaking system an effective deposition inhibiting amount of a hydrophobically modified poly[ethylene glycol] composition comprising the formula:
(R 1 —) x —O—[—CH 2 —CH 2 —O—] n —(—R 2 ) y —Z
wherein R 1 and R 2 are a hydrophobic moiety, or blocks of hydrophobic moieties of x and y repeat units, covalently bonded to poly[ethylene glycol]; 10 to 700; 1 to 4; y is 0 to 4; Z is only present when y=0 and is hydrogen; the sum of x and y is greater than or equal to 2 and not greater than 5.5, and
wherein said hydrophobically modified poly[ethylene glycol] composition is derived from the reaction of a polyethylene glycol and a glycidyl ether; and
wherein the viscosity of a 5 wt % concentration of the hydrophobically modified poly[ethylene glycol] composition is from about 1 cP to about 10,000 cP.