Process to prepare salt
View Patent ↗The present invention relates to a process to prepare salt comprising the following steps: (i) preparing an aqueous salt solution containing at least 100 g/l of sodium chloride and at least 0.01 ppm of polyvalent cations by dissolving a sodium chloride source in industrial water, (ii) adding an effective amount of at least one positive retention enhancing component to the aqueous salt solution, (iii) subsequently subjecting the solution to a nanofiltration step, thereby separating the solution into a retentate which is enriched for the polyvalent cations and a permeate which is the purified aqueous salt solution, and (iv) concentrating the permeate to produce salt.
1. A process to prepare salt comprising the following steps:
(i) preparing an aqueous salt solution containing at least 100 g/l of sodium chloride and at least 0.01 ppm of polyvalent cations by dissolving a sodium chloride source containing more than 25% by weight sodium chloride in industrial water,
(ii) adding an effective amount of at least one positive retention enhancing component to the aqueous salt solution,
(iii) subsequently subjecting the solution to a nanofiltration step, thereby separating the solution into a retentate which is enriched for the polyvalent cations and a permeate which is the purified aqueous salt solution, and
(iv) concentrating the permeate to produce salt.
2. The process according to claim 1 further comprising adjusting the concentration of sodium chloride to be at least 100 g/l in a step subsequent to or simultaneous with step (ii) of adding the positive retention enhancing component to the aqueous solution and before nanofiltration step (iii).
3. The process according to claim 1 wherein at least part of the retentate is recycled for use in dissolution step (i).
4. The process according to claim 1 wherein the aqueous solution comprises at least 300 g/l of sodium chloride.
5. The process according to claim 1 wherein the at least one positive retention enhancing component is selected from the group consisting of polycarboxylic acids; polyacrylates; polymaleic acids; oligopeptides; polypeptides; polymers bearing two or more ester groups or carboxyalkyl groups; sugars; ferrocyanide salts; quaternary ammonium salts; cyclodextrines; urea; polymers bearing amino groups; polymers bearing one or more alcohol groups; polymers bearing quaternary ammonium groups; polymers comprising nitrogen-containing aliphatic rings; sodium salts of polymers bearing anionic groups; chloride salts of polymers bearing cationic groups; surfactants from a natural source; lactic acid; phospholipids; a suspension of yeast cells; a suspension of algae; maleic anhydride homopolymer; amylase; protease; sodium citrate; citric acid; nonanoyloxybenzene sulphonate; polyepoxysuccinic acid; polyacrylamide; sodium ethylenediamine tetraacetate; ethylenediamine tetramethylene phosphonic acid; sulphonated polyoxyethylene ethers; fatty acids; orange juice; apple juice; and Fe(II) or Fe(III) iron complexes with one of the above-mentioned compounds.
6. The process according to claim 5 wherein polymers bearing two or more ester groups or carboxyalkyl groups also bear a member of the group consisting of phosphate groups, phosphonate groups, phosphino groups, sulphate groups, sulphonate groups and combinations thereof; the sugars are selected from the group consisting of functionalized monosaccharides, unfunctionalized monosaccharides, functionalized disaccharides, unfunctionalized disaccharides, functionalized polysaccharides and unfunctionalized polysaccharides; and the natural source is disproportionated rosin acid soap.
7. The process according to claim 1 wherein the at least one positive retention enhancing component is selected from the group consisting of (poly)carboxylic acids, phosphinocarboxylic acids, polyacrylic acids, polymaleic acids, glucose, sucrose, saccharose, and sodium gluconate.
8. The process according to claim 1 wherein the at least one positive retention enhancing component is added in an amount of at least 15 ppm.
9. The process according to claim 1 wherein the at least one positive retention enhancing component is added in an amount of less than 5,000 ppm.
10. The process according to claim 1 wherein the polyvalent ions comprise calcium, magnesium, strontium, iron, barium, and/or aluminium.
11. The process according to claim 10 wherein the amount of either calcium or magnesium in the aqueous solution is less than 2,000 ppm.
12. The process according to claim 10 wherein the amount of either calcium or magnesium in the aqueous solution is less than 1,400 ppm.
13. The process according to claim 1 wherein the amount of sulphate anions in the aqueous salt solution is less than 75,000 ppm.
14. The process according to claim 1 wherein the sodium chloride source is a natural salt source containing more than 75% by weight of NaCl.
15. The process according to claim 1 wherein the aqueous solution is a saturated sodium chloride solution.
16. The process according to claim 1 wherein the at least one positive retention enhancing component is added in an amount of at least 50 ppm.
17. The process according to claim 16 wherein the at least one positive retention enhancing component is added in an amount of less than 350 ppm.
18. The process according to claim 1 wherein the at least one positive retention enhancing component is added in an amount of less than 350 ppm.
19. The process according to claim 1 wherein the amount of sulphate anions in the aqueous salt solution is less than 8,000 ppm.
20. The process according to claim 1 wherein the sodium chloride source is a natural salt source containing more than 90% by weight of NaCl.