Positive photoresist composition
View Patent ↗Disclosed is a positive photoresist composition used for a liquid crystal display. The positive photoresist composition of the present invention includes 3 to 50% by weight of binder resin having a certain structure, 2 to 40% by weight of a photoactive compound and 10 to 94% by weight of an organic solvent. The positive photoresist composition according to the present invention may be useful to form a pattern for an organic insulator of a liquid crystal display, metal patterning, a bump, hole drilling and UV overcoat since it has good basic physical properties such as UV transmittance, film retention, pattern stability, chemical resistance and so on, as well as an excellent heat resistance.
1. A positive photoresist composition, comprising:
3 to 50% by weights of a binder resin selected from the group consisting of a resin having the structure of a Chemical Formula 1, a resin having the structure of a Chemical Formula 2, and their mixture;
2 to 40% by weights of a photoactive compound; and
10 to 94% by weights of an organic solvent:
wherein the Chemical Formula 1 has the structure:
wherein, R 1 , R 2 and R 3 are each independently H or methyl,
R 4 is an alkyl or cycloalkyl group having 1 to 10 carbon atoms which contains an epoxy group, and
x and y represent a mole ratio of the repeating units, wherein x is 0.02 to 0.80 and y is 0.20 to 0.98, provided that the binder resin of said Chemical Formula 1 may be a random copolymer which is not limited to a given order of the repeating unit; and
wherein the Chemical Formula 2 has the structure:
wherein, R 5 , R 6 , R 7 and R 9 are each independently H or methyl;
R 8 is an alkyl or cycloalkyl group having 1 to 10 carbon atoms which contains an epoxy group;
R 10 is at least one selected from the group consisting of carboxylic acid, alkoxycarbonyl and aromatic compound which have 1 to 14 carbon atoms;
l, m and n are each a mole ratio of the repeating units, wherein l is 0.02 to 0.70, m is 0.05 to 0.60, and n is 0.01 to 0.60, provided that the binder resin of said Chemical Formula 2 may be a random copolymer which is not limited to a given order of the repeating unit.
2. The positive photoresist composition according to claim 1 , wherein the binder resin having the structure of Chemical Formula 1 has an average molecular weight of 2,000 to 300,000 and a polydispersity of 1.0 to 10.0.
3. The positive photoresist composition according to claim 1 , wherein the organic solvent comprises at least one selected from the group consisting of ethyl acetate, butyl acetate, diethylene glycol dimethyl ether, diethylene glycol dimethyl ethyl ether, methylmethoxy propionate, ethylethoxy propionate (EEP), ethyllactate, propylene glycol methyl etheracetate (PGMEA), propylene glycol methyl ether, propylene glycol propyl ether, methylcellosolveacetate, ethylcellosolveacetate, diethylene glycol methyl acetate, diethylene glycol ethyl acetate, acetone, methyl isobutyl ketone, cyclohexanone, dimethylformamide (DMF), N,N-dimethylacetamide (DMAc), N-methyl-2-pyrrolidone (NMP), γ-butyrolactone, diethylether, ethylene glycol dimethyl ether, diglyme(Diglyme), tetrahydrofuran (THF), methanol, ethanol, propanol, isopropanol, methylcellosolve, ethylcellosolve, diethylene glycol methyl ether, diethylene glycol ethyl ether, dipropylene glycol methyl ether, toluene, xylene, hexane, heptane and octane.
4. The positive photoresist composition according to claim 1 , wherein the photoactive compound is a compound having a structure in which a group naphthoquinone-1,2-diazide-5-sulfonic acid ester or naphthoquinone-1,2-diazide-4-sulfonic acid ester is substituted with a ballast having 1 to 6 hydroxyl groups.
5. The positive photoresist composition according to claim 1 , further comprising 0.0001 to 3% by weights of a silicon-based compound containing epoxy or amine group.
6. The positive photoresist composition according to claim 5 , wherein the silicon-based compound containing epoxy or amine group comprises at least one selected from the group consisting of (3-glycidoxypropyl)trimethoxysilane, (3-glycidoxypropyl)triethoxysilane, (3-glycidoxypropyl)methyldimethoxysilane, (3-glycidoxypropyl)methyldiethoxysilane, (3-glycidoxypropyl)dimethylmethoxysilane, (3-glycidoxypropyl)dimethylethoxysilane, 3,4-epoxybutyltrimethoxysilane, 3,4-epoxybutyltriethoxysilane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, 2-(3,4-epoxycyclohexyl)ethyltriethoxysilane and aminopropyl trimethoxysilane.