Hydrophilic sealants
The present invention provides water swellable one-component sealants prepared by incorporation of polyols containing ethylene oxide (“EO”) into the backbone of the polymer. The inventive one-component hydrophilic polyurethane sealant contains a silane-terminated polyurethane prepolymer, a compound having an ethylene oxide content of at least about 40 wt. %, based on the weight of the compound and a catalyst, optionally, one or more of plasticizers, fillers, pigments, drying agents, light stabilizers, antioxidants. thixotropic agents and bonding agents. The one-component hydrophilic polyurethane sealant increases at least about 1.4% by weight and at least about 2.5% by volume upon exposure to water for 24 hours and are capable of curing in a high humidity environment (including underwater) without foaming and maintain physical characteristics such as hardness.
1 . A one-component hydrophilic polyurethane sealant comprising:
a silane-terminated polyurethane prepolymer;
a compound having an ethylene oxide content of at least about 40 wt. %, based on the weight of the compound; and
a catalyst,
optionally, one or more of plasticizers, fillers, pigments, drying agents, light stabilizers, antioxidants. thixotropic agents and bonding agents,
wherein the one-component hydrophilic polyurethane sealant increases at least about 1.4% by weight and at least about 2.5% by volume upon exposure to water for 24 hours.
2 . The one-component hydrophilic polyurethane sealant according to claim 1 , wherein the compound having an ethylene oxide content has an ethylene oxide content of at least about 60 wt. %, based on the weight of the compound.
3 . The one-component hydrophilic polyurethane sealant according to claim 1 , wherein the compound having an ethylene oxide content has an ethylene oxide content of at least about 70 wt. %, based on the weight of the compound.
4 . The one-component hydrophilic polyurethane sealant according to claim 1 , wherein the compound having an ethylene oxide content has an ethylene oxide content of at least about 80 wt. %, based on the weight of the compound.
5 . The one-component hydrophilic polyurethane sealant according to claim 1 , wherein the compound having an ethylene oxide content is selected from the group consisting of ethylene oxide capped polyols, ethylene oxide monools, and ethylene oxide polyols.
6 . The one-component hydrophilic polyurethane sealant according to claim 1 , wherein the compound having an ethylene oxide content is a mixture of ethylene oxide containing amines and polyols.
7 . The one-component hydrophilic polyurethane sealant according to claim 1 , wherein the silane-terminated polyurethane prepolymer contains ethylene oxide.
8 . The one-component hydrophilic polyurethane sealant according to claim 1 , wherein the sealant increases at least about 5% by weight and at least about 5% by volume upon exposure to water for 24 hours.
9 . The one-component hydrophilic polyurethane sealant according to claim 1 , wherein the sealant increases at least about 10% by weight and at least about 10% by volume upon exposure to water for 24 hours.
10 . A process for the production of a one-component hydrophilic polyurethane sealant comprising combining:
a silane-terminated polyurethane prepolymer;
a compound having an ethylene oxide content of at least about 40 wt. %, based on the weight of the compound; and
a catalyst,
optionally, one or more of plasticizers, fillers, pigments, drying agents, light stabilizers, antioxidants. thixotropic agents and bonding agents,
wherein the one-component hydrophilic polyurethane sealant increases at least about 1.4% by weight and at least about 2.5% by volume upon exposure to water for 24 hours.
11 . The process according to claim 10 , wherein the compound having an ethylene oxide content has an ethylene oxide content of at least about 60 wt. %, based on the weight of the compound.
12 . The process according to claim 10 , wherein the compound having an ethylene oxide content has an ethylene oxide content of at least about 70 wt. %, based on the weight of the compound.
13 . The process according to claim 10 , wherein the compound having an ethylene oxide content has an ethylene oxide content of at least about 80 wt. %, based on the weight of the compound.
14 . The process according to claim 10 , wherein the compound having an ethylene oxide content is selected from the group consisting of ethylene oxide capped polyols, ethylene oxide monools, and ethylene oxide polyols.
15 . The process according to claim 10 , wherein the compound having an ethylene oxide content is a mixture of ethylene oxide containing amines and polyols.
16 . The process according to claim 10 , wherein the silane-terminated polyurethane prepolymer contains ethylene oxide.
17 . The process according to claim 10 , wherein the sealant increases at least about 5% by weight and at least about 5% by volume upon exposure to water for 24 hours.
18 . The process according to claim 10 , wherein the sealant increases at least about 10% by weight and at least about 10% by volume upon exposure to water for 24 hours.
19 . A one-component hydrophilic polyurethane sealant comprising:
a silane-terminated polyurethane prepolymer having an ethylene oxide content of at least about 40 wt. %, based on the weight of the prepolymer; and
a catalyst,
optionally, one or more of plasticizers, fillers, pigments, drying agents, light stabilizers, antioxidants. thixotropic agents and bonding agents,
wherein the one-component hydrophilic polyurethane sealant increases at least about 1.4% by weight and at least about 2.5% by volume upon exposure to water for 24 hours.
20 . The one-component hydrophilic polyurethane sealant according to claim 19 , wherein the silane-terminated polyurethane prepolymer has an ethylene oxide content of at least about 60 wt. %, based on the weight of the prepolymer.
21 . The one-component hydrophilic polyurethane sealant according to claim 19 , wherein the silane-terminated polyurethane prepolymer has an ethylene oxide content of at least about 70 wt. %, based on the weight of the prepolymer.
22 . The one-component hydrophilic polyurethane sealant according to claim 19 , wherein the silane-terminated polyurethane prepolymer has an ethylene oxide content of at least about 80 wt. %, based on the weight of the prepolymer.
23 . The one-component hydrophilic polyurethane sealant according to claim 19 , wherein the sealant increases at least about 5% by weight and at least about 5% by volume upon exposure to water for 24 hours.
24 . The one-component hydrophilic polyurethane sealant according to claim 19 , wherein the sealant increases at least about 10% by weight and at least about 10% by volume upon exposure to water for 24 hours.