Adhesive for polarizer plate and method for manufacturing the same
Disclosed is an adhesive for a polarizing plate that comprises a polyvinyl alcohol-based resin with an acetoacetyl group and an amine-based metal compound crosslinking agent, and a method of manufacturing the same.
1. An adhesive for a polarizing plate comprising:
a polyvinyl alcohol-based resin with an acetoacetyl group which comprises 0.1 to 30 mol % of the acetoacetyl group; and
an amine-based metal compound crosslinking agent,
wherein the adhesive is an aqueous solution with a pH of more than 2 and 9 or less,
wherein the amine-based metal compound crosslinking agent is a metal complex comprising an amine-based ligand, and
wherein the metal complex comprises titanium (Ti), and one or more amine groups selected from the group consisting of primary amine, secondary amine, and tertiary amine as the ligand.
2. The adhesive for a polarizing plate according to claim 1 , wherein the adhesive comprises 100 parts by weight of the polyvinyl alcohol-based resin with the acetoacetyl group and 1 to 50 parts by weight of the amine-based metal compound crosslinking agent.
3. The adhesive for a polarizing plate according to claim 1 , wherein the pH of the aqueous solution is controlled using one or more acids selected from the group consisting of nitric acid, hydrochloric acid, sulfuric acid, and acetic acid.
4. The adhesive for a polarizing plate according to claim 1 , wherein the adhesive is used to attach a polarizer and a transparent protective film to each other.
5. The adhesive for a polarizing plate according to claim 4 , wherein the transparent protective film is a film that is made of one or more selected from the group consisting of polyethylene terephthalate, polyethylene naphthalate, triacetyl cellulose, polymethylmethacrylate, acrylonitrile-styrene copolymer, polycarbonate, and cycloolefin.